Abstract—
Differences between two types of highly differentiated granites of the Salmi batholith: namely Li-siderophyllite topaz-bearing and Li–F topaz-zinnwaldite granites, were determined based on the study of their structural-morphological, mineralogical and geochemical features are determined. The high degree of the differentiation of these granites is confirmed by the presence of primary topaz, Li-micas of magmatic origin and by the presence of significative tetrad effect of M type. These granites are distinguished due to the types of their micas, the content of topaz (up to 1 and 15%, respectively), the morphology of granite intrusions and the geochemistry of rare elements. The Li–F zinnwaldite granites are depleted in REE and enriched in Ta, Hf, Ba, Sr compared to the Li-siderophyllite granites. The Li-siderophyllite granites clearly fit to the general evolution trend of the Salmi batholith granites, while the genesis of Li–F zinnwaldite granites seems to be associated not only with the processes of crystallization differentiation of the melt but also with the active addition of some components, primarily F and Li, probably from a deeper source, including the mantle.
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REFERENCES
A. M. Aksyuk, “Experimentally established geofluorimeters and the fluorine regime in granite–related fluids,” Petrology 10 (6), 557–569 (2002).
Yu. Amelin, A. Beljaev, A. Larin, L. Neymark, and K. Stepanov, Salmi Batholith and Pitkaranta Ore Field in Soviet Karelia, Guide 33, Ed. by I. Haapala, O. T. Ramo, and P. T. Salonsaari (University of Helsinki, 1991).
Yu. V. Amelin, A. M. Larin, and R. D. Tucker, “Chronology of multiphase emplacement of the Salmi rapakivi granite–anorthosite complex, Baltic Shield: implications for magmatic evolution,” Contrib. Mineral. Petrol. 127 (4), 353–368 (1997).
E. Anders and N. Grevesse, “Abundances of the elements: meteoritic and solar,” Geochim. Cosmochim. Acta 53 (1), 197–214 (1989).
A. Beljaev and K. Stepanov, “Internal structure and composition of the Salmi batholith,” Salmi Batholith and Pitkaranta Ore Field in Soviet Karelia, Ed. by I. Haapala, O. T. Ramo, and P. T. Salonsaari, Guide 33. (University of Helsinki, 1991), pp. 8–11.
A. M. Belyaev, “On the problem of genesis of K–feldspar ovoids and porphyritic quartz in rapakivi granite and related rocks, Vestn. St. Peterb. Gos. Univ., Nauki Zemle 62 (1), 3–19 (2017).
A. M. Belyaev and B. K. L’vov, “Mineralogical–geochemical specialization of the granite rapakivi granites of the Salma massif,” Vestn. Lenigrad. Gos. Univ., No. 6, 15–24 (1981).
S. M. Beskin, E. N. Lishnevskii, and M. I. Didenko, “Structure of the Pitkyaranta granite massif in the Northern Ladoga region, Karelia, Izv. Akad. Nauk SSSR, Ser. Geol., No. 3, 19–26 (1983).
A. Ebadi and W. Johannes, “Beginning of melting and composition of first melts in the system Q–Ab–Or–H2O–CO2,” Contrib. Mineral. Petrol. 106, 286–295 (1991).
O. Eklund and A. D. Shebanov, “The origin of rapakivi texture by sub–isothermal decompression,” Precambrian Res. 95 (1–2), 129–146 (1999).
V. A. Glebovitsky, L. S. Egorov, V. V. Zhdanov, et al., Petrographic Code. Magmatic and Metamorphic Rocks (VSEGEI, St. Petersburg, 1995) [in Russian].
E. N. Gramenitsky and T. I. Shchekina, “Behavior of rare earth elements and yttrium during the final differentiation stages of flourine–bearing magmas,” Geochem. Int. 43 (1), 45–59 (2005).
E. N. Gramenitsky, T. I. Shchekina, and S. M. Klyuchareva, “Rare-metal lithium–fluorine granites of the Uksa massif and their place in the formation of the Salma pluton,” Vestn. Mosk. Univ. Ser. 4: Geol., no. 1, 41–49 (1998).
W. Irber, “The lanthanide tetrad effect and its correlation with K/Rb, Eu/Eu*, Sr/Eu, Y/Ho, and Zr/Hf of evolving peraluminous granite suites,” Geochim. Cosmochim. Acta 63 (3/4), 489–508 (1999).
V. I. Ivashchenko and A. I. Golubev, “New aspects of mineralogy and metallogeny of the Pitkyaranta ore region,” Tr. Kar. Nauchn. Ts. Ross. Akad. Nauk, No. 7, 127–148 (2015).
V. I. Ivashchenko, M. Valkama, K. Sundblad, A. I. Golubev, and V. Yu. Alekseev, “New data on mineralogy and metallogeny of scarns in the Pitkyaranta ore region,” Dokl. Earth Sci. 440 (1), 1307–1311 (2011).
V. K. Karandhashev, V. A. Khvostikov, S. Yu. Nosenko, and Z. P. Burmii, “Application of highly enriched stable isotopes in mass analysis of rocks, soils, and bottom sediments by inductively coupled plasma mass spectrometry,” Zavodskaya Lab. Diagnost. Mineral. 82 (7), 6–15 (2016).
R. A. Khazov, Geological Features of Tin Mineralization of the Northern Ladoga Area (Nauka, Leningrad, 1973) [in Russian].
V. I. Kovalenko, P. V. Koval, V. V. Konusova, E. V. Smirnova, and Yu. A. Balashov, “Geochemistry of rare-earth elements in the calc-alkaline intrusive rocks,” Geokhimiya, No. 2, 172–189 (1983).
A. Larin, “Ore mineralization,” Salmi Batholith and Pitkaranta Ore Field in Soviet Karelia, Ed. by I. Haapala, O. T. Ramo, and P. T. Salonsaari, Guide 33 (University of Helsinki, 1991), pp. 19–34.
A. Larin, A. Beljaev, and K. Stepanov, “Geological setting of the Salmi batholith,” Salmi Batholith and Pitkaranta Ore Field in Soviet Karelia, Ed. by I. Haapala, O. T. Ramo, and P. T. Salonsaari, Guide 33. (University of Helsinki, 1991), pp. 6–7.
A. M. Larin, Rapakivi Granites and Associated Rocks (Nauka, St. Petersburg, 2011) [in Russian].
D. A. C. Manning, “The effect of fluorine on liquidus phase relationships in the system Qz–Ab–Or with excess water at 1 kb,” Contrib. Mineral. Petrol. 76, 206–215 (1981).
A. A. Marakushev, R. A. Khazov, Yu. B. Shapovalov, N. I. Bezmen, and G. M. Pavlov, “Nature of layering of lithium–fluorine granites,” Dokl. Akad. Nauk SSSSR, 318 (3), 695–699 (1991).
A. Masuda, O. Kawakami, Y. Dohmoto, and T. Takenaka, “Lanthanide tetrad effects in nature: two mutually opposite types, W and M,” Geochem. J. 21 (3), 119–124 (1987).
L. A. Neymark, Yu. V. Amelin, and A. M. Larin, “Pb-Nd-Sr isotopic and geochemical constraints on the origin of the 1.54–1.56 Ga Salmi rapakivi granite–anorthosite batholith (Karelia, Russia),” Mineral. Petrol. 50, 173–193 (1994).
Zh. D. Nikol’skaya, “New data on the geology and metallogeny of the Salma rapakivi massif, Karelia,” Tr. VSEGEI, Nov. Serii, 230, 52–57 (1975).
G. M. Pavlov, Extended Abstract of Candidate’s Dissertation in Geology and Mineralogy (MGU. Moscow, 1991) [in Russian].
I. S. Peretyazhko and E. A. Savina, “Fluid-magmatic processes during formation of rocks of the Ary-Bulak ongonite massif, Eastern Transbaikalia,” Russ. Geol. Geophys. 51 (10), 1423–1442 (2010a).
I. S. Peretyazhko and E. A. Savina, “Tetrad effects in the rare earth element patterns of granitoid rocks as an indicator of fluoride–silicate liquid immiscibility in magmatic systems,” Petrology 18 (5), 514–543 (2010b).
M. Poutiainen and T. F. Scherbakova, “Fluid and melt inclusion evidence for the origin of idiomorphic quartz crystals in topaz–bearing granite from the Salmi batholith, Karelia, Russia,” Lithos 44, 141–151 (1998).
F. G. Reyf, R. Seltmann, and G. P. Zaraisky “The role of magmatic processes in the formation of banded Li,F–enriched granites from the Orlovka tantalum deposit, Transbaikalia, Russia: Microthermometric evidence,” Can. Mineral. 38, 915–936 (2000).
M. G. Rub, L. N. Khetchikov, Z. A. Kotelnikova, and A. K. Rub, “Inclusions of mineral-forming media in the minerals of the Precambrian tin-bearing granites of the Northern Ladoga area,” Izv. Akad. Nauk SSSR, Ser. Geol., No. 1, 30–36.
Th. G. Sahama, “On the chemistry of the East Fennoscandian Rapakivi Granites,” Bull. Comm. Geol. Finlande 136, 15–67 (1945).
E. V. Sharkov, “Middle-Proterozoic anorthosite–rapakivi granite complexes: An example of within–plate magmatism in abnormally thick crust: evidence from the East European Craton,” Precambrian Res. 183, 689–700 (2010).
A. D. Shebanov, A. M. Belyaev, and V. M. Savatenkov, “The significance of residual source material (restite) in rapakivi granite petrogenesis: an example from Salmi batholith, Russian Karelia,” Symposium on Rapakivi Granites and Related Rocks, Ed. by I. Haapala, O. T. Ramo, and P. Kosunen (University of Helsinki, 1996).
L. P. Sviridenko, “The evolution of the fluid phase during the crystallization of granite types: Salmi pluton, Karelia, Russia,” Mineral. Petrol. 50, 59–67 (1994).
L. P. Sviridenko, Petrology of the Salma Rapakivi Granite Massif in Karelia (Karel’sk. Knizh. Izd-vo, Petrozavodsk, 1968) [in Russian].
O. Trustedt, “Die Erzlagerstaatten von Pitkaranta am Ladoga–See,” Bull. Comm. Geol. Finland 19, (1907).
I. V. Veksler, A. M. Dorfman, M. Kamenetsky, P. Dulski, and D. B. Dingwell, “Partitioning of lanthanides and Y between immiscible silicate and fluoride melts, fluorite and cryolite and the origin of the lanthanide tetrad effect in igneous rocks,” Geochim. Cosmochim. Acta. 69 (11), 2847–2860 (2005).
D. A. Velikoslavinsky, A. P. Birkis, O. A. Bogatikov, et al., Anorthosite–rapakivi granite formation: East European Platform (Nauka, Leningrad, 1978) [in Russian].
J. R. Weidner and R. F. Martin, “Phase equilibria of a fluorine–rich leucogranite from the St. Austell pluton, Cornwall,” Geochim. Cosmochim. Acta. 51, 1591–1597 (1987).
T. A. Yasnygina and S. V. Rasskazov, “Tetrad effect in rare earth element distribution patterns: Evidence from the Paleozoic granitoids of the Oka zone, Eastern Sayan,” Geochem. Int. 46 (8), 814–825 (2008).
G. P. Zaraisky, A. M. Aksyuk, V. N. Devyatova, O. V. Udoratina, and V. Yu. Chevychelov, “Zr/Hf ratio as an indicator of fractionation of rare–metal granites by the example of the Kukulbei complex, Eastern Transbaikalia,” Petrology 16 (7), 710–736 (2008).
ACKNOWLEDGMENTS
The authors thank M.O. Anosova, N.V. Vasil’ev, V.K. Karandashev, E.A. Minervina, A.N. Nekrasov, A.I. Yakushev, and V.O. Yapaskurt for carrying out high-precision analyses. The manuscript was significantly modified and improved thanks to comments and recommendations from V.S. Antipin, T.I. Shchekina, and O.A. Lukanin.
Funding
This study was supported by the Russian Foundation for Basic Research, project nos. 18-05-01101A; 18-05-01001A, and 15-05-03393A.
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Translated by E. Kurdyukov
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Konyshev, A.A., Chevychelov, V.Y. & Shapovalov, Y.B. Two Types of Highly Differentiated Topaz-Bearing Granites of the Salmi Batholith, Southern Karelia. Geochem. Int. 58, 11–26 (2020). https://doi.org/10.1134/S0016702920010073
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DOI: https://doi.org/10.1134/S0016702920010073