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Physicochemical Characterization of Pelletized Lime Kiln Dust as Potential Liming Material for Acidic Soils

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Abstract

Lime kiln dust (LKD) is a fine particulate material by-product produced during the lime burning processes. Current reuse options are chiefly focused on reuse in the cement industry which are limited by the inherent porosity of this by-product. Due to the presence of calcium (Ca), magnesium (Mg) and other elements which can serve as micronutrients to the plants, LKD has the potential to be used as a replacement for conventional liming materials for both soil pHKCl increase and plant supplement with secondary major- (Ca and Mg) and micronutrients (Mn, Cu, Zn and Ni). The work described here outlines the investigation of physicochemical properties of pelletized LKD materials and their effect on soil pHKCl, available Ca and Mg content in the soil as well as straw and grain yields of spring barley. LKD were analyzed using X-ray diffraction, scanning electron microscopy with energy dispersive analysis, while detailed chemical analysis of both pelletized LKD and soil was performed using Atomic Absorption Spectroscopy. Pellet size and major element composition were used as chief indicators for the liming capacity of LKD. It was shown that low acidic soil (pHKCl 5.4) can be conditioned using fine (0.1–2 mm) pelletized LKD due to the high release rates while coarse pellets (5–8 mm) did not significantly increase available Ca and Mg content in soil and did not reach optimum pHKCl range even after 48 weeks. The highest application rate of LKD at 4 t/ha increased spring barley grain yield compared to control but the increase was not statistically significant. Thus, pelletized lime kiln dust could be a potential alternative to natural limestone or dolomite minerals as liming material for acid soils with the pellet size determining the liming kinetics.

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Acknowledgements

This material is based on work supported by the National Science Foundation under grant no. CHE 1710120 and DBI 1828508, and by the long-term research program ‘Productivity and sustainability of agricultural and forest soils’ implemented by the Lithuanian Research Centre for Agriculture and Forestry. This work is also supported by Engineering for Agricultural Production Systems program grant no. 2020-67022-31144 from the USDA National Institute of Food and Agriculture.

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  1. Department of Chemical and Biomolecular Engineering, Lehigh University, B336 Iacocca Hall, 111 Research Drive, Bethlehem, PA, 18015, USA

    Donata Drapanauskaite, Kristina Buneviciene & Jonas Baltrusaitis

  2. Lithuanian Research Centre for Agriculture and Forestry, Kedainiai Dist., Instituto av. 1, 58344, Akademija, Lithuania

    Donata Drapanauskaite, Kristina Buneviciene, Regina Repsiene & Romas Mazeika

  3. Department of Chemistry, Skidmore College, 815 North Broadway, Saratoga Springs, NY, 12866, USA

    Juan Navea

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Drapanauskaite, D., Buneviciene, K., Repsiene, R. et al. Physicochemical Characterization of Pelletized Lime Kiln Dust as Potential Liming Material for Acidic Soils. Waste Biomass Valor 12, 1267–1280 (2021). https://doi.org/10.1007/s12649-020-01107-0

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