Issue 15, 2020

The construction of three C–P bonds of P-stereogenic tertiary phosphines containing (l)-menthyl

Abstract

A wide range of RP or SP-(L)-menthyl-containing SPOs were prepared via the reaction of 1,1′-bi(2-naphthol) derived phosphonite with a metallic reagent with excellent yield and dr. The formation of the P-stereogenic center was controlled by the binaphthol moiety and the products were stereospecifically converted into TPOs under phase transfer conditions.

Graphical abstract: The construction of three C–P bonds of P-stereogenic tertiary phosphines containing (l)-menthyl

Supplementary files

Article information

Article type
Research Article
Submitted
16 Apr 2020
Accepted
26 May 2020
First published
28 May 2020

Org. Chem. Front., 2020,7, 2063-2068

The construction of three C–P bonds of P-stereogenic tertiary phosphines containing (L)-menthyl

J. Ye, B. Yan, J. Wang, J. Wen, Y. Zhang, M. Qiu, Q. Li and C. Zhao, Org. Chem. Front., 2020, 7, 2063 DOI: 10.1039/D0QO00453G

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