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Surface Modification of Ultradisperse Diamonds by Vacuum Heat Treatment

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Journal of Applied Spectroscopy Aims and scope

The effect of vacuum annealing temperature at 10–2 Pa on the surface structure and functionality of ultradisperse diamond (UDD) produced by detonation synthesis was studied using Raman scattering, IR absorption, x-ray diffraction, and electron paramagnetic resonance techniques. Vacuum annealing at ≤750oC did not affect the structure of diamond nanoparticles although amorphous sp2-hybridized carbon began to form on the particle surfaces at higher temperatures. The UDD surface was completely graphitized and the diamond structure of the particle nucleus was preserved after annealing at 1050oC. Very few functional groups were observed on the UDD surface after annealing at 660–750oC so that the surface remained highly active.

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Authors and Affiliations

  1. A. N. Sevchenko Research Institute of Applied Physics Problems, Belarusian State University, 220045, Minsk, Belarus

    G. A. Gusakov, A. P. Lugovski, M. P. Samtsov & I. I. Azarko

  2. Republican Human Problems Center, Belarusian State University, Minsk, Belarus

    A. A. Lugovski & V. A. Parhomenko

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  1. G. A. Gusakov
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  2. A. A. Lugovski
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  3. A. P. Lugovski
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  4. M. P. Samtsov
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  5. V. A. Parhomenko
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  6. I. I. Azarko
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Correspondence to G. A. Gusakov.

Additional information

Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 87, No. 1, pp. 33–42, January–February, 2020.

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Gusakov, G.A., Lugovski, A.A., Lugovski, A.P. et al. Surface Modification of Ultradisperse Diamonds by Vacuum Heat Treatment. J Appl Spectrosc 87, 26–34 (2020). https://doi.org/10.1007/s10812-020-00958-8

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  • DOI: https://doi.org/10.1007/s10812-020-00958-8

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