Abstract
Copper bis(acetylacetonate) is studied using mass spectrometry taking account of the natural isotopic composition of the metal. Valid data are obtained for the intensity of copper cations in the mass spectrum, which are confirmed by expected intensity ratios of copper-containing signals in the form of doublets. A new scheme for the main directions of Cu(acac)2 destruction is proposed. The assignment of cation signals in the mass spectrum is performed with a special software by representing Cu(acac)2 as a special discrete structure, a labeled simple graph G.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
P. A. Stabnikov, I. A. Baidina, S. V. Sysoev, N. S. Vanina, N. B. Morozova, and I. K. Igumenov. J. Struct. Chem., 2003, 44(6), 1138.
I. A. Baidina, P. A. Stabnikov, A. D. Vasiliev, S. A. Gromilov, and I. K. Igumenov. J. Struct. Chem., 2004, 45(4), 671–677.
N. B. Morozova, P. A. Stabnikov, I. A. Baidina, P. P. Semyannikov, S. V. Trubin, and I. K. Igumenov. J. Struct. Chem., 2007, 48(5), 889–898.
N. V. Kuratieva, E. S. Vikulova, A. D. Shushanyan, N. S. Nikolaeva, S. I. Dorovskikh, N. S. Mikhaleva, and N. B. Morozova. J. Struct. Chem., 2017, 58(5), 1004–1008.
V. N. Vertoprakhov and S. A. Krupoder. Usp. Khim., 2000, 69(12), 1149.
L. G. Sedova et al. Khim. Fiz., 1996, 15(2), 98.
Pat. № US 2006/0121709 A1, publ. 08.06.2006.
Pat. № CA 2 574 816 A1, publ. 10.02.2005.
Pat. № JP2003201563 (A), publ. 18.07.2003.
N. V. Gerbeleu and K. M. Indrichan. Mass-Spectrometry of Coordination Compounds. Shtiinitca: Kishineu, 1984.
S. M. Schildcrout. J. Phys. Chem, 1976, 80(26), 2834.
C. G. Macdonald and J. C. Shannon. Aust. G. Chem., 1966, 19(9), 1545.
S. Sasaki, Y. Itagaki, T. Kurokawa, and K. Nakanishi. Bull. Chem. Soc. Jpn, 1967, 40, 76.
G. M. Bancroft. Inorg. Chem., 1968, 7(5), 870.
S. S. Berdonosov. Encyclopedia of Physics. Bolshay Rossiyskay Encyclopdia: M., 1992, 3, 366.
L. J. Bellamy. The Infra-Red Spectra of Complex Molecules. Methuen and Co. LTD: London, 1954.
L. J. Bellamy. Advances in Infrared Group Frequencies. Chapman and Hall: London; New York, 1980.
K. Nakamoto. Infrared and Raman Spectra of Inorganic and Coordination Compounds. A Wiley-Interscience Publication John Wiley and Sons. New York, Chichester, Brisbane, Toronto, Singapore, 1986.
J. Mitchel and D. M. Smith. Aquametry. 2-nd ed. John Wiley and Sons LTD: New York, 1990.
V. L. Shirokiy et al. Zh. Obsh. Khim., 1996, 66(2), 184.
K. V. Kradenov et al. Deposit with VINITI, № 8696-в86. Novosibirsk, 1986.
K. V. Kradenov et al. Deposit with VINITI, № 8595-в86. Novosibirsk, 1986.
Author information
Authors and Affiliations
Corresponding author
Additional information
Conflict of Interests
The authors declare that they have no conflict of interests.
Russian Text © The Author(s), 2019, published in Zhurnal Strukturnoi Khimii, 2019, Vol. 60, No. 12, pp. 2025-2030.
Rights and permissions
About this article
Cite this article
Kostyuk, N.N., Dik, T.A., Kazak, M.S. et al. A Mass Spectrometric Study of Copper Bis(Acetylacetonate) with Allowance for the Isotopic Composition of the Metals. J Struct Chem 60, 1940–1945 (2019). https://doi.org/10.1134/S0022476619120096
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0022476619120096