Issue 26, 2020

Thermally treated zeolitic imidazolate framework-8 (ZIF-8) for visible light photocatalytic degradation of gaseous formaldehyde

Abstract

The development of wide-spectrum responsive photocatalysts for efficient formaldehyde (HCHO) removal is highly desired yet remains a great challenge. Here we successfully converted zeolitic imidazolate framework-8 (ZIF-8), one of the most well-studied metal–organic frameworks (MOFs), from routine ultraviolet-driven to novel broad-spectrum-driven photocatalyst via a facile thermal treatment. The isocyanate groups (–N[double bond, length as m-dash]C[double bond, length as m-dash]O) formed in the thermally treated ZIF-8 (ZIF-8-T) is crucial in enabling the superior photocatalytic performance in formaldehyde degradation. Specifically, the best-performing ZIF-8-T sample showed around 2.1 and 9.4 times the HCHO adsorption amount and the solar photocatalytic degradation rate, respectively, of pristine ZIF-8. In addition, ZIF-8-T exhibited visible light (λ ≥ 400 nm) photocatalytic HCHO degradation performance, photo-converting 72% and nearly 100% of 20 ppm and 10 ppm HCHO within 1 hour, respectively. This work affords new insights and knowledge that inspire and inform the design and development of MOF-based photocatalysts with broad-spectrum responses for efficient air purification operations.

Graphical abstract: Thermally treated zeolitic imidazolate framework-8 (ZIF-8) for visible light photocatalytic degradation of gaseous formaldehyde

Supplementary files

Article information

Article type
Edge Article
Submitted
08 Mar 2020
Accepted
20 May 2020
First published
21 May 2020
This article is Open Access

All publication charges for this article have been paid for by the Royal Society of Chemistry
Creative Commons BY license

Chem. Sci., 2020,11, 6670-6681

Thermally treated zeolitic imidazolate framework-8 (ZIF-8) for visible light photocatalytic degradation of gaseous formaldehyde

T. Wang, Y. Wang, M. Sun, A. Hanif, H. Wu, Q. Gu, Y. S. Ok, D. C. W. Tsang, J. Li, J. Yu and J. Shang, Chem. Sci., 2020, 11, 6670 DOI: 10.1039/D0SC01397H

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

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