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Molecular Structure and Photoluminescence Behavior of the Zn(II) Carboxylate Complex with Pyrazino[2,3-f][1,10]phenanthroline

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Abstract

A new complex [Zn(Piv)2(Pyzphen)] (I) was prepared by the reaction of pyrazino[2,3-f][1,10]phenanthroline (Pyzphen) with Zn(II) pivalate [Zn(Piv)2]n. An X-ray diffraction study (CIF file CCDC no. 1912821) revealed that complex I has a mononuclear structure, with ZnN2O4 coordination unit being a distorted trigonal prism. Quantum chemical simulation of dimerization of complex I, resulting in the hypothetical binuclear product [Zn(Piv)2(Pyzphen)]2 (II), showed that two energy demanding transition states present on the path of association of the complex molecules may prevent the experimental isolation of binuclear complex II. According to the results of luminescence studies of the Pyzphen ligand and complex I, the ligand emission band shifts to the blue region upon coordination to zinc(II) ion.

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ACKNOWLEDGMENTS

X-ray diffraction analysis, IR spectroscopy, luminescence, and elemental analysis were performed using equipment of the Center for Collective Use of Physical Investigation Methods, Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, within the state assignment of the Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, in the field of fundamental research.

Funding

This study was supported by the Russian Science Foundation (project no. 16-13-10537).

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    S. A. Nikolaevskii, D. S. Yambulatov, A. A. Sidorov, M. A. Kiskin & I. L. Eremenko

  2. Institute of Physical and Organic Chemistry, Southern Federal University, 344090, Rostov-on-Don, Russia

    A. A. Starikova

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  1. S. A. Nikolaevskii
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  2. D. S. Yambulatov
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  6. I. L. Eremenko
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Correspondence to D. S. Yambulatov.

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Translated by Z. Svitanko

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Nikolaevskii, S.A., Yambulatov, D.S., Starikova, A.A. et al. Molecular Structure and Photoluminescence Behavior of the Zn(II) Carboxylate Complex with Pyrazino[2,3-f][1,10]phenanthroline. Russ J Coord Chem 46, 260–267 (2020). https://doi.org/10.1134/S1070328420040053

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