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Fabrication of porous carbon beads from polyacrylonitrile as electrode materials for electric double-layer capacitors

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Abstract

In this study, we developed a facile and template-free strategy for the preparation of activated porous carbon beads (APCBs) from polyacrylonitrile. The chemical activation with KOH was found to enhance the pore properties, such as specific surface area (SSA), pore volume, and pore area. The APCBs exhibited a large SSA of 1147.99 m2/g and a pore area of 131.73 m2/g. The APCB-based electrodes showed a good specific capacitance of 112 F/g at 1 A/g in a 6 M KOH electrolyte, and excellent capacitance retention of 100% at a current density of 5 A/g after 1000 cycles. Therefore, the APCBs prepared in this study can be applied as electrode materials for electric double-layer capacitors.

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Acknowledgements

This work was supported by the Korea Institute of Energy Technology Evaluation and Planning (KETEP) grant funded by the Ministry of Trade, Industry & Energy (MOTIE) of the Republic of Korea (no. 20164010201070) and by the research fund of Chungnam National University.

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  1. Byoung-Min Lee and Beom-Seok Choi contributed equally to this work.

Authors and Affiliations

  1. Department of Polymer Science and Engineering, Chungnam National University, 99 Daehak-ro, Yuseong-gu, Daejeon, 34134, Republic of Korea

    Byoung-Min Lee, Beom-Seok Choi, Jang-Yong Lee, Sung-Kwon Hong & Jae-Hak Choi

  2. Department of Bio-chemical and Polymer Engineering, Chosun University, 309 Pilmun-daero, Dong-gu, Gwangju, 61452, Republic of Korea

    Jung-Soo Lee

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  1. Byoung-Min Lee
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Lee, BM., Choi, BS., Lee, JY. et al. Fabrication of porous carbon beads from polyacrylonitrile as electrode materials for electric double-layer capacitors. Carbon Lett. 31, 67–74 (2021). https://doi.org/10.1007/s42823-020-00150-0

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  • DOI: https://doi.org/10.1007/s42823-020-00150-0

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