Abstract
Many of oil reservoirs have dealt with operational problems due to probability of asphaltene deposition as a consequence of asphaltene precipitation during natural production and gas injection into the reservoir. So the prediction of asphaltene precipitation is very important and many equations of state (such as Ping Robinson (PR) and Soave–Redlich–Kwong (SRK)) are used for this reason. These common equations are suitable for non-polar components and a modification is necessary to use them for prediction of asphaltene precipitation because of the polar nature of asphaltene compounds. In this study, the SRK equation of state was modified by deriving a new equation for calculating b-parameter (co-volume parameter); and this modified SRK equation of state was used to model asphaltene precipitation. Finally asphaltene precipitation during natural depletion and first stage gas injection process (in different concentrations), was monitored at reservoir temperature and various pressures. The experimental results show a good match with the modified SRK equation of state.
References
Abedini, A., S. Ashoori, F. Torabi, Y. Saki, and N. Dinarvand. 2011. “Mechanism of the Reversibility of Asphaltene Precipitation in Crude Oil.” Petroleum Science and Engineering 78 (2): 316–20.10.1016/j.petrol.2011.07.010Search in Google Scholar
Abouie, A., H. Darabi, and K. Sepehmoori. 2017. “Data-Driven Comparison between Solid Model and PC-SAFT for Modeling Asphaltene Precipitation.” Journal of Natural Gas Science and Engineering 45: 325–37.10.4043/26881-MSSearch in Google Scholar
Adams, J. J. 2014. “Asphaltene Adsorption, a Literature Review.” 2831–56.Search in Google Scholar
Andersen, S. I., and J. G. Speight. 1999. “Thermodynamic Models for Asphaltene Solubility and Precipitation.” Journal of Petroleum Science and Engineering 22: 53–66.10.1016/S0920-4105(98)00057-6Search in Google Scholar
Arya, A., X. Liang, N. Von Solms, and G. M. Kontogeorgis. 2016. “Modeling of Asphaltene Onset Precipitation Conditions with Cubic Plus Association (CPA) and Perturbed Chain Statistical Associating Fluid Theory (PC-SAFT) Equations of State.” Energy & Fuels 30 (8): 6835–52.10.1021/acs.energyfuels.6b00674Search in Google Scholar
Arya, A., X. Liang, N. Von Solms, and G. M. Kontogeorgis. 2017. “Prediction of Gas Injection Effect on Asphaltene Precipitation Onset Using the Cubic and Cubic-Plus-Association Equations of State.” Energy & Fuels 31 (3): 3313–28.10.1021/acs.energyfuels.6b03328Search in Google Scholar
Ashoori, S., A. Abedini, R. Abedini, and N. Olsen. 2010. “Comparison of Scaling Equation with Neural Network Model for Prediction of Asphaltene Precipitation.” Journal of Petroleum Science and Engineering 72 (1): 186–94.10.1016/j.petrol.2010.03.016Search in Google Scholar
Ashoori, S., and A. Balavi. 2014. “An Investigation of Asphaltene Precipitation during Natural Production and the CO2 Injection Process.” Petroleum Science and Technology 32: 1283–90.10.1080/10916466.2011.633590Search in Google Scholar
Baibuz, V. F., V. Yu. Zitserman, L. M. Golubushkin, and I. G. Malyshev. August, 1986. “The Co-Volume and Equation of State of High-Temperature Real Gases.” Academy of Sciences of the USSR, Moscow. Inzhenerno-Fizicheskii Jurnal 51 (2): 273–75. Original article submitted April 23, 1985.10.1007/BF00871197Search in Google Scholar
Banki, R., H. Hoteit, and A. Firoozabadi. 2008. “Mathematical Formulation and Numerical Modeling of Wax Deposition in Pipelines from Enthalpy-Porosity Approach and Irreversible Termodynamics.” International Journal of Heat and Mass Transfer 51: 3387–98.10.1016/j.ijheatmasstransfer.2007.11.012Search in Google Scholar
Cimino, R., S. Correra, P. A. Sacomani, and C. Carniani. 1995 “Thermodynamic Modelling for Prediction of Asphaltene Deposition in Live Oils.” Presented in SPE International Symposium on Oilfield Chemistry, San Antonio, Texas, USA.10.2118/28993-MSSearch in Google Scholar
De Bore, R. B., and K. Leeriooyer. “Screening of Crude Oils for Asphalt Precipitation: Theory, Practice, and Selection of Inhibitors.” SPE 24987, European Petroleum Conference, Cannes, France, November 16–18, 1992.Search in Google Scholar
Eskin, D., J. Ratulowski, K. Akbarzadeh, and S. Pan. 2011. “Modeling of Asphaltene Deposition in Turbulent Pipeline Flows.” The Canadian Journal of Chemical Engineering 89: 3.10.1002/cjce.20507Search in Google Scholar
Forte, E., and S. E. Taylor. 2014. “Thermodynamic Modelling of Asphaltene Precipitation and Related Phenomena.” 1–12.10.1016/j.cis.2014.12.002Search in Google Scholar
Gupta, A. K. 1986 “A Model for Asphaltene Flocculation Using an Equation of State.”Search in Google Scholar
Hammami, A. “Asphaltene Precipitation from Live Oils: an Experimental Investigation of the Onset Conditions and Reversibility.” AIChE Spring National Meeting, Houston, Texas, March 14–18, 1999.10.1021/ef990104zSearch in Google Scholar
Hu, Y.-F., G.-J. Chen, J.-T. Yang, and T.-M. Guo. 2000. “A Study on the Application of Scaling Equation for Asphaltene Precipitation.” Fluid Phase Equilibria 171: 181–95.10.1016/S0378-3812(00)00348-4Search in Google Scholar
Hu, Y.-F., and T.-M. Guo. 2001. “Effect of Temperature and Molecular Weight of N- Alkane Precipitants on Asphaltene Precipitation.” Fluid Phase Equilibria 192: 13–25.10.1016/S0378-3812(01)00619-7Search in Google Scholar
Hustad, O. S., N. Jia, K. S. Pedersen, A. I. Memon, and S. Leekumjorn. 2014. “High Pressure Data and Modeling Results for Phase Behavior and Asphaltene Onsets of GoM Oil Mixed with Nitrogen.” In SPE Annual Technical Conference and Exhibition, New Orleans, Louisiana, USA.10.2118/166097-MSSearch in Google Scholar
IP 143/84. 1989. “Standard Methods for Analysis and Testing of Petroleum and Related Products.”Search in Google Scholar
Jafari Behbahani, T., C. Ghotbi, V. Taghikhani, and A. Shahrabadi. 2011. “Experimental Investigation and Thermodynamic Modeling of Asphaltene Precipitation.” Science Iranian 18 (6): 1384–90.10.1016/j.scient.2011.11.006Search in Google Scholar
Jamaluddin, A. K. M., N. Joshi, S. Iwere, and O. Gurpinar. “An Investigation of Asphaltene Instability under Nitrogen Injection.” SPE Paper No. 74393, SPE International Petroleum Conference and Exhibition, Villahermosa, Mexico, February 10-12-2002.Search in Google Scholar
Li, Z., and A. Firoozabadi. 2010. “Cubic-Plus-Association Equation of State for Asphaltene Precipitation in Live Oils.” Energy & Fuels : an American Chemical Society Journal 24: 2956–63.10.1021/ef9014263Search in Google Scholar
Mansoori, G. A. 1997. “Modeling of Asphaltene and Other Heavy Organic Depositions.” Journal of Petroleum Science and Engineering 17: 101–11.10.1016/S0920-4105(96)00059-9Search in Google Scholar
Nghiem, L. X., D. A. Coombe, and F. Ali. 1998. “Compositional Simulation of Asphaltene Deposition and Plugging.” SPE Paper No. 48996, 73rd Annual Technical Conference and Exhibition, New Orleans, LA, September, 27–30.Search in Google Scholar
Nghiem, L. X., M. S. Hassam, R. Nutakki, and A. E. D. George. 1993. “Efficient Modelling of Asphaltene Precipitation.” Presented in SPE Annual Technical Conference and Exhibition, Houston,Texas, USA.10.2118/26642-MSSearch in Google Scholar
Peramanu, S., C. Singh, M. Agrawala, and H. Yarranton. 2001. “Investigation on the Reversibility of Asphaltene Precipitation.” Energy & Fuels : an American Chemical Society Journal 15: 910–17.10.1021/ef010002kSearch in Google Scholar
Ramos, A. C. S., C. C. Delgado, R. S. Mohamed, V. R. Ameida, and W. Loh. “Reversibility and Inhibition of Asphaltene Precipitation in Brazilian Crude Oils.” SPE Paper No. 38967, 5th Latin American and Caribbean Petroleum Engineering Conference and Exhibition, Rio de Janeiro, Brazil, Agust 30- September 3 1997.Search in Google Scholar
Shadman, M. M., and M. H. Badizad. 2017. “How Much Do You Know about the Methods for Determining Onset of Asphaltene Precipitation?” Petroleum 3,: 287–91.10.1016/j.petlm.2016.08.011Search in Google Scholar
Smith, J. M., H. C. Van Ness, and M. M. Abbott. 1916. Introduction to Chemical Engineering Thermodynamics (McGraw-Hill’s Chemical Engineering Seris).Search in Google Scholar
Soleymanzadeh, A., M. Yousefi, Sh. Kord, and O. Mohammadzadeh. 2018. “A Review on Determining Onset of Asphaltene Precipitation.” Petroleum Exploration and Production Technology 9: 1375–96.10.1007/s13202-018-0533-5Search in Google Scholar
Subramanian, S., S. Simon, and J. Sjoblom. 2016. “Asphaltene Precipitation Models: A Review.” Dispersion Science and Technology 37: 1027–49.10.1080/01932691.2015.1065418Search in Google Scholar
Thomas, F. B., D. B. Bennion, D. W. Bennion, and B. E. Hunter. 1992. “Experimental and Theoretical Studies of Solids Precipitation from Reservoir Fluid.” Canadian Petroleum Technology 31 (01): 22–31.10.2118/92-01-02Search in Google Scholar
Wang, P., F. Zhao, J. Hou, G. Lu, M. Zhang, and Zh. Wang. 2018. “Comparative Analysis of CO2N2and Gas Mixture Injection on Asphaltene Deposition Pressure in Reservoir Conditions.” Energies 11 (9): 2483–97.10.3390/en11092483Search in Google Scholar
Zendehboudi, S., A. Shafiei, A. Bahadori, L. James, A. Elkamel, and A. Lohi. 2014. “Asphaltene Precipitation and Deposition in Oil Reservoirs–Technical Aspects, Experimental and Hybrid Neural Network Predictive Tools.” Chemical Engineering Research and Design 92: 857–75.10.1016/j.cherd.2013.08.001Search in Google Scholar
© 2020 Walter de Gruyter GmbH, Berlin/Boston