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4-Chloro-2,6-Pyridinedicarboxylic Acid Functionalized Mesoporous Silica Nanocomposites for the Synthesis of Sinapaldehyde

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Abstract

4-Chloro-2,6-pyridinedicarboxylic acid (CPDA) functionalized mesoporous silica SBA-15 nanocomposites (SBA/5CPDA) were synthesized and characterized for the Knoevenagel condensation of syringaldehyde and acetaldehyde to synthesize sinapaldehyde in the liquid phase. The physicochemical characterization of the SBA/CPDA nanocomposites showed the decrease in the surface properties (surface area, pore size, pore volume) compared to SBA-15 confirming the complete functionalization of CPDA inside the mesopores of SBA-15 materials. The catalytic activity results displayed high activity (~90%) and selectivity (90–95%) of the desired product (sinapaldehyde) under environmental friendly conditions. All the reaction parameters were optimized to accomplish the maximum conversion of the selective products. Finally, the mechanism of the formation of the products was proposed and discussed.

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ACKNOWLEDGMENTS

Authors thank the institute for necessary help and support.

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Authors and Affiliations

  1. Department of Chemistry Maulana Azad National Institute of Technology (MANIT), Bhopal, M.P., India

    S. Verma & A. Dubey

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  1. S. Verma
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  2. A. Dubey
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Correspondence to A. Dubey.

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Abbreviations: PDA, pyridine-2,6-dicarboxylic acid; CPDA, 4‑chloro-2,6-pyridinedicarboxylic acid; SBA/CPDA, CPDA functionalized mesoprous silica SBA-15 nanocomposites; PXRD, powder X-ray diffraction; SEM, scanning electron microscopy.

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Verma, S., Dubey, A. 4-Chloro-2,6-Pyridinedicarboxylic Acid Functionalized Mesoporous Silica Nanocomposites for the Synthesis of Sinapaldehyde. Kinet Catal 61, 112–118 (2020). https://doi.org/10.1134/S0023158420010103

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