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Identification of Impurities in High-Pure Arsine by Chromatography–Mass-Spectrometry

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Abstract

A method of chromatography–mass spectrometry is used to study the impurity composition of arsine synthesized by the reaction of arsenic chloride with sodium borohydride. Capillary adsorption columns with adsorbents modified silica and polytrimethylsilylpropine is used for the separation of impurities. Impurities are identified by comparing their mass spectra with the NIST database, published data, as well as by reconstructing their structures from fragment ions. Impurities of permanent gases; saturated and unsaturated hydrocarbons C1–C6; chlorinated, oxygenated, and aromatic hydrocarbons; volatile inorganic hydrides; and alkyl derivatives of arsine, trimethyl fluorosilane, carbon sulfur dioxide, and dimethyl sulfide are identified in arsine. Mass spectra of C2H3AsH2, CH3AsHC2H5, and C2H5As2H3 impurities are obtained for the first time.

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Funding

This work was carried out in accordance with the Program of Fundamental Scientific Research of State Academies of Sciences for 2019‒2021, topic no. 0095-2019-0001.

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Authors and Affiliations

  1. Devyatykh Institute of Chemistry of High-Purity Substances, Russian Academy of Sciences, 603950, Nizhny Novgorod, Russia

    A. Yu. Sozin, O. Yu. Chernova, T. G. Sorochkina, A. P. Kotkov & N. D. Grishnova

  2. AO NPP “Salyut”, 603950, Nizhny Novgorod, Russia

    A. P. Kotkov, N. D. Grishnova, D. M. Polezhaev & G. V. Pushkarev

  3. Department of Chemistry, Lobachevsky State University of Nizhny Novgorod, 603600, Nizhny Novgorod, Russia

    A. A. Bulanova

Authors
  1. A. Yu. Sozin
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  2. O. Yu. Chernova
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  3. T. G. Sorochkina
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  4. A. P. Kotkov
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  5. N. D. Grishnova
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  6. D. M. Polezhaev
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  7. G. V. Pushkarev
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  8. A. A. Bulanova
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Correspondence to A. Yu. Sozin.

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Translated by V. Kudrinskaya

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Sozin, A.Y., Chernova, O.Y., Sorochkina, T.G. et al. Identification of Impurities in High-Pure Arsine by Chromatography–Mass-Spectrometry. J Anal Chem 75, 600–607 (2020). https://doi.org/10.1134/S1061934820050172

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  • DOI: https://doi.org/10.1134/S1061934820050172

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