Issue 17, 2020

Spin-dependent Schottky barriers and vacancy-induced spin-selective ohmic contacts in magnetic vdW heterostructures

Abstract

2D ferromagnets, such as CrX3 (X = Cl, Br and I), have been attracting extensive attention since they provide novel platforms to fundamental physics and device applications. Integrating CrX3 with other electrodes and substrates is an essential step to their device realization. Therefore, it is important to understand the interfacial properties between CrX3 and other 2D materials. As an illustrative example, we have investigated the heterostructures between CrX3 and graphene (CrX3/Gr) by first-principles calculations. We found a unique Schottky contact type with strongly spin-dependent barriers in CrX3/Gr. This can be understood by synergistic effects between the exchange splitting of the semiconductor band of CrX3 and interlayer charge transfer. The spin-asymmetry of Schottky barriers may result in different tunneling rates of spin-up and down electrons, and then lead to spin-polarized current, namely the spin-filter (SF) effect. Moreover, by introducing X vacancies into CrX3/Gr, an ohmic contact forms in the spin-up direction. It may enhance the transport of spin-up electrons, and improve the SF effect. Our systematic study reveals the unique interfacial properties of CrX3/Gr, and provides a theoretical view of the understanding and designing of spintronic devices based on magnetic vdW heterostructures.

Graphical abstract: Spin-dependent Schottky barriers and vacancy-induced spin-selective ohmic contacts in magnetic vdW heterostructures

Supplementary files

Article information

Article type
Paper
Submitted
04 Mar 2020
Accepted
03 Apr 2020
First published
03 Apr 2020

Phys. Chem. Chem. Phys., 2020,22, 9460-9466

Spin-dependent Schottky barriers and vacancy-induced spin-selective ohmic contacts in magnetic vdW heterostructures

H. Li, Y. Xu, Z. Cheng, B. He and W. Zhang, Phys. Chem. Chem. Phys., 2020, 22, 9460 DOI: 10.1039/D0CP01014F

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