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The influence of the Gemini surfactants hydrocarbon tail on in-situ synthesis of silver nanoparticles: Characterization, surface studies and biological performance

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Abstract

Three different Gemini compounds containing different lengths of multi-carbonyl groups were synthesized, and the effect of their hydrocarbon tail length on the AgNPs synthesis was investigated. The Gemini surfactants with the long hydrocarbon chain tail produces small AgNPs with a narrow size distribution and high colloidal stability in an aqueous phase. The surface parameters of the aqueous solution were affected by the hydrocarbon chain length as well as phase temperature. The critical micelle concentration, assessed by surface tension and conductometric measurements, decreases with both increasing solution temperature and increasing hydrocarbon tail length. Thermodynamic calculations predicted the ability of the synthesized Gemini surfactant to adsorb on the phase surface and aggregate in a cluster.

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Acknowledgements

This work was financially supported by a National Research Foundation of Korea (NRF) grant funded by the Ministry of Education, Science and Technology (NRF-2018R1D1A1B07041584).

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Authors and Affiliations

  1. School of Chemical Engineering, Sungkyunkwan University, Suwon, 16419, Korea

    Samy M. Shaban & Dong-Hwan Kim

  2. Biomedical Institute for Convergence at SKKU (BICS), Sungkyunkwan University, Suwon, 16419, Korea

    Samy M. Shaban & Dong-Hwan Kim

  3. Petrochemical Department, Egyptian Petroleum Research Institute (EPRI), Nasr City, Egypt

    Samy M. Shaban

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  1. Samy M. Shaban
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Correspondence to Dong-Hwan Kim.

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11814_2020_542_MOESM1_ESM.pdf

The influence of the Gemini surfactants hydrocarbon tail on in-situ synthesis of silver nanoparticles: Characterization, surface studies and biological performance

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Shaban, S.M., Kim, DH. The influence of the Gemini surfactants hydrocarbon tail on in-situ synthesis of silver nanoparticles: Characterization, surface studies and biological performance. Korean J. Chem. Eng. 37, 1008–1019 (2020). https://doi.org/10.1007/s11814-020-0542-1

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