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Mössbauer Probe Diagnostics of the Properties of Quasi-Liquid Water Layer on the Aluminosilicate Surface of Natural Origin

  • PROCEEDINGS OF THE XV INTERNATIONAL CONFERENCE “MÖSSBAUER SPECTROSCOPY AND ITS APPLICATIONS”
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Abstract

The structure and properties of the quasi-liquid water layer in the “frozen water–clay mineral” system have been studied using a probe technique developed on the basis of the 57Fe Mössbauer isotope in two forms (Fe2+ and Fe3+). The elasticity parameters (shear modulus, Poisson’s ratio, and Grüneisen parameter) of the surface ice are estimated within the fractal geometry. The “Menger sponge"–"Cantor dust” transition with an increase in the layer thickness is established.

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Notes

  1. The term is due to the fact that the temperature behavior of the Mössbauer parameters differs from the case of “purely” crystalline phase and is typical of the amorphization onset in crystalline forms of ice.

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  1. Yaroslavl State Technical University, 150999, Yaroslavl, Russia

    A. A. Zalutskii

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Translated by A. Zolot’ko

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Zalutskii, A.A. Mössbauer Probe Diagnostics of the Properties of Quasi-Liquid Water Layer on the Aluminosilicate Surface of Natural Origin. Crystallogr. Rep. 65, 371–375 (2020). https://doi.org/10.1134/S1063774520030360

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