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Synthesis and application of carboxyethylthiosuccinic acid by thiol-ene click reaction: as a novel rust remover with corrosion inhibition properties

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Abstract

Carboxyethylthiosuccinic acid (CETSA) was synthesized by thiol-ene click reaction and determined by various characterization methods, such as 1H NMR, IR and TG. A novel rust remover with corrosion inhibition was prepared by using CETSA as the main component. The results of rust removal were tested by the difference method and intuitive comparison method, and its rust removal mechanism was explored. The corrosion inhibition effect of the composite reagent for A3 steel in 1 M HCl solution was investigated by static weight loss test, the adsorption isotherm was calculated and fitted.

Graphic abstract

CETSA was synthesized as a novel rust remover, which removed rust from the metal surface through penetration and chelation. It has excellent rust removal performance and protects the metal from corrosion by forming the adsorption membrane.

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Acknowledgements

This work was supported by Jilin Province Science and Technology Development Plan project (20180201019SF), and the Doctor Startup Foundation of Jilin Institute of Chemical Technology.

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Authors and Affiliations

  1. Jilin Institute of Chemical Technology, Institute of Petrochemical Technology, Jilin, 132022, China

    Huajing Gao, Ning Xie, Jianxin Zhang, Jian Sun & Zhaohui Jin

  2. Yellow River Delta Jingbo Chemical Research Institute Co. Ltd., Shandong, 256500, China

    Jianlin Zhang

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  1. Huajing Gao
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  2. Ning Xie
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  3. Jianxin Zhang
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  4. Jian Sun
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Correspondence to Jian Sun.

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Gao, H., Xie, N., Zhang, J. et al. Synthesis and application of carboxyethylthiosuccinic acid by thiol-ene click reaction: as a novel rust remover with corrosion inhibition properties. J Chem Sci 132, 56 (2020). https://doi.org/10.1007/s12039-020-1756-9

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