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Potentiometric Determination of Palladium(II) in Aqueous Solutions Using a Modified Carbon-Paste Electrode

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Abstract

We studied the main electrode functions of carbon paste electrodes (CPEs) modified with 0–20% of dithiooxamidated polysiloxane with respect to palladium(II). The conditions for the potentiometric titration of palladium(II) using modified CPEs as indicator electrodes were selected, namely, pH 1–2, solutions of EDTA and potassium iodide as the titrants; and modifier concentration is 0, 5, and 10%. A procedure was developed for determining palladium(II) in aqueous solutions. The procedure was tested using a GSO solution of palladium(II) and an industrially produced activator Pd-600.

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Funding

This work was supported by Decree no. 211 of the Government of the Russian Federation, contract no. 02.A03.21.0006.

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Authors and Affiliations

  1. Ural Federal University, 620002, Yekaterinburg, Russia

    A. S. Kholmogorova, E. A. Svintsova, L. K. Neudachina & E. L. Lebedeva

  2. Postovskii Institute of Organic Synthesis, Ural Branch, Russian Academy of Sciences, 620990, Yekaterinburg, Russia

    I. S. Puzyrev

Authors
  1. A. S. Kholmogorova
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  2. E. A. Svintsova
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  3. L. K. Neudachina
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  4. E. L. Lebedeva
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  5. I. S. Puzyrev
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Corresponding author

Correspondence to A. S. Kholmogorova.

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Translated by O. Zhukova

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Kholmogorova, A.S., Svintsova, E.A., Neudachina, L.K. et al. Potentiometric Determination of Palladium(II) in Aqueous Solutions Using a Modified Carbon-Paste Electrode. J Anal Chem 75, 679–684 (2020). https://doi.org/10.1134/S106193482005007X

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  • DOI: https://doi.org/10.1134/S106193482005007X

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