Skip to main content
SpringerLink
Log in

Platinum Electrodeposition from a Carbon Dioxide-Based Supercritical Electrolyte

  • PHYSICAL CHEMISTRY
  • Published:
Doklady Physical Chemistry Aims and scope Submit manuscript

Abstract

The electrodeposition of platinum from a carbon dioxide-based supercritical electrolyte with the addition of acetonitrile as a cosolvent and tetrabutylammonium tetrafluoroborate has been studied for the first time. Dimethyl(1,5-cyclooctadiene)platinum has been used as a precursor. It has been demonstrated that potentiostatic electrodeposition leads to the formation of agglomerates of densely packed platinum nanoparticles rather than to a continuous film.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.

Similar content being viewed by others

REFERENCES

  1. Bartlett, P.N., Cook, D.A., George, M.W., et al., Phys. Chem. Chem. Phys., 2014, vol. 16, pp. 9202–9219. https://doi.org/10.1039/c3cp54955k

    Article  CAS  PubMed  Google Scholar 

  2. Ke, J., Su, W., Howdle, S.M., et al., Proc. Natl. Acad. Sci. U.S.A., 2009, vol. 106, pp. 14768–14772. https://doi.org/10.1073/pnas.0901986106

    Article  PubMed  PubMed Central  Google Scholar 

  3. Cook, D., Bartlett, P.N., Zhang, W., et al., Phys. Chem. Chem. Phys., 2010, vol. 12, p. 11744. https://doi.org/10.1039/c004227g

    Article  CAS  PubMed  Google Scholar 

  4. Sakamoto, K., Nakabayashi, K., and Fuchigami, T., Electrochemistry, 2013, vol. 81, pp. 328–330. https://doi.org/10.5796/electrochemistry.81.328

    Article  CAS  Google Scholar 

  5. Atobe, M., Yoshida, N., Sakamoto, K., et al., Electrochim. Acta, 2013, vol. 87, pp. 409–415. https://doi.org/10.1016/j.electacta.2012.09.032

    Article  CAS  Google Scholar 

  6. Chuang, H.-C., Chang, T.-S., and Sanchez, J., Mater. Lett., 2019, vol. 236, pp. 657–660. https://doi.org/10.1016/j.matlet.2018.11.037

    Article  CAS  Google Scholar 

  7. Bartlett, P.N., Cook, D.A., Hasan, M.M., et al., RSC Adv., 2017, vol. 7, pp. 40720–40726. https://doi.org/10.1039/C7RA07092F

    Article  CAS  Google Scholar 

  8. Lodge, A.W., Hasan, M.M., Bartlett, P.N., et al., RSC Adv., 2018, vol. 8, pp. 24013–24020. https://doi.org/10.1039/C8RA03183E

    Article  CAS  Google Scholar 

  9. Grigor’ev, T.E., Said-Galiev, E.E., Nikolaev, Y.A., et al., Nanotechnol. Russ., 2011, vol. 6, pp. 311–322. https://doi.org/10.1134/S1995078011030062

    Article  Google Scholar 

  10. Abbott, A.P. and Eardley, C.A., J. Phys. Chem. B, 2000, vol. 104, pp. 775–779. https://doi.org/10.1021/jp9932867

    Article  CAS  Google Scholar 

  11. Plyasova, L.M., Molina, I.Y., Gavrilov, A.N., et al., Electrochim. Acta, 2006, vol. 51, pp. 4477–4488. https://doi.org/10.1016/j.electacta.2005.12.027

    Article  CAS  Google Scholar 

  12. Scharifker, B. and Hills, G., Electrochim. Acta, 1983, vol. 28, pp. 879–889. https://doi.org/10.1016/0013-4686(83)85163-9

    Article  CAS  Google Scholar 

  13. Trasatti, S. and Petrii, O.A., Pure Appl. Chem., 1991, vol. 63, pp. 711–734. https://doi.org/10.1351/pac199163050711

    Article  CAS  Google Scholar 

Download references

Funding

The study was supported by the Russian Science Foundation (project no. 16–13–10338 P).

Author information

Authors and Affiliations

  1. Moscow State University, 119991, Moscow, Russia

    E. D. Ursov, M. S. Kondratenko & M. O. Gallyamov

  2. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991, Moscow, Russia

    M. O. Gallyamov

Authors
  1. E. D. Ursov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. M. S. Kondratenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. M. O. Gallyamov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to M. S. Kondratenko.

Additional information

Translated by G. Kirakosyan

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Ursov, E.D., Kondratenko, M.S. & Gallyamov, M.O. Platinum Electrodeposition from a Carbon Dioxide-Based Supercritical Electrolyte. Dokl Phys Chem 489, 173–176 (2019). https://doi.org/10.1134/S0012501619120029

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0012501619120029

Search

Navigation