The influence of an electric field on the transmission of linearly polarized light by polyvinylbutyral composite films doped with particles of the heterometallic complex (NH4)2{[Cu(dien)(H2O)]2[α-V2Mo6O26]}∙5H2O (dien = diethylenetriamine) was studied. The absorption became anisotropic if an electrostatic field was applied during irradiation of the composites by linearly polarized light. The observed electrooptical effect was explained by photo-induced optical anisotropy that was caused by the linearly polarized light and changed in space due to reorientation of the dipole moment of photogenerated electron–hole pairs in the composite under the action of the external electric field.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
A. A. Beznishchenko, V. G. Makhan′kova, N. A. Davidenko, I. I. Davidenko, V. N. Kokozei, and A. N. Popenaka, Zh. Prikl. Spektrosk., 74, No. 4, 481–484 (2007) [A. A. Beznischenko, V. G. Makhankova, N. A. Davidenko, I. I. Davidenko, V. N. Kokozay, and A. N. Popenaka, J. Appl. Spectrosc., 74, 524–532 (2007)].
N. A. Davidenko, V. N. Kokozei, I. I. Davidenko, G. I. Buvailo, V. G. Makhan′kova, and S. L. Studzinskii, Zh. Prikl. Spektrosk., 83, No. 5, 818–823 (2016) [N. A. Davidenko, V. N. Kokozay, I. I. Davidenko, H. I. Buvailo, V. G. Makhankova, and S. L. Studzinsky, J. Appl. Spectrosc., 83, 854–859 (2016)].
N. A. Davidenko, V. N. Kokozei, I. I. Davidenko, H. I. Buvailo, V. G. Kakhan′kova, and S. L. Studzinskii, Teor. Eksp. Khim., 52, No. 1, 9–13 (2016).
S. Ohkoshi, H. Tokoro, T. Hozumi, and Y. Zhang, J. Am. Chem. Soc., 128, No. 1, 270–277 (2006).
J. M. Herrera, V. Marvaud, M. Verdaguer, J. Marrot, M. Kalisz, and C. Mathoniere, Angew. Chem., Int. Ed., 43, No. 41, 5468–5471 (2004).
M. F. Budyka, Usp. Khim., 86, No. 3, 181–210 (2017).
T. G. Prokhorova and E. B. Yagubskii, Usp. Khim., 86, No. 2, 164–180 (2017).
V. V. Rakitin and G. F. Novikov, Usp. Khim., 86, No. 2, 99–112 (2017).
S. Zhao, L. Liu, and Y.-F. Song, Dalton Trans., 41, 9855–9858 (2012).
G. Zhu, E. N. Glass, C. Zhao, H. Lv, J. W. Vickers, Yu. V. Geletii, D. G. Musaev, J. Song, and C. L. Hill, Dalton Trans., 41, 13043–13049 (2012).
F.-Y. Yi, W. Zhu, S. Dang, J.-P. Li, D. Wu, Y. Li, and Z.-M. Sun, Chem. Commun., 51, No. 16, 3336–3339 (2015).
J. M. Clemente-Juan, E. Coronado, and A. Gaita-Arino, Chem. Soc. Rev., 41, 7464–7478 (2012).
R. Tan, X. Pang, H. Wang, S. Cui, Y. Jiang, C. Wang, X. Wang, and W. Song, Inorg. Chem. Commun., No. 25, 70–73 (2012).
H. I. Buvailo, V. G. Makhankova, V. N. Kokozay, I. V. Omelchenko, S. V. Shishkina, J. Jezierska, M. V. Pavliuk, and S. I. Shylin, Inorg. Chem. Front., 6, 1813–1823 (2019).
H. I. Buvailo, O. V. Desiatkina, V. G. Makhankova, V. N. Kokozay, K. V. Domasevitch, I. V. Omelchenko, and V. V. Dyakonenko, J. Solid State Chem., 270, 563–568 (2019).
N. A. Davidenko, M. A. Zabolotny, and A. A. Ishchenko, Spectrochim. Acta, Part A, 61, 213–218 (2005).
N. A. Davidenko, V. A. Pavlov, N. G. Chuprina, I. I. Davidenko, and L. Baath, J. Appl. Phys., 100, 02311–02314 (2006).
N. A. Davidenko, V. N. Kokozei, I. I. Davidenko, O. V. Nesterova, and D. V. Shevchenko, Fiz. Tekh. Poluprovodn., 40, No. 2, 246–254 (2006).
N. A. Davidenko, V. N. Kokozei, I. I. Davidenko, O. V. Nesterova, S. L. Studzinskii, N. G. Spitsyna, and A. S. Lobach, Teor. Eksp. Khim., 42, No. 2, 107–112 (2006).
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 87, No. 1, pp. 21–24, January–February, 2020.
Rights and permissions
About this article
Cite this article
Davidenko, N.A., Kokozay, V.N., Studzinsky, S.L. et al. Electrooptical Effect in Polymeric Composites Containing a Heterometallic Cu/V/Mo Complex. J Appl Spectrosc 87, 15–17 (2020). https://doi.org/10.1007/s10812-020-00955-x
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10812-020-00955-x