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Crystal Structure and Luminescent Property of a new Three-Dimensional Polymer Based on 3,5-Di(1H-Benzimidazol-1-yl)Pyridine

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Abstract

A three-dimensional Cd(II) complex [Cd(L)(BPDC)]-3H2O (1) (L = 3,5-di(1H-benzimidazol-1-yl)pyridine, H2BPDC = biphenyl-4,4-dicarboxylic acid) is synthesized and characterized using single crystal X-ray diffraction, IR spectroscopy, and elemental analysis. The single crystal X-ray diffraction analysis reveals that complex 1 is a novel twofold interpenetrating 4-connected net with a (65·8) topology. Moreover, complex 1 exhibits an emission band at 400 nm with an inconspicuous shoulder at 525 nm (λex = 329 nm).

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Authors and Affiliations

  1. School of Chemistry and Environmental Engineering, Yancheng Teachers University, Yancheng, Jiangsu Province, P.R. China

    C. Zhang, J.-Q. Tao & J. Wang

Authors
  1. C. Zhang
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  2. J.-Q. Tao
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  3. J. Wang
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Corresponding author

Correspondence to J. Wang.

Additional information

Additional Information

Crystallographic data for the structural analysis have been deposited with the Cambridge Crystallographic Data Center, and CCDC No. 1904210 for complex 1. Copies of the data can be obtained free of charge on application to the Director, CCDC, 12 Union Road, Cambridge, CB2 1EZ, UK (Fax: +44-1223-336033; e-mail: deposit@ccdc.cam.ac.uk or http://www.ccdc.cam.ac.uk).

Conflict of Interests

The authors declare that they have no conflict of interests.

Text © The Author(s), 2019, published in Zhurnal Strukturnoi Khimii, 2019, Vol. 60, No. 12, pp. 2082-2088.

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Zhang, C., Tao, JQ. & Wang, J. Crystal Structure and Luminescent Property of a new Three-Dimensional Polymer Based on 3,5-Di(1H-Benzimidazol-1-yl)Pyridine. J Struct Chem 60, 1995–2000 (2019). https://doi.org/10.1134/S0022476619120163

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  • DOI: https://doi.org/10.1134/S0022476619120163

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