Abstract
The effects of carbon and nitrogen on hydrogen embrittlement were investigated in stable austenitic stainless steels, Fe-15Cr-15Mn-4Ni-0.3Si with 0.3C or 0.3N (wt.%). The steels were electro-chemically charged under two different conditions and tensile tested at a slow strain rate. Hydrogen degraded the tensile properties in both alloys via different mechanisms. Hydrogen severely weakened the grain boundary strength of the nitrogen-added steel, resulting in early intergranular fracture. Carbon segregation increased the boundary strength, which reduced the extent of hydrogen embrittlement. Moreover, the degree of hydrogen-induced degradation was dependent on the depth of hydrogen penetration. Since the brittle fracture occurred only in the regions penetrated by hydrogen, the embrittlement ratio was not a good criterion to assess the susceptibility of the two steels to hydrogen embrittlement.
Similar content being viewed by others
Change history
13 November 2020
This correction is to correct Fig.��4.
References
C.L. Briant, Metall. Trans. A 10, 181 (1979).
P. Marshall, Austenitic stainless steels: microstructure and mechanical properties (Netherlands: Springer, 1984), pp. 80–139.
H.S. Khatak and B. Raj, Corrosion of Austenitic stainless steels: mechanism, mitigation and monitoring (Netherlands: Elsevier, 2002), pp. 37–73.
M.R. Louthan and R.G. Derrick, Corros. Sci. 15, 565 (1975).
Y. Yagodzinskyy, O. Todoshchenko, S. Papula, and H. Hänninen, Steel Res. Int. 82, 20 (2011).
L. Zhang, Z. Li, J. Zheng, Y. Zhao, P. Xu, C. Zhou, and X. Li, Int. J. Hydrogen Energy 38, 8208 (2013).
M. Koyama, S. Okazaki, T. Sawaguchi, and K. Tsuzaki, Metall. Mater. Trans. A 47, 2656 (2016).
R.P. Reed and M.W. Austin, Scripta Metall. 23, 1359 (1989).
V.G. Gavriljuk, Mater. Sci. Eng. A 438–440, 75 (2006).
K.J. Irvine, T. Gladman, and F.B. Pickering, J. Iron Steel Inst. 119, 1017 (1969).
H.-Y. Ha, T.-H. Lee, C.-S. Oh, and S.-J. Kim, Scripta Mater. 61, 121 (2009).
S.-P. Hannula, H. Hänninen, and S. Tähtinen, Metall. Trans. A 15, 2205 (1984).
P. Rozenak, J. Mater. Sci. 25, 2532 (1990).
C. San Marchi, B.P. Somerday, X. Tang, and G.H. Schiroky, Int. J. Hydrogen Energy 33, 889 (2008).
H.-S. Noh, J.-H. Kang, K.-M. Kim, and S.-J. Kim, Corros. Sci. 124, 63 (2017).
T. Michler, C. San Marchi, J. Naumann, S. Weber, and M. Martin, Int. J. Hydrogen Energy 37, 16231 (2012).
V.G. Gavriljuk, B.D. Shanina, and H. Berns, Acta Mater. 48, 3879 (2000).
L. Cheng, N.M. van der Pers, A. Böttger, ThH de Keijser, and E.J. Mittemeijer, Metall. Trans. A 21, 2857 (1990).
H.M. Ledbetter and M.W. Austin, Mater. Sci. Technol. 3, 101 (1987).
J.M. Papazian and D.N. Besherb, Metall. Trans. 2, 497 (1971).
YuN Petrov, V.G. Gavriljuk, H. Berns, and Ch Escher, Scripta Mater. 40, 669 (1999).
R.K. Dayal and H.J. Grabke, Steel Res. 71, 255 (2000).
S.M. Teus, V.N. Shyvanyuk, and V.G. Gavriljuk, Mater. Sci. Eng. A 497, 290 (2008).
D. Hardie and W. Zheng, Mater. Sci. Technol. 10, 817 (1994).
M. Tanino, H. Komatsu, and S. Funaki, J. Phys. Colloq. 43, 503 (1982).
M. Usui and S. Asano, Scripta Mater. 31, 445 (1994).
A. Macadre, T. Tsuchiyama, and S. Takaki, J. Mater. Sci. 52, 3419 (2017).
G.S. Mogilny, S.M. Teus, V.N. Shyvanyuk, and V.G. Gavriljuk, Mater. Sci. Eng. A 648, 260 (2015).
A.E. Pontini and J.D. Hermida, Scripta Mater. 37, 1831 (1997).
S. Suzuki, M. Obata, K. Abiko, and H. Kimura, Trans. ISIJ 25, 68 (1985).
M. Yamaguchi, Metall. Mater. Trans. A 42, 319 (2011).
M. Kim, C.B. Geller, and A.J. Freeman, Scripta Mater. 50, 1341 (2004).
G.M. Pressouyre, Metall. Trans. A 10, 1571 (1979).
C. SanMarchi, B.P. Somerday, and S.L. Robinson, Int. J. Hydrogen Energy 32, 100 (2007).
A.R. Troiano, Metallogr. Microstruct. Anal. 5, 557 (2016).
R.A. Oriani, Ann. Rev. Mater. Sci. 8, 327 (1978).
Acknowledgement
This work was supported by the National Research Foundation of Korea (NRF) [Research Project No. 2017R1A2B4009780].
Author information
Authors and Affiliations
Corresponding author
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Kim, KS., Kang, JH. & Kim, SJ. Effect of Carbon and Nitrogen on the Hydrogen Embrittlement of 15Cr-15Mn-4Ni-Based Stable Austenitic Stainless Steels. JOM 72, 2011–2019 (2020). https://doi.org/10.1007/s11837-020-04108-5
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11837-020-04108-5