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Study of the of Polymerization of 2,3,4,5,6-Pentafluorostyrene in the Presence of Poly-2-hydroxyethyl Methacrylate Chain Transfer Agent

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Abstract

The radical polymerization of 2,3,4,5,6-pentafluorostyrene (PFS) in the presence of poly-2-hydroxyethyl methacrylate with a dithiobenzoate end group as a chain transfer agent was studied in DMF-d7 in situ by 1H NMR spectroscopy. It was found that the reaction has virtually no induction period and proceeds at a higher rate than PFS polymerization in the presence of a low-molecular-weight chain transfer agent. A possible reason for the observed kinetic features is the self-assembly of PFS and 2-hydroxyethyl methacrylate diblock copolymers during the polymerization.

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Funding

The study was supported by the Russian Science Foundation (project no. 17–13–01359). Recording of the NMR spectra and elemental analysis were supported by the Ministry of Science and Higher Education of the Russian Federation using the research equipment of the Center of Molecular Structure Investigation, Nesmeyanov Institute of Organoelement Compounds, RAS.

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Authors and Affiliations

  1. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991, Moscow, Russia

    K. E. Chekurov, A. I. Barabanova, I. V. Blagodatskikh, A. V. Muranov, A. S. Peregudov &  A. R. Khokhlov

  2. Department of Physics, Moscow State University, 119991, Moscow, Russia

    T. V. Laptinskaya &  A. R. Khokhlov

Authors
  1. K. E. Chekurov
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  2. A. I. Barabanova
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  3. I. V. Blagodatskikh
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  4. A. V. Muranov
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  5. T. V. Laptinskaya
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  6. A. S. Peregudov
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  7. A. R. Khokhlov
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Corresponding author

Correspondence to K. E. Chekurov.

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Translated by Z. Svitanko

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Chekurov, K.E., Barabanova, A.I., Blagodatskikh, I.V. et al. Study of the of Polymerization of 2,3,4,5,6-Pentafluorostyrene in the Presence of Poly-2-hydroxyethyl Methacrylate Chain Transfer Agent. Dokl Chem 490, 27–31 (2020). https://doi.org/10.1134/S0012500820020020

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  • DOI: https://doi.org/10.1134/S0012500820020020

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