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Fe3O4@Si-MCM-41@EDTA@Ni: as a magnetically recyclable and efficient nano-catalyst in the one-pot clean production of 2‐aryl‐2,3‐dihydroquinazolin‐4(1H)‐ones

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Abstract

Ni-EDTA modified nano-magnetite Fe3O4 with shell silica-MCM-41 (Fe3O4@Si-MCM-41@EDTA@Ni) was designed using a post-grafting process and utilized as an effective, novel, and magnetic heterogeneous recoverable nano-catalyst in the clean production of 2,3-dihydroquinazolin-4(1H)-ones through cyclo-condensation. The structure of nano-catalyst was analyzed by TEM, TGA, XRD, FT-IR, EDS, SEM, VSM, ICP-AES tools and hot filtration test. The heterogeneous nanostructured Fe3O4@Si-MCM-41@EDTA@Ni with the saturation magnetization values 15.2 emu g−1 indicated great recyclability and could be easily reutilized for seven successive times no considerable decrease in its catalytic efficiency and activity. The desirable result was obtained with 1.0 mmol of 2-aminobenzamide and aldehyde in the existence of Fe3O4@MCM-41@APTES@EDTA@Ni (5 mg) and EtOH (4 ml) as clean solvent at reflux. Also, various aldehydes could smoothly participate in the cyclo-condensation reaction and produce quinazoline compounds with good yields %76–95.

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Acknowledgements

We thank a lot the Urmia University Research Council for supporting this work.

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  1. Department of Organic Chemistry, Faculty of Chemistry, Urmia University, Urmia, 57159, Iran

    Khadijeh Ojaghi Aghbash & Nader Noroozi Pesyan

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  1. Khadijeh Ojaghi Aghbash
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Ojaghi Aghbash, K., Noroozi Pesyan, N. Fe3O4@Si-MCM-41@EDTA@Ni: as a magnetically recyclable and efficient nano-catalyst in the one-pot clean production of 2‐aryl‐2,3‐dihydroquinazolin‐4(1H)‐ones. J Porous Mater 27, 1087–1100 (2020). https://doi.org/10.1007/s10934-020-00882-4

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