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Essential Oil of Salvia officinalis as Novel Eco-Friendly Inhibitor for Carbon Steel in HCl Solution: Weight Loss, Electrochemical and XPS Studies

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Abstract

Essential oil of a medicinal plant (Salvia officinalis), used as an eco-friendly inhibitor for the corrosion of carbon steel in 1 M HCl, is presented. The corrosion inhibition properties of Salvia officinalis essential oil were evaluated by gravimetric and electrochemical methods. The results showed that the inhibition efficiency increases with the increase in inhibitor content to reach 82.84 at % 1.8 g/L. X-ray Photoelectron Spectroscopy (XPS) analyses showed that the corrosion inhibition effect is linked to the adsorption of Salvia officinalis essential oil molecules on the steel surface. It was shown that the adsorption of the investigated inhibitor on the substrate surface obeyed to Temkin isotherm model.

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REFERENCES

  1. Rozenfeld, I.L., Corrosion Inhibitors, New York: McGraw-Hill, 1981.

    Google Scholar 

  2. Ahamad, I., Prasad, R., and Quraishi, M.A., Corros. Sci., 2010, vol. 52, p. 933.

    Article  CAS  Google Scholar 

  3. Obot, I.B. and Obi-Egbedi, N.O., Corros. Sci., 2010, vol. 52, p. 282.

    Article  CAS  Google Scholar 

  4. Ahamad, I. and Quraishi, M.A., Corros. Sci., 2010, vol. 52, p. 651.

    Article  CAS  Google Scholar 

  5. Musa, A.Y., Kadhum, A.A.H., Mohamad, A.B., Takriff, M.S., Daud, A.R., and Kamarudin, S., Corros. Sci., 2010, vol. 52, p. 526.

    Article  CAS  Google Scholar 

  6. Singh, A.K. and Quraishi, M.A., Corros. Sci., 2010, vol. 52, p. 152.

    Article  CAS  Google Scholar 

  7. Amin, M.A., Khaled, K.F., Mohsen, Q., and Arida, H.A., Corros. Sci., 2010, vol. 52, p. 1684.

    Article  CAS  Google Scholar 

  8. Lebrini, M., Robert, F., Vezin, H., and Roos, C., Corros. Sci., 2010, vol. 52, p. 3367.

    Article  CAS  Google Scholar 

  9. Outirite, M., Lagrenée, M., Lebrini, M., Traisnel, M., Jama, C., Vezin, H., and Bentiss, F., Electrochim. Acta, 2010, vol. 55, p. 1670.

    Article  CAS  Google Scholar 

  10. Tayebi, H., Bourazmi, H., Himmi, B., El Assyry, A., Ramli, Y., Zarrouk, A., Geunbour, A., Hammouti, B., and Ebenso, E.E., Pharm. Lett., 2014, vol. 6, p. 20.

    CAS  Google Scholar 

  11. Tayebi, H., Bourazmi, H., Himmi, B., El Assyry, A., Ramli, Y., Zarrouk, A., Geunbour, A., and Hammouti, B., Pharma Chem., 2014, vol. 6, p. 220.

    Google Scholar 

  12. Bouyanzer, A. and Hammouti, B., Pigm. Resin Technol., 2004, vol. 33, p. 287.

    Article  CAS  Google Scholar 

  13. Nahlé, A., El Ouadi, Y., Bouyanzer, A., Majidi, L., Paolini, J., Desjobert, J.-M., Costa, J., Chahboun, N., and Zarrouk, A., Hammouti, B., Orient. J. Chem., 2016, vol. 32, no. 4, p. 1909.

    Article  CAS  Google Scholar 

  14. Boujakhrout, A., Hamdani, I., Chahboun, N., Bouyanzer, A., Santana, R.V., and Zarrouk, A., J. Mater. Environ. Sci., 2015, vol. 6, no. 12, p. 3655.

    CAS  Google Scholar 

  15. Chetouani, A., Hammouti, B., and Benkaddour, M., Pigm. Resin Technol., 2004, vol. 33, p. 26.

    Article  CAS  Google Scholar 

  16. El Ouariachi, E., Paolini, J., Bouklah, M., Elidrissi, A., Bouyanzer, A., Hammouti, B., Desjobert, J.-M., and Costa, J., Acta Metall. Sin., 2010, vol. 23, p. 13.

    CAS  Google Scholar 

  17. Bourazmi, H., Tabyaoui, M., EL Hattabi, L., El Aoufir, Y., and Taleb, M., J.Mater. Environ. Sci., 2018, vol. 9, no. 3, p. 928.

    CAS  Google Scholar 

  18. Tourabi, M., Nohair, K., Traisnel, M., Jama, C., and Bentiss, F., Corros. Sci., 2013, vol. 75, p. 123.

    Article  CAS  Google Scholar 

  19. Lotfi, N., Benhiba, F., Chahboun, N., Bourazmi, H., El Hezzat, M., Al Hamzi, A.H., Zarrok, H., Guenbour, A., Ouhssine, M., Oudda, H., and Zarrouk, A., Pharm. Lett., 2015, vol. 7, p. 1.

    CAS  Google Scholar 

  20. El Azzouzi, M., Aouniti, A., Tighadouin, S., Elmsellem, H., Radi, S., Hammouti, B., El Assyry, A., Bentiss, F., and Zarrouk, A., J. Mol. Liq., 2016, vol. 221, p. 633.

    Article  CAS  Google Scholar 

  21. Emregül, K.C. and Hayvali, M., Mater. Chem. Phys., 2004, vol. 83, p. 209.

    Article  CAS  Google Scholar 

  22. Emregül, K.C. and Aksüt, A.A., Corros. Sci., 2000, vol. 42, p. 2051.

    Article  Google Scholar 

  23. Ramezanzadeh, B., Arman, S.Y., Mehdipour, M., and Markhali, B.P., Appl. Surf. Sci., 2014, vol. 289, p. 129.

    Article  CAS  Google Scholar 

  24. Meresht, E.S., Farahani, T.S., and Neshati, J., Corros. Sci., 2012, vol. 54, p. 36.

    Article  CAS  Google Scholar 

  25. Gutiérrez, E., Rodríguez, J.A., Cruz-Borbolla, J., Alvarado-Rodriguez, J.G., and Thangarasu, P., Corros. Sci., 2016, vol. 108, p. 23.

    Article  CAS  Google Scholar 

  26. Punita, M., Sitashree, B., and Singh, M.M., Corros. Sci., 2014, vol. 85, p. 352.

    Article  CAS  Google Scholar 

  27. Ma, H., Cheng, X., Li, G., Chen, S., Quan, Z., Zhao, S., and Niu, L., Corros. Sci., 2000, vol. 42, p. 1669.

    Article  CAS  Google Scholar 

  28. Popova, A., Christov, M., and Vasilev, A., Corros. Sci., 2007, vol. 49, p. 3290.

    Article  CAS  Google Scholar 

  29. Zarrouk, A., Zarrok, H., Ramli, Y., Bouachrine, M., Hammouti, B., Sahibed-dine, A., and Bentiss, F., J. Mol. Liq., 2016, vol. 222, p. 239.

    Article  CAS  Google Scholar 

  30. Zarrouk, A., Hammouti, B., Lakhlifi, T., Traisnel, M., Vezin, H., and Bentiss, F., Corros. Sci., 2015, vol. 90, pp. 572–584.

    Article  CAS  Google Scholar 

  31. Faustin, M., Maciuk, A., Salvin, P., Roos, C., and Lebrini, M., Corros. Sci., 2015, vol. 92, p. 287.

    Article  CAS  Google Scholar 

  32. Solomon, M.M., Gerengi, H., and Umoren, S.A., ACS Appl. Mater. Interfaces, 2017, vol. 9, p. 6376.

    Article  CAS  Google Scholar 

  33. Tawfik, S.M. and Negm, N.A., J. Mol. Liq., 2016, vol. 215, p. 185.

    Article  CAS  Google Scholar 

  34. Flores, E.A., Olivares, O., Likhanova, N.V., Domínguez-Aguilar, M.A., Nava, N., Guzman-Lucero, D., and Corrales, M., Corros. Sci., 2011, vol. 53, p. 3899.

    Article  CAS  Google Scholar 

  35. Bobina, M., Kellenberger, A., Millet, J.P., Muntean, C., and Vaszilcsin, N., Corros. Sci., 2013, vol. 69, p. 389.

    Article  CAS  Google Scholar 

  36. Gunasekaran, G. and Chauhan, L.R., Electrochim. Acta, 2004, vol. 49, p. 4387.

    Article  CAS  Google Scholar 

  37. Li, X., Deng, S., and Fu, H., Corros. Sci., 2012, vol. 62, p. 163.

    Article  CAS  Google Scholar 

  38. Outirite, M., Lagrenée, M., Lebrini, M., Traisnel, M., Jama, C., Vezin, H., and Bentiss, F., Electrochim. Acta, 2010, vol. 55, p. 1670.

    Article  CAS  Google Scholar 

  39. Briggs, D., Seah, M.P., Practical Surface Analysis by Auger and X-ray Photoelectron Spectroscopy, Sussex: John Wiley and Sons, 1983.

    Google Scholar 

  40. Kelemen, S.R., Afeworki, M., anf Gorbaty, M.L., Energy Fuels, 2002, vol. 16, p. 1450.

    Article  CAS  Google Scholar 

  41. Temesghen, W. and Sherwood, P.M.A., Anal. Bioanal. Chem., 2002, vol. 373, p. 601.

    Article  CAS  Google Scholar 

  42. Babić-Samardžija, K., Lupu, C., Hackerman, N., Barron, A.R., and Luttge, A., Langmuir, 2005, vol. 21, p. 12187.

    Article  CAS  Google Scholar 

  43. Boyd, R.D, Verran, J., Hall, K.E., Underhill, C., Hibbert, S., and West, R., Appl. Surf. Sci., 2001, vol. 172, p. 135.

    Article  CAS  Google Scholar 

  44. Kannan, A.G., Choudhury, N.R., andDutta, N.K., Polymer, 2007, vol. 48, p. 7078.

    Article  CAS  Google Scholar 

  45. Di Castro, V., and Ciampi, S., Surf. Sci., 1995, vols. 331–333, p. 294.

    Article  Google Scholar 

  46. Nakayama, N. and Obuchi, A., Corros. Sci., 2003, vol. 45, p. 2075.

    Article  CAS  Google Scholar 

  47. Pech-Canul, M.A. and Bartolo-Perez, P., Surf. Coat. Technol., 2004, vol. 184, p. 133.

    Article  CAS  Google Scholar 

  48. Bouanis, F.Z., Bentiss, F., Traisnel, M., and Jama, C., Electrochim. Acta, 2009, vol. 54, p. 2371.

    Article  CAS  Google Scholar 

  49. Galtayries, A., Warocquier-Clérout, R., Nagel, M.-D., and Marcus, P., Surf. Interface Anal., 2006, vol. 38, p. 186.

    Article  CAS  Google Scholar 

  50. Moulder, F., Stickle, W.F., Sobol, P.E., and Bomben, K.D., in Handbook of X-Ray Photoelectron Spectroscopy, Chastain, J., Ed., Eden Prairie, MN: Perkin-Elmer Corp., 1992.

    Google Scholar 

  51. Sastri, V.S., Elboujdaini, M., Romn, J.R., and Perumareddi, J.R., Corrosion, 1996, vol. 52, p. 447.

    Article  CAS  Google Scholar 

  52. Umoren, S.A., Solomon, M.M., Eduok, U.M., Obot, I.B., and Israel, A.U., J. Environ. Chem. Eng., 2014, vol. 2, p. 1048.

    Article  CAS  Google Scholar 

  53. Solomon, M.M., Umoren, S.A., Obot, I.B., Sorour, A.A., and Gerengi, H., ACS Appl. Mater. Interfaces, 2018, vol. 10, p. 28112.

    Article  CAS  Google Scholar 

  54. Popova, A., Christov, M., and Vasilev, A., Corros. Sci., 2015, vol. 94, p. 70.

    Article  CAS  Google Scholar 

  55. Solomon, M.M., Gerengi, H., and Umoren, S.A., ACS Appl. Mater. Interfaces, 2017, vol. 9, p. 6376.

    Article  CAS  Google Scholar 

  56. Solomon, M.M., Umoren, S.A., Udosoro, I.I., and Udoh, A.P., Corros. Sci., 2010, vol. 52, p. 1317.

    Article  CAS  Google Scholar 

  57. Biswas, A., Pal, S., and Udayabhanu, G., Appl. Surf. Sci., 2015, vol. 353, p. 173.

    Article  CAS  Google Scholar 

  58. Norr, E.A., Corros. Sci., 2005, vol. 47, p. 33.

    Article  CAS  Google Scholar 

  59. Wang, C., Chen, J., Han, J., Wang, C., and Hu, B., J. Alloys Compd., 2019, vol. 771, p. 736.

    Article  CAS  Google Scholar 

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Bourazmi, H., Rbaa, M., Benkaddour, R. et al. Essential Oil of Salvia officinalis as Novel Eco-Friendly Inhibitor for Carbon Steel in HCl Solution: Weight Loss, Electrochemical and XPS Studies. Prot Met Phys Chem Surf 56, 438–449 (2020). https://doi.org/10.1134/S2070205120020045

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