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Investigation of O2 line broadening in nanoporous alumina using gas in scattering media absorption spectroscopy

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Abstract

The broadening of the oxygen absorption line P9P9 due to wall collisions of entrapped oxygen gas in nanoporous solid discs of average pore diameters between 70 and 150 nm is studied using GAs in Scattering Media Absorption Spectroscopy (GASMAS) method. A model based on the kinetic theory of gasses is used to find a correlation between the wall-collision broadening and the average pore diameter measured by Mercury Intrusion Porosimetry (MIP). The shape of the pores of investigated samples is found to be more consistent with a model of pores of cylindrical shapes of heights much larger than their diameters.

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Acknowledgements

The authors would like to acknowledge support by the Deanship of Scientific Research at King Fahd University of Petroleum and Minerals under internal research grants number RG1422-1, RG1422-2, and RG181004.

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Authors and Affiliations

  1. Department of Physics, King Fahd University of Petroleum and Minerals, Dhahran, 31261, Saudi Arabia

    Ahmed Al-Saudi, Abdulaziz Aljalal, Watheq Al-Basheer, Khaled Gasmi & Samer Qari

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  1. Ahmed Al-Saudi
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  2. Abdulaziz Aljalal
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  3. Watheq Al-Basheer
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  4. Khaled Gasmi
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  5. Samer Qari
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Al-Saudi, A., Aljalal, A., Al-Basheer, W. et al. Investigation of O2 line broadening in nanoporous alumina using gas in scattering media absorption spectroscopy. Appl. Phys. B 126, 63 (2020). https://doi.org/10.1007/s00340-020-7404-8

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