Skip to main content
SpringerLink
Log in

Photoluminescence of the Coordination Zinc Compounds with 3-Methyl-4-Formyl-1-Phenylpyrazol-5-one Acylhydrazones

  • Published:
Russian Journal of Coordination Chemistry Aims and scope Submit manuscript

Abstract

New coordination zinc compounds based on 3-methyl-4-formyl-1-phenylpyrazol-5-one acylhydrazones [Zn(L)(CH3COO)Solv] (Solv is H2O (I), Py (II)) are synthesized in order to search for new luminophores demonstrating efficient photoluminescence in the visible range. Complexes I and II are characterized by elemental and thermogravimetric analyses, mass spectrometry, and UV and IR spectroscopy. The structures of two complexes [Zn(L5)(CH3COO)H2O] and [ZnL4(CH3COO)Py] are determined by X-ray structure analysis (CIF files CCDC nos. 1958400 and 1958401, respectively). Complexes I and II demonstrate luminescence in the visible range with a maximum at 414–536 nm and a quantum yield of 9.5–64% depending on the nature of the acyl fragment.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.
Fig. 6.

Similar content being viewed by others

REFERENCES

  1. Ch, Y. and Chou, P.-T., Chem. Soc. Rev., 2010, vol. 39, p. 638.

    Article  Google Scholar 

  2. Eliseeva, S.V. and Bunzl, J.-C.G., Chem. Soc. Rev., 2010, vol. 39, p. 189.

    Article  CAS  Google Scholar 

  3. Xu, Y., Meng, J., Meng, L., et al., Chem.-Eur. J., 2010, vol. 16, p. 12898.

    Article  CAS  Google Scholar 

  4. Yu, X.-Y., Ye, L., Zhang, X., et al., Dalton Trans., 2010, vol. 39, p. 10617.

    Article  CAS  Google Scholar 

  5. Dumur, F., Conta, E., Wantz, G., and Gigmes, D., Eur. J. Inorg. Chem., 2014, p. 4186.

  6. Dong, Y.-W., Fan, R.-Q., Chen, W., et al., RSC Adv., 2016, vol. 6, p. 110422.

    Article  CAS  Google Scholar 

  7. Li, S.M., Zheng, X.J., Yuan, D.Q., et al., Inorg. Chem., 2012, vol. 51, p. 1201.

    Article  CAS  Google Scholar 

  8. Dumur, F., Beouch, L., and Tehfe, M.A., et al, Thin Solid Films, 2014, vol. 564, p. 351.

    Article  CAS  Google Scholar 

  9. Kotova, O.V., Eliseeva, S.V., Averjushkin, A.S., et al., Russ. Chem. Bull. Int. Ed., 2008, vol. 57, p. 1881.

    Article  Google Scholar 

  10. Gusev, A.N., Kiskin, M.A., Braga, E.V., et al., J. Phys. Chem., 2019, vol. 123, p. 11850.

    CAS  Google Scholar 

  11. Burlov, A.S., Vlasenko, V.G., Dmitriev, A.V., et al., Synth. Met., 2015, vol. 203, p. 156.

    Article  CAS  Google Scholar 

  12. Xu, G.-C., Zhang, L., Zhang, Y.-H., et al., CrystEngComm, 2013, vol. 15, p. 2873.

    Article  CAS  Google Scholar 

  13. Wang, L., Qin, W., Tang, X., et al., J. Phys. Chem. A, 2011, vol. 115, p. 1609.

    Article  CAS  Google Scholar 

  14. Borbone, F., Caruso, U., Causa, M., et al., Eur. J. Inorg. Chem., 2014, p. 2695.

  15. Marchetti, F., Pettinari, C., Di Nicola, C., et al., Coord. Chem. Rev., 2019, vol. 401, p. 213069.

    Article  CAS  Google Scholar 

  16. Kvitko, I.Ya. and Porai-Koshits, B.A., Zh. Org. Khim., 1969, vol. 5, no. 9, p. 1685.

    CAS  Google Scholar 

  17. Mohamed, S.K., Mague, J.T., Akkurt, M., et al., I-UCrData, 2017, vol. 2. x171666.

    CAS  Google Scholar 

  18. Sheldrick, G.M., SADABS. Program for Scanning and Correction of Area Detector Data, Göttinngen: Univ. of Göttingen, 1997.

  19. Gusev, A., Shul’gin, V., Braga, E., et al., J. Lumin., 2018, vol. 202, p. 370.

    Article  CAS  Google Scholar 

  20. Gusev, A.N., Shul’gin, V.F., Braga, E.V., et al., Polyhedron, 2018, vol. 155, p. 202.

    Article  CAS  Google Scholar 

  21. Burlov, A.S., Koshchienko, Y.V., Makarova, N.I., et al., Synth. Met., 2016, vol. 220, p. 543.

    Article  CAS  Google Scholar 

Download references

Funding

This work was supported by the President of the Russian Federation in the framework of state support for young Russian scientists, doctors of science (project no. MD-1765.2019.3).

Author information

Authors and Affiliations

  1. Vernadsky Federal University, Simferopol, Crimea, Russia

    A. N. Gusev, E. V. Braga, N. V. Lyubomirskii, E. A. Zamnius & V. F. Shul’gin

  2. St. Petersburg State University, 199164, St. Petersburg, Russia

    M. A. Kryukova

Authors
  1. A. N. Gusev
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. E. V. Braga
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. M. A. Kryukova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. N. V. Lyubomirskii
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. E. A. Zamnius
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. V. F. Shul’gin
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. N. Gusev.

Ethics declarations

The authors declare that they have no conflicts of interest.

Additional information

Translated by E. Yablonskaya

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Gusev, A.N., Braga, E.V., Kryukova, M.A. et al. Photoluminescence of the Coordination Zinc Compounds with 3-Methyl-4-Formyl-1-Phenylpyrazol-5-one Acylhydrazones. Russ J Coord Chem 46, 251–259 (2020). https://doi.org/10.1134/S107032842004003X

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S107032842004003X

Keywords:

Search

Navigation