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Synthesis of Pyridines and Quinolines by Heterogeneous Catalytic Condensation of Ammonia and Aniline with Glycerol and Its Isopropylidene Derivative

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Abstract

Synthesis of pyridines and quinolines by the condensation of ammonia and aniline with glycerol and its isopropylidene derivative on zeolite catalysts with micro- and micro-meso-macroporous structure has been studied for the first time. Effect of processing parameters (temperature, catalyst type, and initial reagent ratio) on product yield (pyridine and a mixture of o- and p-methylpyridines or quinoline and a mixture of o- and p-methylquinolines) has been studied.

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Correspondence to G. Z. Raskil’dina.

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Translated by I. Kudryavtsev

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Bayburtli, A.V., Grigorieva, N.G., Raskil’dina, G.Z. et al. Synthesis of Pyridines and Quinolines by Heterogeneous Catalytic Condensation of Ammonia and Aniline with Glycerol and Its Isopropylidene Derivative. Dokl Chem 490, 32–35 (2020). https://doi.org/10.1134/S0012500820020019

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  • DOI: https://doi.org/10.1134/S0012500820020019

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