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Study of Features of the Composition, Magnetic, and Crystal Structure of Barium Hexaferrite BaFe12 – xTixO19

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Abstract

The features of the composition, crystal, and magnetic structure of Ti-substituted barium hexaferrite BaFe12 – xTixO19 (0.25 ≤ x ≤ 1.5) are studied by Mössbauer spectroscopy, vibration magnetometry, X-ray diffraction, and simultaneous thermal analysis. Bounded heterovalent isomorphism implemented by the scheme 2Fe3+ → Ti4+ + Fe2+ while retaining the charge balance is established when Fe3+ ions are partially substituted with Ti4+ ions. An increase in the 3d-electron density and the presence of Fe2+ in BaFe12 – xTixO19 samples with x = 1.5 is detected by Mössbauer spectroscopy. The heterovalent isomorphic substitution limit is determined to be within 0.75 < x < 1.0. Using Mössbauer spectroscopy and X-ray diffraction, the formation of titanium-contained phases at x = 1.0 whose content increases with the degree of substitution is shown. The data on the preferential distribution of substituent ions (Ti4+) in the barium hexaferrite structure at the 12k and 2b sites are presented.

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Funding

This study was supported by the Russian Science Foundation, agreement no. 19-19-00694, May 6, 2019.

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Authors and Affiliations

  1. National University of Science and Technology MISIS, 119049, Moscow, Russia

    V. V. Korovushkin, A. V. Trukhanov, V. G. Kostishin, I. M. Isaev, I. V. Shchetinin, N. M. Durov, A. Yu. Mironovich & I. O. Minkova

  2. Scientific and Production Center of the National Academy of Sciences of Belarus for Materials Science, 220072, Minsk, Belarus

    A. V. Trukhanov & K. A. Astapovich

Authors
  1. V. V. Korovushkin
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  2. A. V. Trukhanov
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  3. V. G. Kostishin
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  4. I. M. Isaev
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  5. I. V. Shchetinin
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  6. N. M. Durov
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  7. A. Yu. Mironovich
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  8. I. O. Minkova
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  9. K. A. Astapovich
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Corresponding author

Correspondence to A. V. Trukhanov.

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The authors declare that they have no conflicts of interest.

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Translated by A. Kazantsev

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Korovushkin, V.V., Trukhanov, A.V., Kostishin, V.G. et al. Study of Features of the Composition, Magnetic, and Crystal Structure of Barium Hexaferrite BaFe12 – xTixO19. Phys. Solid State 62, 891–901 (2020). https://doi.org/10.1134/S1063783420050145

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