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Production of Nanocrystalline Ceramics Based on Perovskite-Like Oxides Bi1–xSrxFeO3–𝛅

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The formation of ceramics based on Bi1–xSrxFeO3–δ solid solutions produced by glycine-nitrate combustion was studied. The yield of target product was greatest for x = 0 – 0.5. The synthesis temperature range and start of grain sintering correlated with fusion of the surface phase. The sintering activation temperatures and thermal-expansion coefficients of the nanocrystalline ceramics were determined.

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References

  1. J. Wu, Z. Fan, D. Xiao, J. Zhu, and J. Wang, “Multiferroic bismuth ferrite-based materials for multifunctional applications: Ceramic bulks, thin films and nanostructures,” Prog. Mater. Sci., 84, 335 – 340 (2016); DOI: https://doi.org/10.1016/j.pmatsci.2016.09.001.

    Article  CAS  Google Scholar 

  2. V. I. Popkov, O. V. Almjasheva, V. N. Nevedomskiy, et al., “Effect of spatial constraints on the phase evolution of YFeO3-based nanopowders under heat treatment of glycine-nitrate combustion products,” Ceram. Int., 44(17), 20906 – 20912 (2018); DOI: https://doi.org/10.1016/j.ceramint.2018.08.097.

    Article  CAS  Google Scholar 

  3. O. N. Karpov, M. V. Tomkovich, and E. A. Tugova, “Formation of Nd1–xBixFeO3 nanocrystals under conditions of glycine-nitrate synthesis,” Zh. Obshch. Khim., 88(10), 1692 – 1698 (2018); DOI: https://doi.org/10.1134/S0044460X18100177.

    Article  Google Scholar 

  4. J. Pal, S. Kumar, L. Singh, M. Singh, and A. Singh, “Study of the structural and magnetic phase-transitions and multiferroic properties in BiFeO3–Ba0.95Ca0.05TiO3 solid solutions,” Mater. Res. Bull., 102, 36 – 44 (2018); DOI:https://doi.org/10.1016/j.materresbull.2018.02.012.

  5. N. A. Lomanova, M. V. Tomkovich, V. L. Ugolkov, et al., “Formation mechanism, thermal and magnetic properties of (Bi1–xSrx)m+1Fem–3Ti3O3(m+1)–δ (m = 4 – 7) ceramics,” Nanosyst.: Phys., Chem., Math., 9(5), 676 – 687 (2018); DOI: https://doi.org/10.17586/2220-8054-2018-9-5-676-687.

  6. N. A. Lomanova, “Synthesis and thermal properties of nanoand macrocrystalline ceramic materials based on Bi5FeTi3O15,” Nov. Ogneupory, No. 6, 29 – 33 (2018); DOI: https://doi.org/10.17073/1683-4518-2018-6-29-33.

  7. N. A. Lomanova, M. V. Tomkovich, V. V. Sokolov, et al., “Thermal and magnetic behavior of BiFeO3 nanoparticles prepared by glycine-nitrate combustion,” J. Nanopart. Res., 20(2), 17 (2018); DOI: https://doi.org/10.1007/s11051-018-4125-6.

  8. N. A. Baharuddin, A. Muchtar, and M. Rao Somalu, “Preparation of SrFe0.5Ti0.5O3–δ perovskite-structured ceramic using the glycine-nitrate combustion technique,” Mater. Lett., 194, 197 – 201 (2017); DOI: https://doi.org/10.1016/j.matlet.2017.02.064.

    Article  CAS  Google Scholar 

  9. N. A. Lomanova, M. V. Tomkovich, V. V. Sokolov, and V. V. Gusarov, “Special features of formation of nanocrystalline BiFeO3 via the glycine-nitrate combustion method,” Zh. Obshch. Khim., 86(10), 1605 – 1612 (2016); DOI: https://doi.org/10.1134/S1070363216100030.

    Article  CAS  Google Scholar 

  10. V. I. Popkov, E. A. Tugova, A. K. Bachina, and O. V. Almyasheva, “The formation of nanocrystalline orthoferrites of rare-earth elements XFeO3 (X = Y, La, Gd) via heat treatment of coprecipitated hydroxides,” Zh. Obshch. Khim., 87(11), 1771 – 1780 (2017).

  11. E. Tugova, S. Yastrebov, O. Karpov, and R. Smith, “NdFeO3 nanocrystals under glycine nitrate combustion formation,” J. Cryst. Growth., 467, 88 – 92 (2017); DOI:https://doi.org/10.1016/j.jcrysgro.2017.03.022.

    Article  CAS  Google Scholar 

  12. N. Gao, C. Quan, Y. Maa, et al., “Experimental and first principles investigation of the multiferroics BiFeO3 and Bi0.9Ca0.1FeO3: Structure, electronic, optical and magnetic properties,” Phys. B, 481, 45 – 52 (2016).

    Article  CAS  Google Scholar 

  13. I. Sosnowska, T. P. Neumaier, and E. Streichele, “Spiral magnetic ordering in bismuth ferrite,” J. Phys. C: Solid State Phys., 15, 4835 – 4846 (1982); DOI: https://doi.org/10.1088/0022-3719/15/23/020.

    Article  CAS  Google Scholar 

  14. M. I. Morozov, N. A. Lomanova, and V. V. Gusarov, “Specific features of BiFeO3 formation in a mixture of bismuth(III) and iron(III) oxides,” Zh. Obshch. Khim., 73(11), 1772 – 1776 (2003); DOI: https://doi.org/10.1023/B:RUGC.0000018640.30953.70.

    Article  Google Scholar 

  15. M. Valant, A.-K. Axelsson, and N. Alford, “Peculiarities of a solid-state synthesis of multiferroic polycrystalline BiFeO3,” Chem. Mater., 19, 5431 – 5436 (2007); DOI: https://doi.org/10.1021/cm071730+.

    Article  CAS  Google Scholar 

  16. N. A. Lomanova and V. V. Gusarov, “Phase states in the Bi4Ti3O12-BiFeO3 section in the Bi2O3–TiO2–Fe2O3 system,” Zh. Neorg. Khim., 56(4), 661 – 665 (2011); DOI: https://doi.org/10.1134/S0036023611040188.

    Article  CAS  Google Scholar 

  17. V. V. Gusarov, “The thermal effect of melting in polycrystalline systems,” Thermochim. Acta, 256(2), 467 – 472 (1995); DOI: https://doi.org/10.1016/0040-6031(94)01993-Q.

    Article  CAS  Google Scholar 

  18. A. N. Kovalenko and E. A. Tugova, “Thermodynamics and kinetics of non-autonomous phase formation in nanostructured materials with variable functional properties,” Nanosyst.: Phys., Chem., Math., 9(5), 641 – 662 (2018); DOI: https://doi.org/10.17586/2220-8054-2018-9-5-641-662.

  19. R. D. Shannon, “Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides,” Acta Crystallogr., Sect. A: Found. Adv., 32, 751 (1976).

  20. N. A. Lomanova, V. L. Ugolkov, and V. V. Gusarov, “Thermal behavior of layered pervoskite-like compounds in the Bi4Ti3O12–BiFeO3 system,” Fiz. Khim. Stekla, 33(6), 608 – 612 (2007); DOI: https://doi.org/10.1134/S1087659607060120.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. A. F. Ioffe Physical-Technical Institute, Russian Academy of Sciences, St. Petersburg, Russia

    N. A. Lomanova

  2. I. V. Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences, St. Petersburg, Russia

    A. V. Osipov & V. L. Ugolkov

Authors
  1. N. A. Lomanova
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  2. A. V. Osipov
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  3. V. L. Ugolkov
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Corresponding author

Correspondence to N. A. Lomanova.

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Translated from Novye Ogneupory, No. 10, pp. 33 – 37, September, 2019.

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Lomanova, N.A., Osipov, A.V. & Ugolkov, V.L. Production of Nanocrystalline Ceramics Based on Perovskite-Like Oxides Bi1–xSrxFeO3–𝛅. Refract Ind Ceram 60, 501–505 (2020). https://doi.org/10.1007/s11148-020-00393-4

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  • DOI: https://doi.org/10.1007/s11148-020-00393-4

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