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EPR Study on the Intercalation of Azoles into Transition Metal Oxides

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Abstract

Four azoles of different chemical structure were intercalated into MoO3, V2O5, and WO3 oxides synthetized via polycondensation of corresponding oxo-acids under the solvothermal conditions. Structural and morphology peculiarities of these hybrid materials were characterized using X-ray and neutron diffraction, electron microscopy and EPR spectroscopy. The EPR measurements provided the evidence that azole molecules coordinate monomers and oligomers of molybdic, tungstic and vanadic acids during the course of solvothermal synthesis of azole-oxide hybrid structures. This coordination is accompanied with reorganization of growing oxide frame leading to the unprecedently high azole loading. As the result, the azole-intercalated layered oxides with high concentration of ordered paramagnetic centers are formed.

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Funding

T.V.S, A.S.L. and D.V.S. acknowledge the support from the Belarusian Republican Foundation for Fundamental Research (Grant Kh19MS-017). A.I.K. and E.A.K. are thankful for the financial support to the Russian Foundation for Basic Research (Grant № 18-53-00020-Bel-a).

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Authors and Affiliations

  1. Physics Department, M.V. Lomonosov Moscow State University, Moscow, Russian Federation

    E. A. Konstantinova

  2. National Research Center “Kurchatov Institute”, Moscow, Russian Federation

    E. A. Konstantinova

  3. N. N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, Moscow, Russian Federation

    A. I. Kokorin & E. N. Degtyarev

  4. Plekhanov Russian University of Economics, Moscow, Russian Federation

    A. I. Kokorin

  5. Chemistry Department, Belarusian State University, Minsk, Republic of Belarus

    A. S. Logvinovich, T. V. Sviridova & D. V. Sviridov

Authors
  1. E. A. Konstantinova
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  2. A. I. Kokorin
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  3. A. S. Logvinovich
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  4. T. V. Sviridova
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  5. E. N. Degtyarev
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  6. D. V. Sviridov
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Contributions

AIK Supervision, validation, writing–reviewing. ASL visualization, investigation. TVS investigation, data curation. YND investigation, software. EAK investigation, editing. DVS conceptualization, methodology, writing–original draft preparation. All authors approve the final version of the manuscript.

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Correspondence to E. A. Konstantinova.

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Konstantinova, E.A., Kokorin, A.I., Logvinovich, A.S. et al. EPR Study on the Intercalation of Azoles into Transition Metal Oxides. Appl Magn Reson 51, 1079–1092 (2020). https://doi.org/10.1007/s00723-020-01205-1

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  • DOI: https://doi.org/10.1007/s00723-020-01205-1

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