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The Inhibition Effect of (E)-2-Hydroxy-5-(2-benzylidene) Aminobenzoic Acid on Corrosion behaviour of Mild Steel in 1.0 M HCl Solution

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Abstract

It has recently been synthesized a Schiff base (E)-2-hydroxy-5-(2-benzylidene) aminobenzoic acid and characterized by FTIR, UV–vis and 1H NMR analysis. The electrochemical behaviour of mild steel in 1.0 M HCl solutions in the absence and presence of Hha has been investigated by electrochemical techniques such as potentiodynamic polarization and electrochemical impedance spectroscopy. The inhibition efficiency was found to increase with rise in concentration of synthesized molecule. Scanning electron microscopy observations of mild steel surface confirmed the existence of such an adsorbed film. Contact angle on the metal surface was also measured. Computational analyses of (E)2-hydroxy-5-((2-hydroxybenzylidene) amino benzoic acid were done at B3LYP/6-31G(d) level in gas phase. Sensitivity of this compound towards Fe2+ and Fe3+ ions were determined. Interaction mechanism was proposed.

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Funding

The authors are greatly thankfull to Cukurova University Research Found for financial support (project number of FDK-2017-8458).

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  1. Department of Chemistry, Faculty of Sciences and Letters, Çukurova University, Balcalı, Sarıçam, 01330, Adana, Turkey

    Güray Kılınççeker & Mahmut Baş

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Kılınççeker, G., Baş, M. The Inhibition Effect of (E)-2-Hydroxy-5-(2-benzylidene) Aminobenzoic Acid on Corrosion behaviour of Mild Steel in 1.0 M HCl Solution. Prot Met Phys Chem Surf 56, 414–426 (2020). https://doi.org/10.1134/S2070205120020112

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