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Using Porous Ceramic Catalytic Converters for Dehydrogenation of Propane in Propylene

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Self-propagating high temperature synthesis (SHS) was used to obtain porous cermet membranes based on a mixture of aluminum oxide, silicon carbide, and magnesium oxide powders. The obtained membranes are catalytically active. The surfaces of the open pores in them were modified by rhenium-tungsten active components using the alkoxy method. The highest selectivity in terms of propane (about 60%) is achieved at temperature 600°C. In addition, the optimal conditions for implementing the propane dehydrogenation process is temperature 650°C at which the quite high selectivity for the most important monomers remains with a relatively small contribution of accessory processes.

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References

  1. I. Amghizar, L. A. Vandewalle, K. M. Van Geem, and G. B. Marin, “New trends in olefin production,” Engineering, 3(2), 171 – 178 (2017); URL: https://doi.org/10.1016/J.ENG.2017.02.006.

  2. N. L. Morrow, “The industrial production and use of 1,3-butadiene,” Environmental Health Perspectives, 86(7 – 8) (1990); URL: https://doi.org/10.1289/ehp.90867.

  3. W. C. White, “Butadiene production process overview,” Chem.-Biolog. Interactions, 166(1 – 3), 10 – 14 (2007); URL: https://doi.org/10.1016/j.cbi.2007.01.009.

  4. G. O. Ezinkwo, V. F. Tretjakov, R. M. Talyshinky, et al., “Overview of the catalytic production of isoprene from different raw materials; prospects of isoprene production from bio-ethanol,” Catalysis for Sustainable Energy, No. 1, 100 – 111 (2013); URL: https://doi.org/10.2478/cse-2013-0006.

  5. W.W. Kaeding, “Styrene monomer,” Catal. Rev., 8(1), 307 – 316 (1974); URL: https://doi.org/10.1080/01614947408071865.

  6. I. A. Makaryan and V. I. Savchenko, “On the way to develop an alternative energy-saving ‘on-purpose’ propylene production,” Alternative Energy and Ecology, No. 10, 99 – 121 (2009); URL: https://elibrary.ru/download/elibrary_12963698_30637490.pdf.

  7. A. V. Lavrenov, L. F. Saifulina, E. A. Buluchevskii, and E. N. Bogdanets, “Propylene production technology: Today and tomorrow,” Catalysis in Industry, 7(3), 175 – 187 (2015); URL: https://doi.org/10.1134/S2070050415030083.

  8. Chuck Carr, Global Propylene Market, Motivated to Change; URL: http://cdn.ihs.com/www/pdf/asia-chem-conf/Carr.pdf.

  9. Global Production of Propylene Running at 90% Capacity, Information and Analytical Center RUPEC; URL: http://rupec.ru/news/39475/.

  10. IXS Markit: Propylene, Chemical Economics Handbook; URL: https://ihsmarkit.com/products/propylene-chemical-economicshandbook.html.

  11. I. M. Kurchatov, N. I. Laguntsov, M. V. Tsodikov, et al., “The nature of permeability anisotropy and catalytic activity,” Kinetics and Catalysis, 49(1), 121 – 126 (2008); URL: https://doi.org/10.1134/S0023158408010151.

  12. M. V. Tsodikov, A. S. Fedotov, V. V. Zhmakin, et al., “Carbon dioxide reforming of alcohols on porous membrane catalyst systems,” Petroleum Chem., 51(7), 568 – 576 (2011); URL: https://doi.org/10.1134/S0965544111070127.

  13. A. S. Fedotov, D. O. Antonov, V. I. Uvarov, et al., “Synergistic effect in the dry methane reforming on porous ceramic Ni–Co membranes,” Dokl. Chem., 459(1), 202 – 204 (2014); URL: https://doi.org/10.1134/S0012500814110020.

  14. A. S. Fedotov, D. O. Antonov, O. V. Bukhtenko, et al., “The role of aluminum in the formation of Ni–Al–Co-containing porous ceramic converters with high activity in dry and steam reforming of methane and ethanol,” Int. J. Hydrogen Energy, 42(38), 24131 – 24141 (2017); URL: https://doi.org/10.1016/j.ijhydene.2017.07.095.

  15. A. S. Fedotov, D. O. Antonov, V. I. Uvarov, and M. V. Tsodikov, “Original hybrid membrane-catalytic reactor for the CoProduction of syngas and ultrapure hydrogen in the processes of dry and steam reforming of methane, ethanol and DME,” Int. J. Hydrogen Energy, 43(14), 7046 – 7054 (2018); URL: https://doi.org/10.1016/j.ijhydene.2018.02.060.

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Authors and Affiliations

  1. A. G. Merzhanov Institute of Structural Macrokinetics and Materials Science, Russian Academy of Sciences (MISMMS RAN), Chernogolovka, Russia

    V. I. Uvarov, V. É. Loryan & R. D. Kapustin

  2. A. V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences (TIPS RAN), Moscow, Russia

    A. S. Fedotov, M. V. Tsodikov & G. I. Konstantinov

Authors
  1. V. I. Uvarov
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  2. V. É. Loryan
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  3. R. D. Kapustin
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  4. A. S. Fedotov
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  5. M. V. Tsodikov
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  6. G. I. Konstantinov
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Translated from Steklo i Keramika, No. 11, pp. 35 – 39, November, 2019.

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Uvarov, V.I., Loryan, V.É., Kapustin, R.D. et al. Using Porous Ceramic Catalytic Converters for Dehydrogenation of Propane in Propylene. Glass Ceram 76, 428–431 (2020). https://doi.org/10.1007/s10717-020-00216-5

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  • DOI: https://doi.org/10.1007/s10717-020-00216-5

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