Skip to main content
Log in

RETRACTED ARTICLE: Bioactivity measurement of commercially pure titanium processed by micro-electric discharge drilling

  • ORIGINAL ARTICLE
  • Published:
The International Journal of Advanced Manufacturing Technology Aims and scope Submit manuscript

This article was retracted on 21 September 2023

This article has been updated

Abstract

The surface modification is a pivotal step in the field of the biomedical implant in order to improve its biomedical characteristics. A number of methods can be adopted to improve surface characteristics like coating, evaporation, sputtering, and ion implantation. The surface of any material can also be improved by machining. In the present work, an electric discharge drilling (EDD) was used for the development of quality holes on any conductive material regardless of its hardness. In the present research, commercially pure titanium (CPTi) was drilled for the development of microhole using the EDD. The effect of microholes on the apatite formation and weight gain was determined. The apatite formation was measured in the presence of simulated body fluid (SBF) after 7, 14, and 21 days of immersion. The temperature and pH during the apatite formation were 37 °C and 7.4, respectively. It was found that after the development of microholes, the quantity of apatite formation increases. On the contrary side on the normal CPTi material (without drilling), an insignificant apatite formation was observed. However, after drilling, the elements of calcium and phosphate were observed ever after 4 days of immersion in SBF. The surface area of the apatite formation increases by 24% after the development of microholes. Scanning electron microscopy (SEM) revealed the microstructure of the drilled surface before and after the immersion of CPTi in SBF. In addition, it was observed that with the increase in the number of holes and immersion period, the apatite formation increases.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

Similar content being viewed by others

Change history

  • 05 August 2020

    EDITOR'S NOTE: The Editorial team is currently investigating questions raised about figures presented in the Article. We will update readers once we have further information and all parties have been given an opportunity to respond in full.

  • 21 September 2023

    This article has been retracted. Please see the Retraction Notice for more detail: https://doi.org/10.1007/s00170-023-12363-4

References

  1. McGeough JA (1988) Advanced methods of machining. Chapman and Hall, London

    Google Scholar 

  2. Leigh EP, Schuller JK, Smith S (2000) Advanced machining techniques on titanium rotor parts. In: 56th annual forum, American Helicopter Society, Virginia Beach, Virginia, USA

  3. Donachie MJ (2000) Titanium: a technical guide, 2nd edn. ASM international, USA

    Book  Google Scholar 

  4. Yang X, Liu CR (1998) Machining titanium and its alloys. JMach Sci Technol 3:107–139

    Google Scholar 

  5. Jeelani S (1983) Subsurface plastic deformation in machining 6Al-2Sn-4Zr-2Mo titanium alloy. Wear 85:121–130

    Article  Google Scholar 

  6. Sarkar S, Sekh M, Mitra S, Bhattacharyya B (2008) Modelling and optimization of wire electrical discharge machining of γ -TiAl in trim cutting operation. J Mater Process Technol 205:376–387

    Article  Google Scholar 

  7. Yan WQ, Nakamura T, Kobayashi M, Kim HM, Miyaji F, Kokubo T (1997) Bonding of chemically treated titanium implants to bone. J Biomed Mater Res 37:267–275

    Article  Google Scholar 

  8. Hacking SA, Tanzer M, Harvey EJ, Krygier JJ, Bobyn JD (2002) Relative contributions of chemistry and topography to the osseointegration of hydroxyapatite coatings. Clin Orthop Relat Res 405:24–38

    Article  Google Scholar 

  9. Kokubo T, Pattanayak DK, Yamaguchi S, Takadama H, Matsushita T, Kawai T, Takemoto M, Fujibayashi S, Nakamura T (2010) Positively charged bioactive Ti metal prepared by simple chemical and heat treatments. J R Soc Interface 7:S503

    Article  Google Scholar 

  10. Wang XX, Hayakawa S, Tsuru K, Osaka A (2002) Bioactive titania gel layers formed by chemical treatment of Ti substrate with a H2O2/HCl solution. Biomaterials 23:1353–1357

    Article  Google Scholar 

  11. Lu X, Zhao Z, Leng Y (2007) Biomimetic calcium phosphate coatings on nitric acid treated titanium surfaces. Mater Sci Eng C 27:700–708

    Article  Google Scholar 

  12. Wu JM, Hayakawa S, Tsuru K, Osaka A (2004) Low temperature preparation of anatase and rutile layers on titanium substrates and their ability to induce in vitro apatite deposition. J Am Ceram Soc 87:1635–1642

    Article  Google Scholar 

  13. Kokubo T, Takadama H (2006) How useful is SBF in predicting in vivo bone bioactivity? Biomaterials 27:2907–2915

    Article  Google Scholar 

  14. Hashimoto M, Hayashi K, Kitaoka S (2013) Enhanced apatite formation on Ti metal heated in PO2-controlled nitrogen atmosphere. Mater Sci Eng C 33:4155–4159

    Article  Google Scholar 

  15. Uetsuki K, Nakai S, Shirosaki Y, Hayakawa S, Osaka A (2013) Nucleation and growth of apatite on an anatase layer irradiated with UV light under different environmental conditions. J Biomed Mater Res Part A 101A:712–719

    Article  Google Scholar 

  16. Ferraris S, Spriano S, Pan G, Venturello A, Bianchi CL, Chiesa R, Faga MG, Maina G, Verne E (2011) Surface modification of Ti–6Al–4V alloy for biomineralization and specific biological response: part I, inorganic modification. J Mater Sci Mater Med 22:533–545

    Article  Google Scholar 

  17. Hascalık A, Caydas U (2007) A comparative study of surface integrity of Ti–6Al–4V alloy machined by EDM and AECG. J Mater Process Technol 190(1–3):173–180

    Article  Google Scholar 

  18. Hascalık A, Caydas U (2007) Electrical discharge machining of titanium alloy (Ti–6Al–4V). Appl Surf Sci 253(22):9007–9016

    Article  Google Scholar 

  19. Lin YC, Yan BH, Chang YS (2000) Machining characteristics of titanium alloy (Ti-6Al-4V) using a combination process of EDM with USM. J Mater Process Technol 104(3):171–177

    Article  Google Scholar 

  20. Alias A, Abdullah B, Abbas NM (2012) Influence of machine feed rate in WEDM of titanium Ti-6Al-4V with constant current (6a) using brass wire. Procedia Eng 41:1806–1811

    Article  Google Scholar 

  21. Sivaprakasam P, Hariharan P, Gowri S (2014) Modeling and analysis of micro-WEDM process of titanium alloy (Ti-6Al-4V) using response surface approach. Int J Eng Sci Technol 17:227–235

    Google Scholar 

  22. Kolli M, Kumar A (2015) Effect of dielectric fluid with surfactant and graphite powder on electrical discharge machining of titanium alloy using Taguchi method. Int J Eng Sci Technol 18(4):524–535

    Google Scholar 

  23. Khan MAR, Rahman MM, Kadirgama K (2015) An experimental investigation on surface finish in die-sinking EDM of Ti-5Al-2.5Sn. Int J Adv Manuf Technol 77(9):1727–1740

    Article  Google Scholar 

  24. Kao JY, Tsao CC, Wang SS, Hsu CY (2010) Optimization of the EDM parameters on machining Ti-6Al-4V with multiple quality characteristics. Int J Adv Manuf Technol 47(1):395–402

    Article  Google Scholar 

  25. Tiwary AP, Pradhan BB, Bhattacharyya B (2015) Study on the influence of micro-EDM process parameters during machining of Ti–6Al–4V superalloy. Int J Adv Manuf Technol 76(1):151–160

    Article  Google Scholar 

  26. Altug M, Erdem M, Ozay C (2015) Experimental investigation of kerf of Ti6Al4V exposed to different heat treatment processes in WEDM and optimization of parameters using genetic algorithm. Int J Adv Manuf Technol 78(9):1573–1583

    Article  Google Scholar 

  27. Gill RS, Kumar K, Batra U (2017) Apatite formation and weight loss study in EDMed perforated AZ31 Mg-alloy. J Magnes Alloy 5:362–367

    Article  Google Scholar 

  28. Yang Z, Si S, Zeng X, Zhang C, Dai H (2008) Mechanism and kinetics of apatite formation on nanocrystalline TiO2 coatings: a quartz crystal microbalance study. Acta Biomater 4:560–568

    Article  Google Scholar 

  29. Archana PS, Jose R, Jin TM, Vijila C, Yusoff MM, Ramakrishnaw S, Structural and electrical properties of Nb-doped Anatase TiO2 nanowires by electrospinning J. Am Ceram Soc 93 (2010) 4096–4102

  30. Avansi W, Arenal R Jr, de Mendonça VR, Ribeiro C, Longo E (2014) Vanadium-doped TiO2 anatase nanostructures: the role of V in solid solution formation and its effect on the optical properties. Cryst Eng Comm 16:5021–5027

    Article  Google Scholar 

  31. Yu D, Zhou W, Liu Y, Wu P (2016) Magnetic and optical properties of Al-doped anatase TiO2 (101) surface from density functional theory. J Magn Magn Mater 404:7–13

    Article  Google Scholar 

  32. Textor M, Sitting C, Franchiger V, Tosatti S, Brunette DM (2001) Properties and biological significance of natural oxide films on titanium and its alloys. In Titanium in Medicine; Brunette DM, Tengrall P, Textor M, Thomsen P, Eds.; Springer: New York, NY, USA, Chapter 7; pp. 172–230. ISBN 978-3-642-63119-1

Download references

Funding

The work is supported by the National Key Research and Development Project [Grant no. 2018YFB2002202].

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Hussien Hegab.

Additional information

Publisher’s note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

This article has been retracted. Please see the retraction notice for more detail:https://doi.org/10.1007/s00170-023-12363-4

Rights and permissions

Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Ahuja, N., Sharma, N., Hegab, H. et al. RETRACTED ARTICLE: Bioactivity measurement of commercially pure titanium processed by micro-electric discharge drilling. Int J Adv Manuf Technol 107, 2797–2805 (2020). https://doi.org/10.1007/s00170-020-05224-x

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00170-020-05224-x

Keywords

Navigation