Issue 15, 2020
From the journal:

Journal of Materials Chemistry C

Ferroelectricity in a lead free organic–inorganic 0D hybrid: formamidinium bromoantimonate(iii)†

K. Mencel,a   A. Gągor, ORCID logo b   R. Jakubas, ORCID logo a   A. Ciżman, ORCID logo c   W. Medycki, ORCID logo d   J. K. Zaręba ORCID logo e  and  A. Piecha-Bisiorek ORCID logo *a  

* Corresponding authors

a Faculty of Chemistry, University of Wrocław, F. Joliot-Curie 14, 50–383 Wrocław, Poland
E-mail: anna.piecha@chem.uni.wroc.pl
Fax: +48 713757270
Tel: +48 713757646

b W. Trzebiatowski Institute of Low Temperature and Structure Research PAS, P.O. Box 1410, 50-950 Wrocław, Poland

c Department of Experimental Physics, Wrocław University of Science and Technology, Wybrzeże Wyspiańskiego 27, 50-370 Wrocław, Poland

d Institute of Molecular Physics, Polish Academy of Science, M. Smoluchowskiego 17, 60-179 Poznań, Poland

e Advanced Materials Engineering and Modelling Group, Faculty of Chemistry, Wroclaw University of Science and Technology, Wybrzeze Wyspianskiego 27, 50-370 Wrocław, Poland

Abstract

A multiphase, low-temperature ferroelectric material of haloantimonate(III) with a unique R5M2X11 composition and spontaneous polarization of about 3 μC cm−2 resulting from the mixed ‘order–disorder’ and ‘displacive’ molecular mechanism is successfully synthesized and characterized.

Graphical abstract: Ferroelectricity in a lead free organic–inorganic 0D hybrid: formamidinium bromoantimonate(iii)

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Article information

DOI
https://doi.org/10.1039/D0TC00168F
Article type
Communication
Submitted
10 Jan 2020
Accepted
25 Mar 2020
First published
26 Mar 2020

J. Mater. Chem. C, 2020,8, 5025-5028

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Ferroelectricity in a lead free organic–inorganic 0D hybrid: formamidinium bromoantimonate(III)

K. Mencel, A. Gągor, R. Jakubas, A. Ciżman, W. Medycki, J. K. Zaręba and A. Piecha-Bisiorek, J. Mater. Chem. C, 2020, 8, 5025 DOI: 10.1039/D0TC00168F

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