Abstract
Oxygenated fuels are of great interest as these are more energy efficient and environment friendly. Therefore, thermodynamic properties like density, ultrasonic speed and refractive indices of diisopropyl ether+benzene+n-hexane mixtures were measured experimentally at 298.15 K, 308.15 K and 318.15 K. Excess properties like volume (\(V_m^E\)), isentropic compressibility (\(K_S^E\)), intermolecular free length (\(L_f^E\)) as well as deviation in ultrasonic speed (Δu) and refractive index (Δn) of these mixtures were derived from experimental data. The \(V_m^E\) values were also fitted to the Singh, Cibulka and Nagata equations, and the same were also predicted using Prigogine-Flory-Patterson theory and four geometrical models from constituent binary \(V_m^E\) data. The u data were correlated by Nomato, van Dael, impedance dependence correlations and CFT theory at 298.15 K. \(L_f^E\) and \(V_a^E\) were also calculated using Jacobson free length theory at 298.15 K. The n data were also predicted by Arago-Biot, Gladstone-Dale, Weiner, Heller, Newton, Eyring and John mixing rules.
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This research was supported by BK21 PLUS (Brain Korea 21 Program) project.
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Gahlyan, S., Devi, R., Verma, S. et al. Measurement and correlation of thermodynamic properties of ternary mixtures of oxygenated fuel. Korean J. Chem. Eng. 37, 1181–1194 (2020). https://doi.org/10.1007/s11814-020-0502-9
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DOI: https://doi.org/10.1007/s11814-020-0502-9