Skip to main content
Log in

Preparation of TiO2/Ser filler with ultraviolet resistance and antibacterial effects and its application in SBR/TRR blend rubber

  • Original Paper
  • Published:
Journal of Rubber Research Aims and scope Submit manuscript

Abstract

TiO2/sericite (Ser) was prepared by depositing a nano-TiO2 film onto a carrier composed of sericite, an inorganic and nonmetallic mineral. Ultraviolet-resistant and antibacterial layers were then separately loaded onto the nano-TiO2 film, forming a multifunctional composite. The obtained functional TiO2/Ser composite was used as a filler and introduced into a rubber composite. It was indicated that the functional TiO2/Ser composite was straightforward, cost-effective, and easy to prepare under a low temperature. The nano-TiO2 layer exhibited a high loading capacity and was firmly loaded onto the inorganic and nonmetallic mineral carrier. The morphology and structure of the filler were observed using transmission electron microscopy. Moreover, the air permeability, antibacterial, aging-protection, and mechanical properties were measured and analyzed using the functional TiO2/Ser as a filler for SBR/TRR blend rubber. Compared with silica, the TiO2/Ser filler could reduce the material cost and improve the density, antibacterial, aging-protection, and mechanical properties of the SBR/TRR blend rubber.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Scheme 1
Fig. 3
Fig. 4

Similar content being viewed by others

References

  1. Haque MM, Khan A, Umar K et al (2013) Synthesis, characterization and photocatalytic activity of visible light induced Ni-doped TiO2. Energy Environ Focus 2:73–78

    Article  Google Scholar 

  2. Zhang ZZ, Luo ZS, Yang ZP et al (2013) Band-gap tuning of N-doped TiO2 photocatalysts for visible-light-driven selective oxidation of alcohols to aldehydes in water. RSC Adv 3:7215–7218

    Article  CAS  Google Scholar 

  3. Wang B, Ding H (2010) Preparation and characterization of calcined kaolin–TiO2 composites. China Powder Sci Technol 16:22–26

    CAS  Google Scholar 

  4. Asahi R, Morikana T, Ohwaki T et al (2001) Visible-light photocatalysis in nitrogen-doped titanium oxides. Science 293:269–271

    Article  CAS  Google Scholar 

  5. LuJun HE, Zao-yang WU, Yu-cheng ZHENG Zhi-xiang (2010) Preparation of TiO2 film on mica and their photocatalytic activity. Trans Mater Heat Treat 31:19–23

    Google Scholar 

  6. Zhang J, Xu XY, Han S et al (2013) Preliminary discussion on composite coating of TiO2 and SiO2 on sericite and corresponding photocatalytic performance. Min Metallurg Eng 36:102–106

    Google Scholar 

  7. Hou XF, Ding H, Du GX et al (2013) Preparation of sericite/TiO2 composite particle material via mechno-chemistry and its characterization. J Beijing Univ Technol 39:1414–1419

    Google Scholar 

  8. Shanghai World-Prospect Industrial Co., Ltd. (2013) Preparation method and application of an inorganic nonmetal mineral composite material carrying titanium dioxide. China 201110255735.5 [P] 3-22

  9. Ren M, Yin HB, Lu ZZ et al (2010) Evolution of rutile TiO2 coating layers on lamellar sericite surface induced by Sn4+ and the pigmentary properties. Powder Technol 204:249–254

    Article  CAS  Google Scholar 

  10. Ohya T, Ito M, Yamada K et al (2004) Aqueous titanate sols from Ti alkoxide-alpha hydroxycarboxylic acid system and preparation of titania films from the sols. Sol Gel Sci Technol 30:71–81

    Article  CAS  Google Scholar 

  11. Ren M, Yin HB, Lu ZZ et al (2009) Effect of La3+ on evolution of TiO2 coating layers on lamellar sericite and their pigmentary properties. Trans Nonferrous Metals Soc China 19:626–634

    Article  CAS  Google Scholar 

  12. Shi J, Wang XD (2011) Growth of rutile titanium dioxide nanowires by pulsed chemical vapor deposition. Cryst Growth Des 11:949–954

    Article  CAS  Google Scholar 

  13. Prado R, Beobide G, Marcaide A et al (2010) Development of multifunctional sol–gel coatings: antireflection coatings with enhanced self-cleaning capacity. Sol Energy Mater Sol Cells 94:1081–1088

    Article  CAS  Google Scholar 

  14. Sun SM, Li XL, Zheng YY et al (2015) Preparation and properties of modified and emulsified nano montmorillonite asphalt. Mater Rev 29:129–132

    CAS  Google Scholar 

  15. Zhao YW, Zou H, Tian M et al (2015) Study on properties of conductive carbon black/EPDM electromagnetic shielding composites. China Rubber Ind 62:5–9

    Google Scholar 

  16. Weng GW, Nie HK (2009) Testing the physical and mechanical properties of rubber. Chemical Industry Press Co. Ltd, Beijing, pp 124–133

    Google Scholar 

  17. Toshihiko K, Kazuhiko S, Masayasu A et al (2004) Microstructure and hydrogen absorption–desorption properties of Mg–TiFe0.92Mn0.08 composites prepared by wet mechanical milling. J Alloy Compd 375:283–291

    Article  Google Scholar 

  18. Yang J, Mei S, Ferreira JMF (2004) Hydrothermal processing of nanocrtalline anatase films rom tetraethylamonium hydroxide peptized titania sols. J Eur Ceram Soc 2:335–339

    Article  Google Scholar 

  19. Li MM, Wu WJ, Qiao R et al (2016) Ag-decorated Fe3O4@SiO2 core-shell nanospheres: seed-mediated growth preparation and their antibacterial activity during the consecutive recycling. J Alloy Compd 676:113–119

    Article  CAS  Google Scholar 

  20. Han ZZ, Ren LL, Cui ZH et al (2012) Ag/ZnO flower heterostructures as a visible-light driven photocatalyst via surface plasmon resonance. Appl Catal B Environ 126:298–305

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Yunhui Xu.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Xu, Y., Feng, L., Cong, H. et al. Preparation of TiO2/Ser filler with ultraviolet resistance and antibacterial effects and its application in SBR/TRR blend rubber. J Rubber Res 23, 47–55 (2020). https://doi.org/10.1007/s42464-020-00035-x

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s42464-020-00035-x

Keywords

Navigation