Skip to main content
Log in

Cement-Free Refractory Concretes. Part 2. High-Alumina and Corundum Ceramic Concretes1

  • SCIENTIFIC RESEARCH AND DEVELOPMENT
  • Published:
Refractories and Industrial Ceramics Aims and scope

On the basis of refractory bauxite and very fine quartz glass (VFQG) by means of stagewise combined wet grinding HCBS are prepared having a low moisture content and good binder properties that are achieved due to an optimum content within them of very fine particles (nano-particles and colloidal component). These HCBS are used as a matrix system in the manufacture of many forms of ceramic concrete in the systems Al2O3–SiO2, Al2O3–SiO2–SiC, and Al2O3–SiO2–SiC–C. All of them are distinguished by improved thermomechanical and operating properties. Based on electrocorundum and VFQG similar HCBS and corundum ceramics are prepared (95% Al2O3) with their use. Corundum ceramic concretes are prepared based on a vibration-cast mixture with a moisture content of 3.8% having porosity up to 11% and good strength at elevated temperature.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.
Fig. 6.
Fig. 7.
Fig. 8.
Fig. 9.
Fig. 10.

Similar content being viewed by others

References

  1. I. Allenshtein, Refractory Materials. Structure, Properties, Testing: Handbook [Russian translation], Intermet Inzhiniring, Moscow (2010).

  2. A. P. Luz, M. A. J. Braulio, and V. C. Pandolfelli, Refractory Castable Engineering, Goller Verlag GmbH, Baden-Baden, Germany (2015).

    Google Scholar 

  3. Yu. E. Pivinskii, Unmolded Refractories, in 2 Vol., Vol. 1, General Questions of Technology [in Russian] Teploenergetik, Moscow (2003).

  4. Yu. E. Pivinskii, Ceramics and Refractory Materials, Vol. 2 [in Russian] Stroizdat, St. Petersburg (2003).

  5. Yu. E. Pivinskii, Rheology of Dispersed Systems, HCBS and Ceramic Concretes. Elements of Nanotechnology in Silicate Materials Science [in Russian], Politekhnika, St. Petersburg (2012)

  6. S. Banerjee, Monolithic Refractories - a Comprehensive Handbook. World Scientific, The American Ceramic Society, Singapore (1998).

    Book  Google Scholar 

  7. D. Park, “Cement-free refractory materials based on colloidal- silicic binder,” Novye Ogneupory, No. 9, 36 – 39 (2005).

    Google Scholar 

  8. Yu. E. Pivinskii and M. A. Trubitsy, “Refractory concretes of new generation. General characteristics of the binder systems,” Refractories, 3(11), 673 – 681 (1990).

    Article  Google Scholar 

  9. M. R. Ismael, P. Bonadia, and V. C. Pandofelli, “Thermo-mechanical properties of colloidal silica containing castables,” Refractories Applications and News, 15(1), 19 – 23 (2010).

    CAS  Google Scholar 

  10. Yu. E. Pivinskii, “New refractory concretes and binding systems: Basic trends of development, production, and use of refractories in the XXIst century. Part 1. Trends of development, binding systems,” Refract. Ind. Ceram., 39(1), 39 – 45 (1998).

    Article  CAS  Google Scholar 

  11. I. D. Kashcheev, Refractory Chemical Technology [in Russian], Intermet Inzhiniring, Moscow (2007).

    Google Scholar 

  12. Yu. E. Pivinskii, “Fundamentals of the technology of ceramoconcrete,” Refractories, 19(1), 102 – 111 (1978).

    Article  Google Scholar 

  13. Yu. E. Pivinskii and P. L. Mityakin, “Rheological and binding properties of high-alumina suspensions,” Refractories, 22(3), 292 – 297 (1981).

    Article  Google Scholar 

  14. P. L. Mityakin, Yu. E. Pivinskii, and L. P. Ivanova, “Production and properties of high-alumina ceramic concrete,” Refractories, 23(1/2), 97 – 99 (1982).

    Article  Google Scholar 

  15. Yu. E. Pivinskii, Ceramic Binders and Ceramic Concretes [in Russian], Metallurgiya, Moscow (1990).

    Google Scholar 

  16. E. M. Grishpun and Yu. E. Pivinskii, “Twenty year epoch of cooperation,” Novye Ogneupory, No. 1, 15 – 25 (2007).

    Google Scholar 

  17. E. M. Grishpun and Yu. E. Pivinskii, “HCBS and ceramic concretes — breakthrough in XXI century refractory technology,” Novye Ogneupory, No. 2, 28 – 33 (2002).

    Google Scholar 

  18. Yu. E. Pivinskii and D. A. Dobrodon, “Fabrication and properties of binders for high-alumina suspensions. 1. HCBS based on bauxite,” Refract. Ind. Ceram., 41(5), 205 – 210 (2000).

    Google Scholar 

  19. Yu. E. Pivinskii and D. A. Dobrodon, “Preparation and properties of high-silica suspensions in the bauxite-quartz system,” Novye Ogneupory, No. 5, 10 – 16 (2002).

    Google Scholar 

  20. W. M. Grishpun, A. M. Gorokhovskii, L. A. Karpets, et al., “Production prospects and exploitation of new forms of OAO Dinur refractory,” Novye Ogneupory, No. 4, 100 – 102 (2004).

    Google Scholar 

  21. E. M. Grishpun, A. M. Gorokhovskii, E. V. Beklemyshev, et al., “OAO Dinur refractory objects and mixtures,” Novye Ogneupory, No. 8, 16 – 23 (2011).

    Google Scholar 

  22. A. M. Gorokhovskii, and E. V. Beklemyshev, “OAO Dinur unmolded refractory production,” Novye Ogneupory, No. 11, 15 – 21 (2014).

    Google Scholar 

  23. Yu. E. Pivinskii, E. M. Grishpun, and A. M. Gorokhovskii, “Engineering, manufacturing and servicing of shaped and unshaped refractories based on highly concentrated ceramic binding suspensions,” Refract. Ind. Ceram., 56(3), 245 – 253 (2015).

    Article  CAS  Google Scholar 

  24. Yu. E. Pivinskii and E. I. Suzdal’tsev, Quartz Ceramics and Refractories. Part. 1. Theoretical Baes and Production Processes [in Russian], Teploenergetika, Moscow (2008).

  25. Yu. E. Pivinskii and E. I. Suzdal’tsev, Quartz Ceramics and Refractories. Part. 2. Materials, their Properties, and Fields of Application [in Russian], Teploenergetika, Moscow 2008).

  26. Yu. E. Pivinskii, “Research in the area of preparing materials based on fused quartz HCBS. Part 3. Study and improvement of centrifugal casting,” Refract. Ind. Ceram., 56(2), 126 – 135 (2015).

    Article  CAS  Google Scholar 

  27. Yu. E. Pivinskii, P. V. Dyakin, and V. A. Perepelitsyn, “Research in the field of preparing molded and unmolded refractories based on high-alumina HCBS. Part 1. High-alumina bauxite as a basic raw material component,” Refract. Ind. Ceram., 56(4), 344 – 350 (2015).

    Article  CAS  Google Scholar 

  28. P. Hubert, “Application of a high temperature calcined andalusite in fired bricks and low cement castables,” Taikabutsu Refractories, 57(5), 262 – 268)2005).

  29. E. M. Grischpun, Yu. Å. Pivinskii, E. V. Rozhkov, et al., “Production and service of high-alumina ceramic castables. 1. Ramming mixtures based on modified bauxite HCBS,” Refract. Ind. Ceram., 41(3), 104 – 108 (2000).

    Article  Google Scholar 

  30. E. V. Rozhkov, Yu. E. Pivinskii, M. Z. Naginskii, et al., “Production and service of high-alumina ceramic castables. 2. Properties and service of vibration-placed castables based on bauxite — modified highly concentrated binding suspensions (HCBS) for use in blast-furnace runners,” Refract. Ind. Ceram., 52(5), 209 – 216 (2001).

    Article  Google Scholar 

  31. Yu. E. Pivinskii, P. V. Dyakin., and L. V. Ostryakov, “Research in the field of preparing molded and unmolded refractories based on high-alumina HCBS. Part 14. Composition and some properties of composite composition ceramic concretes in the system Al2O3–SiO2–SiC–C,” Refract. Ind. Ceram., 59(1), 63 – 70 (2018).

    Article  CAS  Google Scholar 

  32. Yu. E. Pivinskii, Quartz Ceramics, HCBS and Ceramic Concretes. Creation History and Technology Development [in Russian], Teploenergetika – Print, St. Petersburg (2018).

  33. Yu. E. Pivinskii and P. V. Dyakin, “Preparation and properties of corundum HCBS and ceramic concretes. Part 1. Mixed HCBS in the system electrocorundum – very fine quartz glass,” Refract. Ind. Ceram., 51(1), 25 – 31 (2010).

    Article  CAS  Google Scholar 

  34. Yu. E. Pivinskii and P. V. Dyakin, “Preparation and properties of corundum HCBS and ceramic concretes. Part 2. Composition and properties of compacted ceramic concretes,” Refract. Ind. Ceram., 51(1), 32 – 38 (2010).

    Article  CAS  Google Scholar 

  35. Yu. E. Pivinskii and P. V. Dyakin, “Preparation and properties of corundum HCBS and ceramic concretes. Part 3. Casting and volume constancy of ceramic concretes,” Refract. Ind. Ceram., 51(1), 88 – 94 (2010).

    Article  CAS  Google Scholar 

  36. Yu. E. Pivinskii, P. V. Dyakin, and A. Yu. Kolobov, “Research in the field of preparing molded and unmolded refractories based on high-alumina HCBS. Part 9. Preparation and properties of mixed HCBS composition: fuzed bauxite-corundum, quartz glass, reactive alumina. Dilatometric study of materials based on them,” Refract. Ind. Ceram., 58(1), 103 – 108 (2017).

    Article  CAS  Google Scholar 

  37. Yu. E. Pivinskii and V. Yu. Belousova, “Materials based on highly concentrated ceramic binding suspensions (HCBS). Corundum- mullite ceramic castables based on plasticized HCBS of bauxite,” Refract. Ind. Ceram., 40(3/4), 391 – 395 (1999).

    Article  CAS  Google Scholar 

  38. Yu. E Pivinskii, E. A. Doroganov, and D. A. Dobrodon, “Materials on basis of highly concentrated ceramic binding suspensions (HCBS). Properties of mixed binders in system of highly concentrated ceramic binding suspensions of mullite highly concentrated very dispersed binding ceramic suspension of quartz glass,” Refract. Ind. Ceram., 38(11), 409 – 413 (1997).

    Article  CAS  Google Scholar 

  39. Yu. E. Pivinskii and P. V. Dyakin, “Alumosilicate refractories based on high-alumina HCBS in the system bauxite – silica,” Refract. Ind. Ceram., 51(5), 358 – 365 (2010).

    Article  Google Scholar 

  40. Yu. E. Pivinskii, D. A. Dobrodon, Yu. N. Ermak, et al., “Effect of thinning on properties of high-alumina castables,” Refract. Ind. Ceram., 45(2), 78 – 84 (2004).

    Article  CAS  Google Scholar 

  41. Yu. E. Pivinskii, E. B. Skorodumova, E. V. Degtyareva, et al., “Evaluation of the production methods and the properties of corundum suspensions,” Refractories, 26(11), 651 – 656 (1985).

    Article  Google Scholar 

  42. Yu. E. Pivinskii, “Phase relationships, important working properties, and classification of ceramic and other bonding systems,” Refractories, 23(5), 97 – 102 (1982).

    Google Scholar 

  43. Yu. E. Pivinskii, “Structural ceramics and technology problems,” in: Chemistry and Technology of Silicate and Refractory Nonmetallic Materials [in Russian], Nauka, Leningrad (1989).

  44. Yu. E. Pivinskii and P. V. Dyakin, “Research in the field of preparing molded and unmolded refractories based on high-alumina HCBS. Part 2. Properties of starting components and castings based on composite composition HCBS. Study of the initial stage of sintering and mullitization,” Refract. Ind. Ceram., 56(5), 544 – 550 (2015).

    Article  Google Scholar 

  45. Yu. E. Pivinskii, P. V. Dyakin, and A. Yu. Kolobov, “Research in the field of preparing molded and unmolded refractories based on high-alumina HCBS. Part 6. Mullitization and thermal expansion of materials based on compound composition HCBS,” Refract. Ind. Ceram., 57(3), 297 – 303 (2016).

    Article  CAS  Google Scholar 

  46. Yu. E. Pivinskii and P. V. Dyakin, “Research in the field of preparing molded and unmolded refractories based on high-alumina HCBS. Part 7. Sintering and secondary mullite formation of material based on composite-composition HCBS during thermal heating and isothermal heating,” Refract. Ind. Ceram., 57(5), 536 – 544 (2016).

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Yu. E. Pivinsky.

Additional information

1Part 1 of the article published in Novye Ogneupory, No. 9 (2019).

Translated from Novye Ogneupory, No. 11, pp. 39 – 48, November, 2019.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Pivinsky, Y.E., Dyakin, P.V., Grishpun, E.M. et al. Cement-Free Refractory Concretes. Part 2. High-Alumina and Corundum Ceramic Concretes1. Refract Ind Ceram 60, 566–573 (2020). https://doi.org/10.1007/s11148-020-00408-0

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11148-020-00408-0

Keywords

Navigation