Skip to main content
SpringerLink
Log in

Analysis of High-Purity Germanium Dioxide by Inductively Coupled Plasma Atomic Emission Spectrometry with Reaction Distillation of the Matrix

  • ARTICLES
  • Published:
Journal of Analytical Chemistry Aims and scope Submit manuscript

Abstract

A combined method of analysis of high-purity germanium dioxide by atomic emission spectrometry with matrix preseparation and trace element preconcentration was developed. The matrix was separated in an autoclave of a MARS 5 microwave system without the contact of samples with an acid solution. The method allows the determination of the following 50 analytes with the limits of detection 10–8–10–5 wt %: Ag, Al, As, Au, B, Ba, Be, Cd, Ce, Co, Cr, Cu, Dy, Er, Eu, Fe, Ga, Gd, Hf, Hg, Ho, In, La, Li, Lu, Mg, Mn, Na, Nb, Nd, Ni, P, Pb, Pr, Re, Sb, Sc, Sm, Sn, Sr, Ta, Tb, Te, Ti, Tm, W, Y, Yb, Zn, and Zr.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

REFERENCES

  1. Devyatykh, G.G., Karpov, Yu.A., and Osipova, L.I., Vystavka-kollektsiya veshchestv osoboi chistoty (Collection Exhibition of High-Purity Substances), Moscow: Nauka, 2003.

  2. Nazarenko, V.A., Analiticheskaya khimiya germaniya (Analytical Chemistry of Germanium), Moscow: Nauka, 1973.

  3. Medvedev, N.S., Shaverina, A.V., Tsygankova, A.R., and Saprykin, A.I., Talanta, 2016, no. 155, p. 358.

  4. Petrova, N.I., Tsygankova, A.R., and Saprykin, A.I., Inorg. Mater., 2015, vol. 51, no. 1. P. 57.)

    Article  CAS  Google Scholar 

  5. Chanysheva, T.A., Shelpakova, I.R., and Saprykin, A.I., Zavod. Lab.,Diagn. Mater., 2009, vol. 75, no. 1, p. 7.

    CAS  Google Scholar 

  6. Meruva, A.R., Raparthi, S., and Kumar, S.J., Talanta, 2016, no. 146, p. 259.

  7. Karandashev, V.K., Bezrukov, L.B., Kornoukhov, V.N., Noshenko, S.V., Glavin, G.G., and Ovchinnikov, S.V., J. Anal. Chem., 2009, vol. 64, no. 3, p. 259.

    Article  CAS  Google Scholar 

  8. Ueng, R.L., Sahayam, A.C., Jiang, S.J., and Wan, C.C., J. Anal. At. Spectrom., 2004, no. 19, p. 681.

  9. Shaverina, A.V., Tsygankova, A.R., and Saprykin, A.I., J. Anal. Chem., 2015, vol. 70, no. 1, p. 28.

    Article  CAS  Google Scholar 

  10. Gusel’nikova, T.Ya., Tsygankova, A.R., and Saprykin, A.I., Zavod. Lab., Diagn. Mater., 2019, vol. 85, no. 1, part 2, p. 50.

  11. Tsygankova, A.R., Makashova, G.V., Shelpakova, I.R., and Saprykin, A.I., Analitika Kontrol’, 2011, vol. 15, no. 2, p. 182.

    Google Scholar 

  12. Tsygankova, A.R., Makashova, G.V., Shelpakova, I.R., and Saprykin, A.I., Zavod. Lab.,Diagn. Mater., 2013, vol. 79, no. 3, p. 12.

    CAS  Google Scholar 

  13. TU (Technical Specifications) 48-4-545-90: Germanium Dioxide, Moscow: Giredmet, 1990.

Download references

Funding

This work was carried out in accordance with the Plan of the Scientific and Research Institute of the National Economy of the Siberian Branch of the Russian Academy of Sciences, project no. V.45.1.4, state registration number 0300-2016-0020.

Author information

Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia

    T. Ya. Gusel’nikova, A. R. Tsygankova & A. I. Saprykin

  2. Novosibirsk State University, 630090, Novosibirsk, Russia

    A. R. Tsygankova & A. I. Saprykin

Authors
  1. T. Ya. Gusel’nikova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. R. Tsygankova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. I. Saprykin
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to T. Ya. Gusel’nikova.

Additional information

Translated by O. Zhukova

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Gusel’nikova, T.Y., Tsygankova, A.R. & Saprykin, A.I. Analysis of High-Purity Germanium Dioxide by Inductively Coupled Plasma Atomic Emission Spectrometry with Reaction Distillation of the Matrix. J Anal Chem 75, 582–586 (2020). https://doi.org/10.1134/S1061934820050056

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1061934820050056

Keywords:

Search

Navigation