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Development of deep eutectic solvent extraction method for extraction of Zn2+ from powdered milk and baby formula samples and its determination by ICP-OES

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Abstract

In the present study, the deep eutectic solvent-based extraction method has been developed for separation of Zn prior to ICP-OES analysis. Five different choline chloride-based deep eutectic solvents were prepared. The Zn extraction ability of DESs from milk powder and baby formulation samples which contain a high amount of milk protein was investigated. The parameters affecting the extraction efficiency such as the amount and type of solvent, extraction time and ambient temperature were optimized. Oxalic acid-based DES gave the highest yield and reproducible results and appropriate preparation criteria. It is concluded from the results that DES-oxalic can quantitatively extract Zn from milky samples. The analytical parameters such as linear calibration range, limit of detection (4.2 µg L−1) and quantification (14.1 µg L−1) were also calculated. The added-found method is successfully applied to ERM BD 150 standard reference material, and the recovery values and standard deviation values were found between the ranges of 79.4–97.21 µg L−1 and 4.1–6.31 µg L−1, respectively. The method was also applied to real samples, and the recovery values were found between 73 and 106% in the spiked samples.

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Acknowledgements

This study is a part of master’s thesis of Aylin Kurt.

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Authors and Affiliations

  1. Analytical Chemistry Division, Department Basic Pharmaceutical Sciences, Faculty of Pharmacy, Sivas Cumhuriyet University, 58140, Sivas, Turkey

    Aylin Kurt & Esra Bagda

  2. Department of Chemistry, Faculty of Science, Sakarya University, Sakarya, Turkey

    Hüseyin Altundag

Authors
  1. Aylin Kurt
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  2. Esra Bagda
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  3. Hüseyin Altundag
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Correspondence to Esra Bagda.

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Kurt, A., Bagda, E. & Altundag, H. Development of deep eutectic solvent extraction method for extraction of Zn2+ from powdered milk and baby formula samples and its determination by ICP-OES. J IRAN CHEM SOC 17, 1359–1367 (2020). https://doi.org/10.1007/s13738-020-01861-x

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  • DOI: https://doi.org/10.1007/s13738-020-01861-x

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