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Thermodynamic properties of solid solutions in the PbSe—AgSbSe2 system

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Abstract

The results of the study of the PbSe—AgSbSe2 system by measuring the emf of concentration chains with respect to PbSe in a temperature range of 300–450 K are presented. The formation in the system of a wide (37–100 mol.% AgSbSe2) region of solid solutions based on AgSbSe2 is shown. The partial thermodynamic functions of PbSe and lead in the alloys are calculated from the equations of the temperature dependences of the emf. The standard thermodynamic functions of formation and standard entropies of solid solutions (2PbSe)x(AgSbSe2)1−x (x = 0.4, 0.6, 0.8, and 0.9) are calculated by the integration of the Gibbs—Duhem equation over the PbSe—AgSbSe2 section using the literature data on the corresponding thermodynamic data for compounds PbSe and AgSbSe2.

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Authors and Affiliations

  1. M. F. Nagiev Institute of Catalysis and Inorganic Chemistry, National Academy of Sciences of Azerbaijan, 113 prosp. Dzhavida Guseina, AZ1143, Baku, Azerbaijan

    L. F. Mashadiyeva, K. N. Babanly & M. B. Babanly

  2. Baku State University, 23 ul. Khalilova, AZ1148, Baku, Azerbaijan

    Sh. G. Mansimova

  3. Ganja State University, 187 ul. Khatai, AZ2000, Ganja, Azerbaijan

    Yu. A. Yusibov

Authors
  1. L. F. Mashadiyeva
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  2. Sh. G. Mansimova
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  3. K. N. Babanly
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  4. Yu. A. Yusibov
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  5. M. B. Babanly
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Corresponding author

Correspondence to M. B. Babanly.

Additional information

This work was financially supported by the Foundation for Science Development of the President of the Azerbaij an Republic (Grant No. EIF-BGM-4-RFTF-1/2017-21/11/4-M-12).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 0660–0664, April, 2020.

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Mashadiyeva, L.F., Mansimova, S.G., Babanly, K.N. et al. Thermodynamic properties of solid solutions in the PbSe—AgSbSe2 system. Russ Chem Bull 69, 660–664 (2020). https://doi.org/10.1007/s11172-020-2814-7

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  • DOI: https://doi.org/10.1007/s11172-020-2814-7

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