Abstract
This paper presents a study of direct conversion of chemical energy into electrical energy during the combustion of a (80Zr + 20CuO)–(LiF + CaF2 + MgF2)–(15Zr + 85CuO) thin three-layer condensed energy system, which is a high-temperature galvanic cell. It is determined that this cell during combustion generates an electric signal with an amplitude of 1.6 V and a half-width of 15 s. Its formation mechanism is proposed. A time-resolving X-ray diffraction method is used to identify the phases formed.
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Yu. G. Morozov, M. V. Kuznetsov, M. D. Nersesyan, and A. G. Merzhanov, “Electrochemical Phenomena in Self-Propagating High-Temperature Synthesis Processes,” Dokl. Akad. Nauk 351 (6), 780–782 (1996).
Yu. G. Morozov, M. V. Kuznetsov, and A. G. Merzhanov, “Electric Fields in the Processes of Self-Propagating High-Temperature Synthesis,” Int. J. SHS 6 (1), 1–13 (1997).
D. B. Dem’yanenko and A. S. Dudyrev, “Electromotive Forces Arising from the Combustion of a Pyrotechnic Mixture of Zirconium Carbide with Sodium Nitrate in a Metal Shell with an Axial Electrode,” in Inf. Bul. USSR Acad. of Sci., No. 5 (121): Direct Conversion of Different Types of Energies into Electrical Energy (1984), pp. 94–100.
A. I. Kirdyashkin, V. L. Polyakov, Yu. M. Maksimov, and V. S. Korogodov, “Specific Features of Electric Phenomena in Self-Propagating High-Temperature Synthesis,” Fiz. Goreniya Vzryva 40 (2), 61–67 (2004) [Combust., Expl., Shock Waves 40 (2), 180–185 (2004)].
I. A. Filimonov and N. I. Kidin, “High-Temperature Combustion Synthesis: Generation of Electromagnetic Radiation and the Effect of External Electromagnetic Fields (Review),” Fiz. Goreniya Vzryva 41 (6), 34–53 (2005) [Combust., Expl., Shock Waves 41 (6), 639–656 (2004)].
D. B. Dem’yanenko, A. S. Dudyrev, and I. M. Egorov, “Mechanism of Formation of Electric Potentials in a Condensed Phase in the Combustion of a Combustible–Oxidizer System,” in Modern Problems of Pyrotechnics, Proc. of the III All-Russian Anniversary Conf., October 20–22, 2004) (Ves’ Sergiev Posad, Sergiev Posad, 2005) [in Russian].
Yu. G. Morozov, M. V. Kuznentsov, and O. V. Belousova, “Generation of Electric Potentials in Heterogeneous Combustion in Systems Containing the Group IV Chemical Elements,” Khim. Fiz. 28 (10), 58–64 (2009).
V. K. Smolyakov, A. I. Kirdishkin, and Yu. M. Maksimov, “Convective Mechanism of the Formation of EMF in the Combustion of Heterogeneous Condensed Systems,” Vychisl. Tekhnol. 6 (2), 358–362 (2001).
V. A. Shcherbakov and V. Yu. Barinov, “Measurement of Thermal Electromotive Force and Determination of Combustion Parameters of a Mixture of 5Ti + 3Si under Quasi-Isostatic Compression,” Fiz. Goreniya Vzryva 53 (2), 39–46 (2017) [Combust., Expl., Shock Waves 53 (2), 157–164 (2017)].
A. V. Poletayev, D. Yu. Kovalev, V. V. Prosyanyuk, et al., “Experimental Investigation of Electrical and Optical Phenomena during Combustion of Two-Layer Energetic Condensed (Zr + CuO + LiF)–(Zr + BaCrO4 + LiF) Systems,” Persp. Mater., No. 3, 73–78 (2015) [Inorg. Mater.: Appl. Res. 6 (5), 542–546 (2015)].
A. V. Poletaev, M. I. Alymov, and S. G. Vadchenko, “Physical Processes in the Combustion of (Zr + CuO + LiF)–(Zr + BaCrO4 + LiF) Energy Condensed Systems,” in Energy Condensed Systems, Proc. of the VII All-Russian Conf., December 17–19, 2014 (Chernogolovka, Dzerzhinsky, 2014).
Handbook on Electrochemistry (Ed. by A. M. Sukhotin) (Khimiya, Leningrad, 1981) [in Russian].
V. L. Ponomarev and D. Yu. Kovalev, “Time-Resolved X-ray Diffraction during Combustion in the Ti–C–B System,” Int. J. SHS 14 (2), 111–117 (2005).
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Original Russian Text © V.Yu. Barinov, D.Yu. Kovalev, S.G. Vadchenko, O.A. Golosova, V.V. Prosyanyuk, I.S. Suvorov, S.V. Gil’bert.
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Barinov, V.Y., Kovalev, D.Y., Vadchenko, S.G. et al. Direct Conversion of Chemical Energy into Electrical Energy in the Combustion of a Thin Three-Layer Charge. Combust Explos Shock Waves 55, 678–685 (2019). https://doi.org/10.1134/S0010508219060078
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DOI: https://doi.org/10.1134/S0010508219060078