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Effect of Matrix Element and Acid on Analytical Signals in Nitrogen Microwave-Plasma Atomic Emission Spectrometry

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Abstract

The effect of matrix elements (Na, In, Bi, Zn, Cu) and nitric and hydrochloric acids on the analytical signals of impurity elements in nitrogen microwave-plasma atomic emission spectrometry (MP AES) was studied. In the range of acid concentrations 0.1–0.5 M (for rare-earth elements, 0.1–0.9 M), the analytical signals of the elements did not change. The presence of a matrix element in a concentration of 1 wt % led to a significant change in the signal for most elements, which must be taken into account in selecting a calibration strategy. In MP AES, it is necessary to fully comply with the conformity of samples and calibration solutions regarding the type and concentration of acid and matrix elements.

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Funding

This work was supported by the Program of the Federal Scientific Research Institute of State Academies of Sciences for 2013–2020 (project no. V.45.1.4.).

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia

    E. V. Polyakova & A. I. Saprykin

  2. Novosibirsk State University, 630090, Novosibirsk, Russia

    E. V. Polyakova, Yu. N. Nomerotskaya & A. I. Saprykin

Authors
  1. E. V. Polyakova
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  2. Yu. N. Nomerotskaya
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  3. A. I. Saprykin
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Correspondence to E. V. Polyakova.

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Translated by O. Zhukova

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Polyakova, E.V., Nomerotskaya, Y.N. & Saprykin, A.I. Effect of Matrix Element and Acid on Analytical Signals in Nitrogen Microwave-Plasma Atomic Emission Spectrometry. J Anal Chem 75, 474–478 (2020). https://doi.org/10.1134/S1061934820040115

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  • DOI: https://doi.org/10.1134/S1061934820040115

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