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Synthesis, Structure and Photoluminescence Analysis of a Ho3+- cluster-based 3D coordination polymer: {Ho2(H2O)2(DMF)2(ATPA)3}n

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Abstract

A new Ho(III) cluster-based 3D coordination polymer with the formula {Ho2(H2O)2(DMF)2(ATPA)3}n (H2ATPA = 2-Aminoterephthalic acid, DMF = N,N-dimethylformamide), 1, has been successfully synthesized via the hydrothermal method and characterized by elemental analysis, FT-IR, UV, single crystal and powder X-ray diffraction and photoluminescence measurements. Each Holmium atom has a distorted bicapped trigonal prismatic geometry with coordination of eight oxygen atoms. The shifting of the absorption band in the UV–Visible spectrum of 1 indicates the Ho atoms involved in coordination with H2ATPA ligand. Ho(III)-based characteristic narrow strong emission bands due to the f–f transitions of Ho(III) cation have been detected for 1 in the visible region. The emission bands observed at 442 nm and 464 nm are the most severe, so the investigated complex emits the bright-blue light. One can conclude that the energy transfers from the H2ATPA ligand to Ho(III) have been done effectively so that 1 would have the potential applications in the optical amplification field.

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Acknowledgment

This paper has been granted by the Muğla Sıtkı Koçman University Research Projects Coordination Office through Project Grant Number: (17/295). The author is grateful to the Dokuz Eylul University for the use of the Agilent Xcalibur Eos diffractometer and acknowledges Balıkesir University, Science and Technology Application and Research Center (BUBTAM), for the use photoluminescence measurements. The author is very thankful to Dr. Hülya Kara SUBAŞAT, Dr. Uğur ERKARSLAN, Dr. M. Burak ÇOBAN and Dr. Çiğdem Elif DEMİRCİ DÖNMEZ for their helpful and constructive suggestions.

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Dönmez, A. Synthesis, Structure and Photoluminescence Analysis of a Ho3+- cluster-based 3D coordination polymer: {Ho2(H2O)2(DMF)2(ATPA)3}n. J Clust Sci 31, 887–896 (2020). https://doi.org/10.1007/s10876-020-01760-4

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