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Controllable synthesis of ZSM-11/ZSM-5 intergrowth zeolite using 1,3-cyclohexanedimethanamine as organic template

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Abstract

A new organic template, 1,3-cyclohexanedimethanamine (1,3-CDA), is found to be effective in directing the crystallization of ZSM-11 zeolite. Phase transformation from ZSM-11 to ZSM-5 was observed when varying the molar ratios of OH−/SiO2, Na+/SiO2 and SiO2/Al2O3. ZSM-11/ZSM-5 intergrowth zeolites with ZSM-5 contents from 10 to 100% were synthesized. The structural intergrowth was evidenced by TEM, and its formation may be ascribed to the competition between ZSM-11 and ZSM-5 zeolite in the system. The morphology of zeolite varies with the change of composition of the starting gel. The particle sizes of the products decrease with the increase of 1,3-CDA/SiO2 and Na+/SiO2 ratios. With the increase the OH−/SiO2 ratio, the sizes decrease at first and then increase. Meanwhile, the morphologies change from cross-like aggregates of orthotropic rods to aggregates of nano-rods, and then to irregular bulk crystals. With the decrease of SiO2/Al2O3 ratios from 100 to 40, the particle sizes decrease from 200 to about 50 nm, resulting in the formation of nanosized ZSM-11/ZSM-5 intergrowth zeolite.

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Acknowledgements

The authors gratefully acknowledge Dr. Jin-gang Jiang and Dr. Li Chen for their assistance with the NMR and TEM characterization, and Mr. Ruidan Liu for his help with improving the writing.

Funding

This work was supported by the National Key R&D Program of China (2017YFB0702800), the National Natural Science Foundation of China (21503280, 21972168), and China Petrochemical Corporation (Sinopec Group).

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Authors and Affiliations

  1. State Key Laboratory of Green Chemical Engineering and Industrial Catalysis, Sinopec Shanghai Research Institute of Petrochemical Technology, Shanghai, 201208, China

    Zhendong Wang, Yi Luo, Xiangcheng Li & Weimin Yang

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  1. Zhendong Wang
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  2. Yi Luo
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  3. Xiangcheng Li
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  4. Weimin Yang
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Correspondence to Zhendong Wang or Weimin Yang.

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Wang, Z., Luo, Y., Li, X. et al. Controllable synthesis of ZSM-11/ZSM-5 intergrowth zeolite using 1,3-cyclohexanedimethanamine as organic template. J Porous Mater 27, 1329–1337 (2020). https://doi.org/10.1007/s10934-020-00905-0

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