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Effects of Co Element on the Structure, Magnetic, and Microwave Absorption Properties of La-Fe-B Alloys

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Abstract

In order to understand the intrinsic properties of high abundance permanent magnet materials, effects of Co element on the structure, magnetic, and microwave absorption properties of La12.5(Fe1-xCox)81.3B6.2 alloys have been investigated with x = 0, 0.1, 0.2, 0.3. The X-ray diffraction results revealed that compounds of La12.5(Fe1-xCox)81.3B6.2 crystallized the Nd2Fe14B-type structure with the space group P42/mnm. The saturation magnetization of the powders increases with the Co content increasing, 97.7 emu/g for x = 0.3. The minimum absorption peak value of La12.5(Fe1-xCox)81.3B6.2 alloy reaches about − 18.69 dB at 10.56 GHz with the matching thickness of 2.5 mm.

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References

  1. Hu, Z.H., Qu, H.J., Zhao, J.Q., et al.: Effect of sintering process on the magnetic and mechanical properties of sintered Nd-Fe-B magnets. J. Magn. Magn. Mater. 368, 54 (2014)

    Article  ADS  Google Scholar 

  2. Sugimoto, S.: Current status and recent topics of rare-earth permanent magnets. J. Phys. D. Appl. Phys. 44, 111 (2011)

    Article  Google Scholar 

  3. Gutfleisch, O., Willard, M.A., Bruck, E., Chen, C.H., Shankar, S.G., Liu, J.P.: Magnetic materials and devices for the 21st century: stronger, lighter, and more energy efficient. Adv. Mater. 23, 821 (2011)

    Article  Google Scholar 

  4. Woodcock, T.G., Zhang, Y., Hrkac, G., et al.: Understanding the microstructure and coercivity of high performance NdFeB-based magnets. Scr. Mater. 67, 537 (2012)

    Article  Google Scholar 

  5. Alam, A., Khan, M., Mccallum, R.W., et al.: Site-preference and valency for rare-earth sites in (R-Ce)2Fe14B magnets[J]. Appl. Phys. Lett. 102, 4176 (2013)

    Article  Google Scholar 

  6. Susner, M.A., Conner, B.S., Saparov, B.I., et al.: Growth and characterization of Ce- substituted Nd2Fe14B single crystals. J. Magn. Magn. Mater. 434, (2015)

  7. Yan, C., Guo, S., Chen, L., et al.: Enhanced temperature stability of coercivity in sintered permanent magnet by substitution of Ce for didymium. IEEE T. Magn. 52, 1 (2016)

    ADS  Google Scholar 

  8. Fan, X., Shuai, G., Kan, C., et al.: Tuning Ce distribution for high performanced Nd-Ce-Fe-B sintered magnets. J. Magn. Magn. Mater. 394, 419 (2016)

    Google Scholar 

  9. Zhou, T.D., Liang, D.F., Deng, L.J., et al.: Electron structure and microwave absorbing ability of flaky FeSiAl powders. J. Mater. Sci. Technol. 27, 170 (2011)

    Article  Google Scholar 

  10. Wei, L., Che, R., Jiang, Y., et al.: Study on preparation and microwave absorption property of the core-nanoshell composite materials doped with La. J. Environ. Sci. 25, 27 (2013)

    Article  Google Scholar 

  11. Xie, W., Cheng, H.F., Chu, Z.Y., et al.: Comparison of hollow-porous and solid carbon fibers as microwave sbsorbents[J]. Adv. Mater. Res. 7, 150 (2011)

    Google Scholar 

  12. Zhang, X.F., Zhang, L.L., Li, Z.B., et al.: Variation of coercivity with Ce content in (Pr, Nd, Ce)2Fe14B sintered magnets. AIP Adv. 7, 056228 (2017)

    Article  ADS  Google Scholar 

  13. Nakayama, T.: Nd-Fe-B anisotropic magnet powders produced by the HDDR process. J. Alloys Compd. 193, 259 (1993)

    Article  Google Scholar 

  14. Pathak, A.K., Khan, M., Gschneidner, K.A., et al.: Cerium: an unlikely replacement of dysprosium in high performance Nd-Fe-B permanent magnets. Adv. Mater. 27, 2663 (2015)

    Article  Google Scholar 

  15. Susner, M.A., Conner, B.S., Saparov, B.I., et al.: Growth and characterization of Ce- substituted Nd2Fe14B single crystals. J. Magn. Magn. Mater. 434, (2015)

  16. Ling, C., Cao, X., Shuai, G., et al.: Coercivity enhancement of Dy-free sintered Nd–Fe–B magnets by grain refinement and induction heat treatment. IEEE T. Magn. 51, 1 (2015)

    Google Scholar 

  17. Xu, Y., Yao, Q., Yang, P., et al.: The effects of La doping on the crystal structure, magnetic, and microwave absorption properties of Nd2Fe14B compound. J. Supercond. Nov. Magn. 1, (2018)

  18. Yao, Q., Shen, Y., Yang, P., et al.: Crystal structure and phase relations of Pr2Fe14B-La2Fe14B system. J. Rare Earths. 34, 1121 (2016)

    Article  Google Scholar 

  19. Arrhenius, G.: X-ray diffraction procedures for polycrystalline and amorphous materials. J. Chem. Educ. 32, (1955)

  20. Zhang, M., Li, Z., Shen, B., et al.: Permanent magnetic properties of rapidly quenched (La, Ce) 2Fe14B nanomaterials based on La–Ce mischmetal. J. Alloys Compd. 144, (2015)

  21. Shoemaker, C.B., Shoemaker, D.P., Fruchart, R.: The structure of a new magnetic phase related to the sigma phase: iron neodymium boride Nd2Fe14B. Acta Crystallogr. C. 40, 1665 (1984)

    Article  Google Scholar 

  22. Slater, J.C.: Atomic radii in crystals. J. Chem. Phys. 41, 3199 (1964)

    Article  ADS  Google Scholar 

  23. Matsuura, Y., Hirosawa, S., Yamamoto, H., et al.: Magnetic properties of the Nd2(Fe1-xCox)14B system. Appl. Phys. Lett. 46, 308 (1985)

    Article  ADS  Google Scholar 

  24. Liu, Z., Lin, W.C., Shih, C.W., et al.: Effect of Co addition on the microstructure and magnetic properties of Nd9.5Febal.CoxNb2.5Zr0.5B15 (x = 0, 10, 20) bulk magnets. J. Alloys Compd. 538, (2012)

  25. Michielssen, E., Sajer, J.M., et al.: Design of lightweight, broad-band microwave absorbers using genetic algorithms. IEEE T. Microw. Theory. 41, 1024 (1993)

    Article  Google Scholar 

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Funding

This work was financially supported by the National Natural Science Foundations of China (No. 51871066, No. 51761007, and No. 2016YFB0700901) and the Guangxi Natural Science Foundation (No. 2016GXNSFGA38001).

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Correspondence to Qingrong Yao.

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Yang, P., Tian, C. & Yao, Q. Effects of Co Element on the Structure, Magnetic, and Microwave Absorption Properties of La-Fe-B Alloys. J Supercond Nov Magn 33, 1125–1128 (2020). https://doi.org/10.1007/s10948-019-05323-1

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  • DOI: https://doi.org/10.1007/s10948-019-05323-1

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