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Preparation of Vitamin K3 in Mo–V–P Heteropoly Acid Solutions by Diene Synthesis

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Abstract

The possibility of obtaining vitamin K3 (2-methyl-1,4-naphthoquinone, menadione) by diene synthesis from accessible substrates such as 2-methylphenol (o-cresol) and 2-methylaniline (o-toluidine) was shown. The bifunctional catalysts of these processes are the aqueous solutions of Mo–V–P heteropoly acids, which allow the oxidation and diene synthesis to be performed as a one-pot process.

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Funding

This study was performed under government contract at the Institute of Catalysis, Siberian Branch, Russian Academy of Sciences (project no. АААА-А17-117041710081-1).

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Authors and Affiliations

  1. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia

    L. L. Gogin & E. G. Zhizhina

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  1. L. L. Gogin
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  2. E. G. Zhizhina
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Correspondence to L. L. Gogin.

Additional information

Abbreviations: MD, 2-methyl-1,4-naphthoquinone (vitamin K3, menadione); MN, 2-methylnaphthalene; HPA, heteropoly acid; Su, substrate; х, the number of V atoms in the HPA; m, the degree of reduction of HPA-х equal to the number of accepted electrons or the number of VIV ions; Е, redox potential of the HPA-х solution; MBQ, 2-methyl-1,4-benzoquinone; DMSO, dimethyl sulfoxide; SHE, standard hydrogen electrode.

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Gogin, L.L., Zhizhina, E.G. Preparation of Vitamin K3 in Mo–V–P Heteropoly Acid Solutions by Diene Synthesis. Kinet Catal 61, 276–282 (2020). https://doi.org/10.1134/S0023158420010012

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  • DOI: https://doi.org/10.1134/S0023158420010012

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