Abstract
So far no designated mission to either of the two ice giants, Uranus and Neptune, exists. Almost all of our gathered information on these planets comes from remote sensing. In recent years, NASA and ESA have started planning for future mission to Uranus and Neptune, with both agencies focusing their attention on orbiters and atmospheric probes. Whereas information provided by remote sensing is undoubtedly highly valuable, remote sensing of planetary atmospheres also presents some shortcomings, most of which can be overcome by mass spectrometers. In most studies presented to date a mass spectrometer experiment is thus a favored science instrument for in situ composition measurements on an atmospheric probe. Mass spectrometric measurements can provide unique scientific data, i.e., sensitive and quantitative measurements of the chemical composition of the atmosphere, including isotopic, elemental, and molecular abundances. In this review paper we present the technical aspects of mass spectrometry relevant to atmospheric probes. This includes the individual components that make up mass spectrometers and possible implementation choices for each of these components. We then give an overview of mass spectrometers that were sent to space with the intent of probing planetary atmospheres, and discuss three instruments, the heritage of which is especially relevant to Uranus and Neptune probes, in detail. The main part of this paper presents the current state-of-art in mass spectrometry intended for atmospheric probe. Finally, we present a possible descent probe implementation in detail, including measurement phases and associated expected accuracies for selected species.
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R. Arevalo, J. Danell, R.M. Danell, C. Gundersen, L. Hovmand, A.E. Southard, F. Tan, A. Grubisic, W.B. Brinckerhoff, S. Getty, P.R. Mahaffy, H. Cottin, C. Briois, F. Collin, C. Szopa, V. Vuitton, A. Makarov, M. Reinhardt-Szyba, Advanced Resolution Organic Molecule Analyzer (AROMA): simulations, development and initial testing of a linear ion trap-orbitrap instrument for space, in 3rd International Workshop on Instrumentation for Planetary Missions (2016)
S.K. Atreya, A. Crida, T. Guillot, J.I. Lunine, N. Madhusudhan, O. Mousis, The Origin and Evolution of Saturn, with Exoplanet Perspective. Cambridge Planetary Science (Cambridge University Press, Cambridge, 2018), pp. 5–43. https://doi.org/10.1017/9781316227220.002
S.K. Atreya, M.H. Hofstadter, K. Reh, J.H. In, O. Mousis, M.H. Wong, Icy giant planet exploration: are entry probes essential? Acta Astronaut. 162, 266–274 (2019). https://doi.org/10.1016/j.actaastro.2019.06.020
S.K. Atreya, M.H. Hofstadter, J.H. In, O. Mousis, K. Reh, M.H. Wong, Deep atmosphere composition, structure, origin, and exploration, with particular focus on critical in situ science at the icy giants. Space Sci. Rev. (2020). https://doi.org/10.1007/s11214-020-0640-8
G. Avice, A. Belousov, K.A. Farley, S. Madzunkov, J. Simcic, D. Nikolić, M.R. Darrach, C. Sotin, High-precision measurements of krypton and xenon isotopes with a new static-mode quadrupole ion trap mass spectrometer. J. Anal. At. Spectrom. 34, 104–117 (2019). https://doi.org/10.1039/C8JA00218E
H. Balsiger, P. Eberhardt, J. Geiss, E. Kopp, A mass spectrometer for the simultaneous measurement of the neutral and the ion composition of the upper atmosphere. Rev. Sci. Instrum. 42(4), 475–476 (1971). https://doi.org/10.1063/1.1685134
H. Balsiger, K. Altwegg, P. Bochsler, P. Eberhardt, J. Fischer, S. Graf, A. Jäckel, E. Kopp, U. Langer, M. Mildner, J. Müller, T. Riesen, M. Rubin, S. Scherer, P. Wurz, S. Wüthrich, E. Arijs, S. Delanoye, J.D. Keyser, E. Neefs, D. Nevejans, H. Rème, C. Aoustin, C. Mazelle, J.L. Médale, J.A. Sauvaud, J.J. Berthelier, J.L. Bertaux, L. Duvet, J.M. Illiano, S.A. Fuselier, A.G. Ghielmetti, T. Magoncelli, E.G. Shelley, A. Korth, K. Heerlein, H. Lauche, S. Livi, A. Loose, U. Mall, B. Wilken, F. Gliem, B. Fiethe, T.I. Gombosi, B. Block, G.R. Carignan, L.A. Fisk, J.H. Waite, D.T. Young, H. Wollnik, Rosina – Rosetta Orbiter Spectrometer for Ion and Neutral Analysis. Space Sci. Rev. 128(1), 745–801 (2007). https://doi.org/10.1007/s11214-006-8335-3
S. Barabash, P. Wurz, P. Brandt, M. Wieser, M. Holmström, Y. Futaana, G. Stenberg, H. Nilsson, A. Eriksson, M. Tulej, A. Vorburger, N. Thomas, C. Paranicas, D.G. Mitchell, G. Ho, B.H. Mauk, D. Haggerty, J.H. Westlake, M. Fränz, N. Krupp, E. Roussos, E. Kallio, W. Schmidt, K. Szego, S. Szalai, K. Khurana, X. Jia, C. Paty, R.F. Wimmer-Schweingruber, B. Heber, A. Kazushi, M. Grande, H. Lammer, T. Zhang, S. McKenna-Lawlor, S.M. Krimigis, T. Sarris, D. Grodent, Particle Environment Package (PEP), in European Planetary Science Congress (2013), EPSC2013–709
W.H. Bennett, Radiofrequency mass spectrometer. J. Appl. Phys. 21(2), 143–149 (1950). https://doi.org/10.1063/1.1699613
A. Benninghoven, F.G. Rüdenauer, H.W. Werner, Secondary Ion Mass Spectrometry—Basic Concepts, Instrumental Aspects, Applications and Trends. Surface and Interface Analysis (Wiley, New York, 1987). https://doi.org/10.1002/sia.740100811
J.J. Berthelier, J.M. Illiano, D. Nevejans, E. Neefs, E. Arijs, N. Schoon, High resolution focal plane detector for a space-borne magnetic mass spectrometer. Int. J. Mass Spectrom. 215(1), 89–100 (2002). https://doi.org/10.1016/S1387-3806(02)00527-4
S.J. Bolton, A. Adriani, V. Adumitroaie, M. Allison, J. Anderson, S. Atreya, J. Bloxham, S. Brown, J.E.P. Connerney, E. DeJong, W. Folkner, D. Gautier, D. Grassi, S. Gulkis, T. Guillot, C. Hansen, W.B. Hubbard, L. Iess, A. Ingersoll, M. Janssen, J. Jorgensen, Y. Kaspi, S.M. Levin, C. Li, J. Lunine, Y. Miguel, A. Mura, G. Orton, T. Owen, M. Ravine, E. Smith, P. Steffes, E. Stone, D. Stevenson, R. Thorne, J. Waite, D. Durante, R.W. Ebert, T.K. Greathouse, V. Hue, M. Parisi, J.R. Szalay, R. Wilson, Jupiter’s interior and deep atmosphere: the initial pole-to-pole passes with the Juno spacecraft. Science 356(6340), 821–825 (2017). https://doi.org/10.1126/science.aal2108
A.P. Boss, Giant planet formation by gravitational instability. Science 276(5320), 1836–1839 (1997). www.scopus.com. Cited by :529
A.P. Boss, Formation of planetary-mass objects by protostellar collapse and fragmentation. Astrophys. J. 551(2 PART 2), L167–L170 (2001). www.scopus.com. Cited by :103
C. Briois, R. Thissen, L. Thirkell, K. Aradj, A. Bouabdellah, A. Boukrara, N. Carrasco, G. Chalumeau, O. Chapelon, F. Colin, P. Coll, H. Cottin, C. Engrand, N. Grand, J.P. Lebreton, F.R. Orthous-Daunay, C. Pennanech, C. Szopa, V. Vuitton, P. Zapf, A. Makarov, Orbitrap mass analyser for in situ characterisation of planetary environments: performance evaluation of a laboratory prototype. Planet. Space Sci. 131, 33–45 (2016). https://doi.org/10.1016/j.pss.2016.06.012
T.G. Brockwell, K.J. Meech, K. Pickens, J.H. Waite, G. Miller, J. Roberts, J.I. Lunine, P. Wilson, The mass spectrometer for planetary exploration (MASPEX), in 2016 IEEE Aerospace Conference (2016), pp. 1–17. https://doi.org/10.1109/AERO.2016.7500777
M.V. Buchanan, M.B. Wise, in Fourier Transform Mass Spectrometry Studies of Negative Ion Processes (Am. Chem. Soc., Washington, 1987), pp. 175–191. https://doi.org/10.1021/bk-1987-0359.ch011, Chap. 11
T. Cavalié, O. Venot, M. Yamila, L. Fletcher, P. Wurz, O. Mousis, R. Bounaceur, V. Hue, J. Leconte, M. Dobrijevic, The deep composition of Uranus and Neptune from in situ exploration and thermochemical modeling. Space Sci. Rev. (2020). https://doi.org/10.1007/s11214-020-00677-8
L. Colin, Encounter with Venus: an update. Science 205(4401), 44–46 (1979). https://doi.org/10.1126/science.205.4401.44
R.J. Cotter, Time-of-Flight Mass Spectrometry: Instrumentation and Applications in Biological Research (Am. Chem. Soc., Washington, 1992)
M.R. Darrach, S. Madzunkov, R. Schaefer, D. Nikolic, J. Simcic, K. Richard, E. Neidholdt, M. Pilinski, A. Jaramillo-Botero, K. Farley, The Mass Analyzer for Real-time Investigation of Neutrals at Europa (MARINE), in 2015 IEEE Aerospace Conference (2015), pp. 1–13
P.H. Dawson, Quadrupole Mass Spectrometry and Its Applications (Elsevier, Amsterdam, 1976). https://doi.org/10.1016/C2013-0-04436-2
G. Durry, A. Hauchecorne, J. Ovarlez, H. Ovarlez, I. Pouchet, V. Zeninari, B. Parvitte, In situ measurement of H2O and CH4 with telecommunication laser diodes in the lower stratosphere: dehydration and indication of a tropical air intrusion at mid-latitudes. J. Atmos. Chem. 43(3), 175–194 (2002). https://doi.org/10.1023/A:1020674208207
G. Durry, J. Li, I. Vinogradov, A. Titov, L. Joly, J. Cousin, T. Decarpenterie, N. Amarouche, X. Liu, B. Parvitte, O. Korablev, M. Gerasimov, V. Zéninari, Near infrared diode laser spectroscopy of C2H2, H2O, CO2 and their isotopologues and the application to TDLAS, a tunable diode laser spectrometer for the martian PHOBOS-GRUNT space mission. Appl. Phys. B 99, 339–351 (2010). https://doi.org/10.1007/s00340-010-3924-y
J. Foust, Europa Clipper passes key review. Space News (2019). https://spacenews.com/europa-clipper-passes-key-review/
S.A. Getty, W.B. Brinckerhoff, T. Cornish, S. Ecelberger, M. Floyd, Compact two-step laser time-of-flight mass spectrometer for in situ analyses of aromatic organics on planetary missions. Rapid Commun. Mass Spectrom. 26(23), 2786–2790 (2012). https://doi.org/10.1002/rcm.6393
K.H. Glassmeier, H. Boehnhardt, D. Koschny, E. Kührt, I. Richter, The Rosetta Mission: flying towards the origin of the Solar System. Space Sci. Rev. 128(1–4), 1–21 (2007). https://doi.org/10.1007/s11214-006-9140-8
F. Goesmann, H. Rosenbauer, R. Roll, C. Szopa, F. Raulin, R. Sternberg, G. Israel, U. Meierhenrich, W. Thiemann, G. Munoz-Caro, Cosac, the cometary sampling and composition experiment on philae. Space Sci. Rev. 128(1–4), 257–280 (2007). https://doi.org/10.1007/s11214-006-9000-6
O. Grasset, M.K. Dougherty, A. Coustenis, E.J. Bunce, C. Erd, D. Titov, M. Blanc, A. Coates, P. Drossart, L.N. Fletcher, H. Hussmann, R. Jaumann, N. Krupp, J.P. Lebreton, O. Prieto-Ballesteros, P. Tortora, F. Tosi, T.V. Hoolst, JUpiter ICy moons Explorer (JUICE): an ESA mission to orbit Ganymede and to characterise the Jupiter system. Planet. Space Sci. 78, 1–21 (2013). https://doi.org/10.1016/j.pss.2012.12.002
D. Grinfeld, H. Stewart, M. Skoblin, E. Denisov, M. Monastryrsky, A. Makarov, Space-charge dynamics in Orbitrap mass spectrometers. Int. J. Mod. Phys. A 34(36), 15 (2019). https://doi.org/10.1142/S0217751X19420077
M. Hässig, K. Altwegg, H. Balsiger, J. Berthelier, A. Bieler, U. Calmonte, F. Dhooghe, B. Fiethe, S. Fuselier, S. Gasc, T. Gombosi, L. Le Roy, A. Luspay-Kuti, K. Mandt, M. Rubin, C.Y. Tzou, S. Wampfler, P. Wurz, Isotopic composition of CO2 in the coma of 67P/Churyumov-Gerasimenko measured with ROSINA/DFMS. Astron. Astrophys. 605, A50 (2017). https://doi.org/10.1051/0004-6361/201630140
L. Hofer, P. Wurz, A. Buch, M. Cabane, P. Coll, D. Coscia, M. Gerasimov, D. Lasi, A. Sapgir, C. Szopa, M. Tulej, Prototype of the gas chromatograph - mass spectrometer to investigate volatile species in the lunar soil for the Luna-Resurs mission. Planet. Space Sci. 111, 126–133 (2015)
J.H. Hoffman, R.R. Hodges Jr., D.E. Evans, Lunar orbital mass spectrometer experiment, in Lunar and Planetary Science Conference Proceedings, vol. 3 (1972), p. 2205
J.H. Hoffman, R.R. Hodges, F.S. Johnson, D.E. Evans, Lunar atmospheric composition results from Apollo 17, in Lunar and Planetary Science Conference, vol. 4 (1973), p. 376
M. Hofstadter, A. Simon, K. Reh, J. Elliot, Ice Giant Mission Study Final Report. Tech. Rep., National Aeronautics and Space Administration and Jet Propulsion Laboratory, California Institute of Technology (2017). JPL D-100520
M. Hohl, P. Wurz, S. Scherer, K. Altwegg, H. Balsiger, Mass selective blanking in a compact multiple reflection time-of-flight mass spectrometer. Int. J. Mass Spectrom. 188(3), 189–197 (1999). https://doi.org/10.1016/S1387-3806(99)00040-8
S.M. Hörst, R.V. Yelle, A. Buch, N. Carrasco, G. Cernogora, O. Dutuit, E. Quirico, E. Sciamma-O’Brien, M.A. Smith, Á. Somogyi, C. Szopa, R. Thissen, V. Vuitton, Formation of amino acids and nucleotide bases in a titan atmosphere simulation experiment. Astrobiology 12(9), 809–817 (2012). https://doi.org/10.1089/ast.2011.0623
Q. Hu, R.J. Noll, H. Li, A. Makarov, M. Hardman, R. Graham Cooks, The Orbitrap: a new mass spectrometer. J. Mass Spectrom. 40(4), 430–443 (2005). https://doi.org/10.1002/jms.856
V. Istomin, K. Grechnev, V. Kotchnev, Mass spectrometer measurements of the composition of the lower atmosphere of Venus, in Space Research, ed. by M. Rycroft. COSPAR Colloquia Series, vol. 20 (Pergamon, Elmsford, 1980), pp. 215–218. https://doi.org/10.1016/S0964-2749(13)60044-X
C.Y. Johnson, E.B. Meadows, First investigation of ambient positive-ion composition to 219 km by rocket-borne spectrometer. J. Geophys. Res. 60(2), 193–203 (1955). https://doi.org/10.1029/JZ060i002p00193
J. Kissel, A. Glasmachers, E. Grün, H. Henkel, H. Höfner, G. Haerendel, H. von Hoerner, K. Hornung, E.K. Jessberger, F.R. Krueger, D. Möhlmann, J.M. Greenberg, Y. Langevin, J. Silén, D. Brownlee, B.C. Clark, M.S. Hanner, F. Hoerz, S. Sandford, Z. Sekanina, P. Tsou, N.G. Utterback, M.E. Zolensky, C. Heiss, Cometary and Interstellar Dust Analyzer for comet Wild 2. J. Geophys. Res., Planets 108(E10), 8114 (2003). https://doi.org/10.1029/2003JE002091
D. Krankowsky, P. Lammerzahl, I. Herrwerth, J. Woweries, P. Eberhardt, U. Dolder, U. Herrmann, W. Schulte, J.J. Berthelier, J.M. Illiano, R.R. Hodges, J.H. Hoffman, In situ gas and ion measurements at comet Halley. Nature 321, 326–329 (1986). https://doi.org/10.1038/321326a0
T. Le Barbu, I. Vinogradov, G. Durry, O. Korablev, E. Chassefière, J.L. Bertaux, Tdlas, a diode laser sensor for the in situ monitoring of H2O and CO2 isotopes. in 35th COSPAR Scientific Assembly, vol. 35 (2004), p. 2115
J.P. Lebreton, O. Witasse, C. Sollazzo, T. Blancquaert, P. Couzin, A.M. Schipper, J.B. Jones, D.L. Matson, L.I. Gurvits, D.H. Atkinson, B. Kazeminejad, M. Pérez-Ayúcar, An overview of the descent and landing of the Huygens probe on Titan. Nature 438(7069), 758–764 (2005). https://doi.org/10.1038/nature04347
X. Li, R.M. Danell, V.T. Pinnick, A. Grubisic, F. van Amerom, R.D. Arevalo, S.A. Getty, W.B. Brinckerhoff, A.E. Southard, Z.D. Gonnsen, T. Adachi, Mars organic molecule analyzer (moma) laser desorption/ionization source design and performance characterization. Int. J. Mass Spectrom. 422, 177–187 (2017). https://doi.org/10.1016/j.ijms.2017.03.010
N. Ligterink, A. Riedo, P. Wurz, P. Ehrenfreund, C. Cockell, M. Tulej, V. Grimaudo, R. Lindner, ORIGIN: a novel and compact Laser Desorption - Mass Spectrometry system for sensitive in situ detection of amino acids on extraterrestrial surfaces. Nature Sci. Rep. (2019). https://doi.org/10.7892/boris.135853
R. Lorenz, E. Turtle, J. Barnes, M. Trainer, D. Adams, K. Hibbard, C. Sheldon, K. Zacny, P. Peplowski, D. Lawrence, M. Ravine, T. McGee, K. Sotzen, S. MacKenzie, J. Langelaan, S. Schmitz, L. Wolfarth, P. Bedini, Dragonfly: a rotorcraft lander concept for scientific exploration at titan. Johns Hopkins APL Technical Digest (Applied Physics Laboratory) 34(3), 374–387 (2018)
S.M. Madzunkov, D. Nikolić, Accurate Xe isotope measurement using JPL ion trap. J. Am. Soc. Mass Spectrom. 25, 1841–1852 (2014). https://doi.org/10.1007/s13361-014-0980-2
P.R. Mahaffy, H.B. Niemann, A. Alpert, S.K. Atreya, J. Demick, T.M. Donahue, D.N. Harpold, T.C. Owen, Noble gas abundance and isotope ratios in the atmosphere of Jupiter from the Galileo Probe Mass Spectrometer. J. Geophys. Res. 105(E6), 15,061–15,072 (2000). https://doi.org/10.1029/1999JE001224
P.R. Mahaffy, C.R. Webster, M. Cabane, P.G. Conrad, P. Coll, S.K. Atreya, R. Arvey, M. Barciniak, M. Benna, L. Bleacher, W.B. Brinckerhoff, J.L. Eigenbrode, D. Carignan, M. Cascia, R.A. Chalmers, J.P. Dworkin, T. Errigo, P. Everson, H. Franz, R. Farley, S. Feng, G. Frazier, a. Freissinet, D.P. Glavin, D.N. Harpold, D. Hawk, V. Holmes, C.S. Johnson, A. Jones, P. Jordan, J. Kellogg, J. Lewis, E. Lyness, C.A. Malespin, D.K. Martin, J. Maurer, A.C. McAdam, D. McLennan, T.J. Nolan, M. Noriega, A.A. Pavlov, B. Prats, E. Raaen, O. Sheinman, D. Sheppard, J. Smith, J.C. Stern, F. Tan, M. Trainer, D.W. Ming, R.V. Morris, J. Jones, C. Gundersen, A. Steele, J. Wray, O. Botta, L.A. Leshin, T. Owen, S. Battel, B.M. Jakosky, H. Manning, S. Squyres, R. Navarro-González, C.P. McKay, F. Raulin, R. Sternberg, A. Buch, P. Sorensen, R. Kline-Schoder, D. Coscia, C. Szopa, S. Teinturier, C. Baffes, J. Feldman, G. Flesch, S. Forouhar, R. Garcia, D. Keymeulen, S. Woodward, B.P. Block, K. Arnett, R. Miller, C. Edmonson, S. Gorevan, E. Mumm, The sample analysis at Mars investigation and instrument suite. Space Sci. Rev. 170(1), 401–478 (2012). https://doi.org/10.1007/s11214-012-9879-z
P.R. Mahaffy, M. Benna, T. King, D.N. Harpold, R. Arvey, M. Barciniak, M. Bendt, D. Carrigan, T. Errigo, V. Holmes, C.S. Johnson, J. Kellogg, P. Kimvilakani, M. Lefavor, J. Hengemihle, F. Jaeger, E. Lyness, J. Maurer, A. Melak, F. Noreiga, M. Noriega, K. Patel, B. Prats, E. Raaen, F. Tan, E. Weidner, C. Gundersen, S. Battel, B.P. Block, K. Arnett, R. Miller, C. Cooper, C. Edmonson, J.T. Nolan, The neutral gas and ion mass spectrometer on the Mars atmosphere and volatile evolution mission. Space Sci. Rev. 195(1–4), 49–73 (2015). https://doi.org/10.1007/s11214-014-0091-1
S.M. Maiga, S.M. Gatica, Monolayer adsorption of noble gases on graphene. Chem. Phys. 501, 46–52 (2018). https://doi.org/10.1016/j.chemphys.2017.11.020
A. Makarov, Electrostatic axially harmonic orbital trapping: a high-performance technique of mass analysis. Anal. Chem. 72(6), 1156–1162 (2000)
B.A. Mamyrin, V.I. Karataev, D.V. Shmikk, V.A. Zagulin, The mass-reflectron, a new nonmagnetic time-of-flight mass spectrometer with high resolution. Sov. Phys. JETP 37, 45 (1973)
R. March, R. Hughes, Quadrupole storage mass spectrometry, in Chemical Analysis: A Series of Monographs on Analytical Chemistry and Its Applications, vol. 102 (Wiley, New York, 1989). https://books.google.ch/books?id=FkYaAQAAMAAJ
A. Marshall, V. Verdun, Fourier Transforms in NMR, Optical, and Mass Spectrometry (Elsevier, Amsterdam, 1990)
H. Mizuno, Formation of the giant planets. Prog. Theor. Phys. 64(2), 544–557 (1980). https://doi.org/10.1143/PTP.64.544
R. Moor, E. Kopp, U. Jenzer, H. Ramseyer, U. Waelchli, E. Arijs, D. Nevejans, J. Ingels, D. Fussen, A. Barassin, A double focussing mass-spectrometer for simultaneous ion measurements in the stratosphere, in Presented at the 9th ESA Symposium on European Rocket and Balloon Programs and Related Research (1989), pp. 3–7
P. Moreno-García, V. Grimaudo, A. Riedo, M. Tulej, M.B. Neuland, P. Wurz, P. Broekmann, Towards structural analysis of polymeric contaminants in electrodeposited Cu films. Electrochim. Acta 199, 394–402 (2016). https://doi.org/10.1016/j.electacta.2016.03.123
O. Mousis, L.N. Fletcher, J.P. Lebreton, P. Wurz, T. Cavalié, A. Coustenis, R. Courtin, D. Gautier, R. Helled, P.G.J. Irwin, A.D. Morse, N. Nettelmann, B. Marty, P. Rousselot, O. Venot, D.H. Atkinson, J.H. Waite, K.R. Reh, A.A. Simon, S. Atreya, N. André, M. Blanc, I.A. Daglis, G. Fischer, W.D. Geppert, T. Guillot, M.M. Hedman, R. Hueso, E. Lellouch, J.I. Lunine, C.D. Murray, J. O‘Donoghue, M. Rengel, A. Sánchez-Lavega, F.X. Schmider, A. Spiga, T. Spilker, J.M. Petit, M.S. Tiscareno, M. Ali-Dib, K. Altwegg, S.J. Bolton, A. Bouquet, C. Briois, T. Fouchet, S. Guerlet, T. Kostiuk, D. Lebleu, R. Moreno, G.S. Orton, J. Poncy, Scientific rationale for Saturn’s in situ exploration. Planet. Space Sci. 104, 29–47 (2014). https://doi.org/10.1016/j.pss.2014.09.014
O. Mousis, D.H. Atkinson, R. Ambrosi, S. Atreya, D. Banfield, S. Barabash, M. Blanc, T. Cavalié, A. Coustenis, M. Deleuil, G. Durry, F. Ferri, L. Fletcher, T. Fouchet, T. Guillot, P. Hartogh, R. Hueso, M. Hofstadter, J.P. Lebreton, K.E. Mandt, H. Rauer, P. Rannou, J.B. Renard, A. Sanchez-Lávega, K. Sayanagi, A. Simon, T. Spilker, E. Venkatapathy, J.H. Waite, P. Wurz, In situ Exploration of the Giant Planets, pp. 1–17 (2019). arXiv:1908.00917
H.B. Niemann, D.N. Harpold, S.K. Atreya, G.R. Carignan, D.M. Hunten, T.C. Owen, Galileo Probe Mass Spectrometer experiment. Space Sci. Rev. 60(1–4), 111–142 (1992). https://doi.org/10.1007/BF00216852
H.B. Niemann, S.K. Atreya, G.R. Carignan, T.M. Donahue, J.A. Haberman, D.N. Harpold, R.E. Hartle, D.M. Hunten, W.T. Kasprzak, P.R. Mahaffy, T.C. Owen, N.W. Spencer, S.H. Way, The Galileo Probe Mass Spectrometer: composition of Jupiter’s atmosphere. Science 272(5263), 846–849 (1996). https://doi.org/10.1126/science.272.5263.846
H. Niemann, S. Atreya, G. Carignan, T. Donahue, J. Haberman, D. Harpold, R. Hartle, D. Hunten, W. Kasprzak, P. Mahaffy, T. Owen, N. Spencer, Chemical composition measurements of the atmosphere of Jupiter with the Galileo Probe mass spectrometer. Adv. Space Res. 21(11), 1455–1461 (1998a). https://doi.org/10.1016/S0273-1177(98)00019-2
H.B. Niemann, S.K. Atreya, G.R. Carignan, T.M. Donahue, J.A. Haberman, D.N. Harpold, R.E. Hartle, D.M. Hunten, W.T. Kasprzak, P.R. Mahaffy, T.C. Owen, S.H. Way, The composition of the Jovian atmosphere as determined by the Galileo probe mass spectrometer. J. Geophys. Res. 103(E10), 22,831–22,846 (1998b). https://doi.org/10.1029/98JE01050
H.B. Niemann, S.K. Atreya, S.J. Bauer, K. Biemann, B. Block, G.R. Carignan, T.M. Donahue, R.L. Frost, D. Gautier, J.A. Haberman, D. Harpold, D.M. Hunten, G. Israel, J.I. Lunine, K. Mauersberger, T.C. Owen, F. Raulin, J.E. Richards, S.H. Way, The gas chromatograph mass spectrometer for the Huygens probe. Space Sci. Rev. 104(1), 553–591 (2002). https://doi.org/10.1023/A:1023680305259
H.B. Niemann, S.K. Atreya, S.J. Bauer, G.R. Carignan, J.E. Demick, R.L. Frost, D. Gautier, J.A. Haberman, D.N. Harpold, D.M. Hunten, G. Israel, J.I. Lunine, W.T. Kasprzak, T.C. Owen, M. Paulkovich, F. Raulin, E. Raaen, S.H. Way, The abundances of constituents of Titan’s atmosphere from the GCMS instrument on the Huygens probe. Nature 438(7069), 779–784 (2005). https://doi.org/10.1038/nature04122
H.B. Niemann, S.K. Atreya, J.E. Demick, D. Gautier, J.A. Haberman, D.N. Harpold, W.T. Kasprzak, J.I. Lunine, T.C. Owen, F. Raulin, Composition of Titan’s lower atmosphere and simple surface volatiles as measured by the Cassini-Huygens probe gas chromatograph mass spectrometer experiment. J. Geophys. Res., Planets 115(E12), E12006 (2010)
A.O. Nier, A mass spectrometer for isotope and gas analysis. Rev. Sci. Instrum. 18(6), 398–411 (1947). https://doi.org/10.1063/1.1740961
A.O. Nier, M.B. McElroy, Composition and structure of Mars’ upper atmosphere: results from the neutral mass spectrometers on Viking 1 and 2. J. Geophys. Res. 82(28), 4341–4349 (1977). https://doi.org/10.1029/JS082i028p04341
A.O. Nier, J.H. Hoffman, C.Y. Johnson, J.C. Holmes, Neutral constituents of the upper atmosphere: the minor peaks observed in a mass spectrometer. J. Geophys. Res. 69(21), 4629–4636 (1964). https://doi.org/10.1029/JZ069i021p04629
E.N. Nikolaev, I.A. Boldin, R. Jertz, G. Baykut, Initial experimental characterization of a new ultra-high resolution FTICR cell with dynamic harmonization. J. Am. Soc. Mass Spectrom. 22, 1125–1133 (2011). https://doi.org/10.1007/s13361-011-0125-9
M. Nikolić, Darrach: response of QIT-MS to noble gas isotopic ratios in a simulated venus flyby. Atmosphere 10(5), 232 (2019). https://doi.org/10.3390/atmos10050232
D. Okumura, M. Toyoda, M. Ishihara, I. Katakuse, A compact sector-type multi-turn time-of-flight mass spectrometer ‘multum ii’. Nucl. Instrum. Methods Phys. Res., Sect. A, Accel. Spectrom. Detect. Assoc. Equip. 519(1), 331–337 (2004). https://doi.org/10.1016/j.nima.2003.11.249. Proceedings of the Sixth International Conference on Charged Particle Optics
S. Orsini, S. Livi, K. Torkar, S. Barabash, A. Milillo, P. Wurz, A.M. di Lellis, E. Kallio (SERENA Team), SERENA: a suite of four instruments (ELENA, STROFIO, PICAM and MIPA) on board BepiColombo-MPO for particle detection in the Hermean environment. Planet. Space Sci. 58(1–2), 166–181 (2010). https://doi.org/10.1016/j.pss.2008.09.012
P.T. Palmer, T.F. Limero, Mass spectrometry in the U.S. space program: past, present, and future. J. Am. Soc. Mass Spectrom. 12(6), 656–675 (2001). https://doi.org/10.1021/jasms.8b01630
R. Pappalardo, S. Vance, F. Bagenal, B. Bills, D. Blaney, D. Blankenship, W. Brinckerhoff, J. Connerney, K. Hand, T. Hoehler, J. Leisner, W. Kurth, M. McGrath, M. Mellon, J. Moore, G. Patterson, L. Prockter, D. Senske, B. Schmidt, E. Shock, D. Smith, K. Soderlund, Science potential from a Europa Lander. Astrobiology 13(8), 740–773 (2013). https://doi.org/10.1089/ast.2013.1003. PMID: 23924246
J.B. Pollack, O. Hubickyj, P. Bodenheimer, J.J. Lissauer, M. Podolak, Y. Greenzweig, Formation of the giant planets by concurrent accretion of solids and gas. Icarus 124(1), 62–85 (1996). https://doi.org/10.1006/icar.1996.0190
C. Poole, Gas chromatography, in Handbooks in Separation Science (Elsevier, Amsterdam, 2012). https://books.google.ch/books?id=O77061hwfd4C
A. Riedo, V. Grimaudo, P. Moreno-García, M.B. Neuland, M. Tulej, P. Wurz, P. Broekmann, High depth-resolution laser ablation chemical analysis of additive-assisted Cu electroplating for microchip architectures. J. Anal. At. Spectrom. 30, 2371–2374 (2015). https://doi.org/10.1039/C5JA00295H
A. Riedo, V. Grimaudo, P. Moreno-García, M.B. Neuland, M. Tulej, P. Broekmann, P. Wurz, Laser ablation/ionisation mass spectrometry: sensitive and quantitative chemical depth profiling of solid materials. CHIMIA Int. J. Chem. 70(4), 268–273 (2016). https://doi.org/10.2533/chimia.2016.268
A. Riedo, C. de Koning, A. Stevens, A. McDonald, A.C. Lopez, M. Tulej, P. Wurz, C. Cockell, P. Ehrenfreund, The detection of microbes in Martian mudstone analogues using laser ablation ionization mass spectrometry at high spatial resolution. Astrobiology (2019). https://doi.org/10.7892/boris.135851
M. Rubin, K. Altwegg, H. Balsiger, A. Bar-Nun, J.J. Berthelier, C. Briois, U. Calmonte, M. Combi, J. De Keyser, B. Fiethe, S. Fuselier, S. Gasc, T. Gombosi, K. Hansen, E. Kopp, A. Korth, D. Laufer, L. Le Roy, U. Mall, B. Marty, O. Mousis, T. Owen, H. Rème, T. Sémon, C.Y. Tzou, J. Waite, P. Wurz, Krypton isotopes and noble gas abundances in the coma of comet 67P/Churyumov-Gerasimenko. Sci. Adv. 4, eaar6297 (2018). https://doi.org/10.1126/sciadv.aar6297
M. Rubin, D.V. Bekaert, M.W. Broadley, M.N. Drozdovskaya, S.F. Wampfler, Volatile species in comet 67P/Churyumov-Gerasimenko: investigating the link from the ISM to the terrestrial planets. ACS Earth Space Chem. 3(9), 1792–1811 (2019). https://doi.org/10.1021/acsearthspacechem.9b00096
D.R. Rushneck, A.V. Diaz, D.W. Howarth, J. Rampacek, K.W. Olson, W.D. Dencker, P. Smith, L. McDavid, A. Tomassian, M. Harris, K. Bulota, K. Biemann, A.L. LaFleur, J.E. Biller, T. Owen, Viking gas chromatograph-mass spectrometer. Rev. Sci. Instrum. 49(6), 817–834 (1978). https://doi.org/10.1063/1.1135623
S. Scherer, K. Altwegg, H. Balsiger, J. Fischer, A. Jäckel, A. Korth, M. Mildner, D. Piazza, H. Reme, P. Wurz, A novel principle for an ion mirror design in time-of-flight mass spectrometry. Int. J. Mass Spectrom. 251(1), 73–81 (2006). https://doi.org/10.1016/j.ijms.2006.01.025
R. Schletti, P. Wurz, S. Scherer, O.H. Siegmund, Fast microchannel plate detector with an impedance matched anode in suspended substrate technology. Rev. Sci. Instrum. 72(3), 1634–1639 (2001). https://doi.org/10.1063/1.1344601
I. Schroeder I, K. Altwegg, H. Balsiger, J.J. Berthelier, M. Combi, J. De Keyser, B. Fiethe, S. Fuselier, T. Gombosi, K. Hansen, M. Rubin, Y. Shou, V. Tenishev, T. Sémon, S. Wampfler, P. Wurz, A comparison between the two lobes of comet 67P / Churyumov-Gerasimenko based on D/H ratios in H2O measured with the Rosetta / ROSINA DFMS. Mon. Not. R. Astron. Soc. 489, 4734–4740 (2019a). https://doi.org/10.1093/mnras/stz2482
I. Schroeder I, K. Altwegg, H. Balsiger, J.J. Berthelier, J. De Keyser, B. Fiethe, S. Fuselier, S. Gasc, T. Gombosi, M. Rubin, T. Sémon, C.-Y. Tzou, S. Wampfler, P. Wurz, The \(^{16}{\mathrm{O}}/^{18}{\mathrm{O}}\) ratio in water in the Coma of Comet 67P/Churyumov-Gerasimenko measured with the Rosetta/ROSINA double focusing mass spectrometer. Astron. Astrophys. 630, A29 (2019b). https://doi.org/10.1051/0004-6361/201833806
R. Schulz, J. Benkhoff, BepiColombo: payload and mission updates. Adv. Space Res. 38(4), 572–577 (2006). https://doi.org/10.1016/j.asr.2005.05.084. Mercury, Mars and Saturn
L. Selliez, C. Briois, N. Carrasco, L. Thirkell, R. Thissen, M. Ito, F.R. Orthous-Daunay, G. Chalumeau, F. Colin, H. Cottin, C. Engrand, L. Flandinet, N. Fray, B. Gaubicher, N. Grand, J.P. Lebreton, A. Makarov, S. Ruocco, C. Szopa, V. Vuitton, P. Zapf, Identification of organic molecules with a laboratory prototype based on the laser ablation-cosmorbitrap. Planet. Space Sci. 170, 42–51 (2019). https://doi.org/10.1016/j.pss.2019.03.003
S. Shimma, M. Toyoda, Miniaturized mass spectrometer in analysis of greenhouse gases: the performance and possibilities, in Greenhouse Gases, ed. by G. Liu (IntechOpen, Rijeka, 2012). https://doi.org/10.5772/33815, chap. 11
D.F. Smith, D.C. Podgorski, R.P. Rodgers, G.T. Blakney, C.L. Hendrickson, 21 tesla ft-icr mass spectrometer for ultrahigh-resolution analysis of complex organic mixtures. Anal. Chem. 90(3), 2041–2047 (2018). https://doi.org/10.1021/acs.analchem.7b04159. PMID: 29303558
C. Snodgrass, G.H. Jones, TI - The European Space Agency’s Comet Interceptor lies in wait. Nat. Commun. 10, 5418 (2019). https://doi.org/10.1038/s41467-019-13470-1
M. Toyoda, D. Okumura, M. Ishihara, I. Katakuse, Multi-turn time-of-flight mass spectrometers with electrostatic sectors. J. Mass Spectrom. 38(11), 1125–1142 (2003). https://doi.org/10.1002/jms.546
A.P. Vinogradov, Y.A. Surkov, B.M. Andreichikov, O.M. Kalinkina, I.M. Grechischeva, The chemical composition of the atmosphere of Venus, in Symposium - International Astronomical Union, vol. 40 (1971), pp. 3–16. https://doi.org/10.1017/S0074180900102529
U. Von Zahn, D. Hunten, The Jupiter helium interferometer experiment on the Galileo entry probe. Space Sci. Rev. 60(1–4), 263–281 (1992). https://doi.org/10.1007/BF00216857
U. Von Zahn, D. Hunten, G. Lehmacher, Helium in Jupiter’s atmosphere: results from the Galileo probe helium interferometer experiment. J. Geophys. Res., Planets 103(E10), 22,815–22,829 (1998). https://doi.org/10.1029/98JE00695
S.E. Waller, A. Belousov, R.D. Kidd, D. Nikolić, S.M. Madzunkov, J.S. Wiley, M.R. Darrach, Chemical ionization mass spectrometry: applications for the in situ measurement of nonvolatile organics at ocean worlds. Astrobiology 19(10), 1196–1210 (2019). https://doi.org/10.1089/ast.2018.1961
C.R. Webster, P.R. Mahaffy, G.J. Flesch, P.B. Niles, J.H. Jones, L.A. Leshin, S.K. Atreya, J.C. Stern, L.E. Christensen, T. Owen, H. Franz, R.O. Pepin, A. Steele, Isotope ratios of H, C, and O in CO2 and H2O of the Martian atmosphere. Science 341(6143), 260–263 (2013). https://doi.org/10.1126/science.1237961
M.H. Wong, P.R. Mahaffy, S.K. Atreya, H.B. Niemann, T.C. Owen, Updated Galileo probe mass spectrometer measurements of carbon, oxygen, nitrogen, and sulfur on Jupiter. Icarus 171(1), 153–170 (2004). https://doi.org/10.1016/j.icarus.2004.04.010
I.P. Wright, S.J. Barber, G.H. Morgan, A.D. Morse, S. Sheridan, D.J. Andrews, J. Maynard, D. Yau, S.T. Evans, M.R. Leese, J.C. Zarnecki, B.J. Kent, N.R. Waltham, M.S. Whalley, S. Heys, D.L. Drummond, R.L. Edeson, E.C. Sawyer, R.F. Turner, C.T. Pillinger, Ptolemy—an instrument to measure stable isotopic ratios of key volatiles on a cometary nucleus. Space Sci. Rev. 128(1–4), 363–381 (2007). https://doi.org/10.1007/s11214-006-9001-5
P. Wurz, D. Abplanalp, M. Tulej, H. Lammer, A neutral gas mass spectrometer for the investigation of lunar volatiles. Planet. Space Sci. 74(1), 264–269 (2012). https://doi.org/10.1016/j.pss.2012.05.016
P. Wurz, M. Rubin, K. Altwegg, H. Balsiger, J.J. Berthelier, A. Bieler, U. Calmonte, J. De Keyser, B. Fiethe, S.A. Fuselier, A. Galli, S. Gasc, T.I. Gombosi, A. Jäckel, L. Le Roy, U.A. Mall, H. Rème, V. Tenishev, C.Y. Tzou, Solar wind sputtering of dust on the surface of 67P/Churyumov-Gerasimenko. Astron. Astrophys. 583, A22 (2015). https://doi.org/10.1051/0004-6361/201525980
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A. Vorburger and P. Wurz gratefully acknowledge the financial support by the Swiss National Science Foundation.
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In Situ Exploration of the Ice Giants: Science and Technology
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Vorburger, A., Wurz, P. & Waite, H. Chemical and Isotopic Composition Measurements on Atmospheric Probes Exploring Uranus and Neptune. Space Sci Rev 216, 57 (2020). https://doi.org/10.1007/s11214-020-00684-9
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DOI: https://doi.org/10.1007/s11214-020-00684-9