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Mn2Cl4 Cluster Based Two-Dimensional Coordination Polymer for Dichromate Sensing Property

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Abstract

The new coordination polymer of {Mn2Cl4(L1)2}n (1, 1′ and 1′′ for different synthesis conditions) [L1 = 1,3,5-tris(4′-pyridyloxadiazole)-2,4,6-triethylbenzene] has been synthesized and characterized by single crystal X-ray diffraction, elemental analysis, infrared spectroscopy and powder X-ray diffraction. As revealed by the single crystal X-ray diffraction, there exist two kinds of L1 ligands and one kind of Mn2Cl4 dimer cluster in complex {Mn2Cl4(L1)2}n. L1 and the Mn2Cl4 dimer form a 3 × 6 two-dimensional layer structure. Each 2D net is composed of Mn2Cl4 linking Mn2-organic cycles. The 2D nets are packed into 3D frameworks through kinds of weak interactions including C-H···N and C-H···Cl hydrogen bonds in the AB fashion. As the assembly reaction can be conducted at room temperature or 90 °C giving rise to 1 and 1′ respectively, the micro-sized products 1′′ can be easily obtained under open solvothermal condition. Finally, the photo-luminescence of the coordination polymer is applied to the harmful dichromate anion sensing in aqueous media. And a fast respond to Cr2O72− at low concentration is realized. The CCDC number of 1 and 1′ are 1977023 and 1977024, respectively.

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References

  1. G.-E. Wang, C. Sun, M.-S. Wang, and G.-C. Guo (2020). Nanoscale. https://doi.org/10.1039/c9nr10164k.

    Article  PubMed  PubMed Central  Google Scholar 

  2. A. Kojima, K. Teshima, Y. Shirai, and T. Miyasaka (2009). J. Am. Chem. Soc. 131, 6050.

    Article  CAS  Google Scholar 

  3. Z. Xiao, R. A. Kerner, N. Tran, L. Zhao, G. D. Scholes, and B. P. Rand (2019). Adv. Funct. Mater. 29, 1807284.

    Article  Google Scholar 

  4. G. Xu, G. C. Guo, J. S. Guo, S. P. Guo, X. M. Jiang, C. Yang, M. S. Wang, and Z. J. Zhang (2010). Dalton Trans. 39, 8688.

    Article  CAS  Google Scholar 

  5. R. Peng, M. Li, and D. Li (2010). Coord. Chem. Rev. 254, 1.

    Article  CAS  Google Scholar 

  6. C. Chen, L. X. Cai, B. Tan, Y. J. Zhang, X. D. Yang, and J. Zhang (2015). Chem. Commun. 51, 8189.

    Article  CAS  Google Scholar 

  7. X. H. Jin, J. K. Sun, L. X. Cai, and J. Zhang (2011). Chem. Commun. 47, 2667.

    Article  CAS  Google Scholar 

  8. C.-W. Zhao, J.-P. Ma, Q.-K. Liu, X.-R. Wang, Y. Liu, J. Yang, J.-S. Yang, and Y.-B. Dong (2016). Chem. Commun. 52, 5238.

    Article  CAS  Google Scholar 

  9. Y. Miao, Y. Ke, N. Wang, W. Zou, M. Xu, Y. Cao, Y. Sun, R. Yang, Y. Wang, Y. Tong, W. Xu, L. Zhang, R. Li, J. Li, H. He, Y. Jin, F. Gao, W. Huang, and J. Wang (2019). Nat. Commun. 10, 3624.

    Article  Google Scholar 

  10. N. Busschaert, C. Caltagirone, W. Van Rossom, and P. A. Gale (2015). Chem. Rev. 115, 8038.

    Article  CAS  Google Scholar 

  11. N. Maximova and O. Dahl (2007). Chem. Soc. Rev. 36, 1323.

    Article  CAS  Google Scholar 

  12. W. P. Lustig, S. Mukherjee, N. D. Rudd, A. V. Desai, J. Li, and S. K. Ghosh (2017). Chem. Soc. Rev. 46, 3242.

    Article  CAS  Google Scholar 

  13. C.-S. Cao, H.-C. Hu, H. Xu, W.-Z. Qiao, and B. Zhao (2016). Cryst. Eng. Commun. 18, 4445.

    Article  CAS  Google Scholar 

  14. X. H. Huang, L. Shi, S. M. Ying, G. Y. Yan, L. H. Liu, Y. Q. Sun, and Y. P. Chen (2018). Cryst. Eng. Commun. 20, 189.

    Article  CAS  Google Scholar 

  15. C. M. Álvarez, L. Álvarez-Miguel, R. García-Rodríguez, J. M. Martín-Álvarez, and D. Miguel (2015). Eur. J. Inorg. Chem. 2015, 4921.

    Article  Google Scholar 

  16. R. Wortmann, U. Flörke, B. Sarkar, V. Umamaheshwari, G. Gescheidt, S. Herres-Pawlis, and G. Henkel (2011). Eur. J. Inorg. Chem. 2011, 121.

    Article  Google Scholar 

  17. C.-W. Zhao, J.-P. Ma, Q.-K. Liu, Y. Yu, P. Wang, Y.-A. Li, K. Wang, and Y.-B. Dong (2013). Green Chem. 15, 3150.

    Article  CAS  Google Scholar 

  18. G. M. Sheldrick (2008). Acta Crystallogr. Sect. A 64, 112.

    Article  CAS  Google Scholar 

  19. J. L. Manson, Q. Z. Huang, C. M. Brown, J. W. Lynn, M. B. Stone, J. Singleton, and F. Xiao (2015). Inorg. Chem. 54, 11897.

    Article  CAS  Google Scholar 

  20. A. V. Artem’ev, M. P. Davydova, A. S. Berezin, V. K. Brel, V. P. Morgalyuk, I. Y. Bagryanskaya, and D. G. Samsonenko (2019). Dalton Trans. 48, 16448.

    Article  Google Scholar 

  21. A. S. Berezin, K. A. Vinogradova, V. A. Nadolinny, T. S. Sukhikh, V. P. Krivopalov, E. B. Nikolaenkova, and M. B. Bushuev (2018). Dalton Trans. 47, 1657.

    Article  CAS  Google Scholar 

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Acknowledgements

This study was supported by National Natural Science Foundation of China (Grant Nos. 51773207, 21574138, 21801213) of China and Jiangxi Provincial Department of Science and Technology (20192ACB20009, 20192BBEL50026).

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Authors and Affiliations

  1. Institute of Applied Chemistry, Jiangxi Academy of Sciences, Nanchang, 330096, People’s Republic of China

    Yuefeng Zhang, Chaowei Zhao, Shengyong You, Jiyong Zou, Nanfu Yan & Weiwei Li

  2. State Key Laboratory of Organic–Inorganic Composites, Beijing University of Chemical Technology, Beijing, 100029, People’s Republic of China

    Weiwei Li

  3. School of Materials and Chemical Engineering, Anhui Jianzhu University, Hefei, 230601, People’s Republic of China

    Jun Zhang

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  1. Yuefeng Zhang
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  2. Chaowei Zhao
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  5. Nanfu Yan
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Correspondence to Chaowei Zhao or Weiwei Li.

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Zhang, Y., Zhao, C., You, S. et al. Mn2Cl4 Cluster Based Two-Dimensional Coordination Polymer for Dichromate Sensing Property. J Clust Sci 32, 235–241 (2021). https://doi.org/10.1007/s10876-020-01781-z

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  • DOI: https://doi.org/10.1007/s10876-020-01781-z

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