Skip to main content
Log in

Index of refraction variation and photoluminescence quenching in silver-ion-exchanged glasses, due to interaction with low-energy He+ beam

  • Published:
Journal of Materials Science: Materials in Electronics Aims and scope Submit manuscript

Abstract

In the present work, interaction of a low-energy (~ 40 keV) He+ ion beam with silver-ion-exchanged glasses is studied. It is found that the interaction leads to increase of index of refraction and optical density of the interaction area of the samples, and at the same time, results in quenching of luminescence radiation of the interacted area on the samples. A remarkable dispersion for the index of refraction (n = n(λ)) is observed. Maximum change in the index of refraction occurs for the wavelength very close to the wavelength of the red-shifted surface plasmon resonance of the silver nanoclusters embedded in the glass matrix. Photoluminescence spectra studies show that interaction of silver-ion-exchanged glasses with low-energy He+ beam results in reduction of ionic silver clusters to the neutral ones, which is accompanied with increase of the index of refraction. That is, the produced neutral silver nanoparticles increase the index of refraction of the interacted area on the samples. Such manipulation of the index of refraction has potential for manufacturing miniaturized phase optical diffractive elements.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12
Fig. 13

Similar content being viewed by others

References

  1. F. Gonella, G. Mattei, P. Mazzoldi, E. Cattaruzza, G.W. Arnold, G. Battaglin, P. Calvelli, R. Polloni, B. Bertonecello, R.F. Haglund Jr., Interaction of high-power laser light with silver nanocluster composite glasses. Appl. Phys. Lett. 69, 3101 (1996)

    Article  CAS  Google Scholar 

  2. S.R. Friberg, P.W. Smith, Nonlinear optical glasses for ultrafast optical switches. IEEE J. Quantum Electron. QE-23, 2089 (1987)

    Article  CAS  Google Scholar 

  3. A. Nahal, H.R.M. Kkhalesifard, J. Mostafavi-Amjad, Photothermal-induced dichroism and micro-cluster formation in Ag+-doped glasses. Appl. Phys. B 79, 513–518 (2004)

    Article  CAS  Google Scholar 

  4. A. Nahal, J. Mostafavi-Amjad, A. Ghods, M.R.H. Khajehpour, S.N.S. Reihani, M.R. Kolahchi, Laser-induced dendritic microstructures on the surface of Ag+-doped glass. J. Appl. Phys. 100, 053503 (2006)

    Article  Google Scholar 

  5. A.L. Stepanov, V.N. Popok, D.E. Hole, A.A. Bukharaev, Interaction of high-power laser pulses with glasses containing implanted metallic nanoparticles. Phys. Solid State 43, 2192 (2001)

    Article  CAS  Google Scholar 

  6. A. Pinchuk, A. Hilger, G. vonPlessen, U. Kreibig, Substrate effect on the optical response of silver nanoparticles. Nanotechnology 15, 1890 (2004)

    Article  CAS  Google Scholar 

  7. F. Caccavale, G. De Marchi, F. Gonella, P. Mazzoldi, C. Meneghini, A. Quaranta, G.W. Arnold, G. Battaglin, G. Mattei, Irradiation-induced Ag-colloid formation in ion-exchanged soda-lime glass. Nucl. Instrum. Methods Phys. Res. 96, 382–386 (1995)

    Article  CAS  Google Scholar 

  8. M.C. Gupta, J. Ballato, The Handbook of Photonics (CRC Press, Taylor & Francis Group, Boca Raton, 2007)

    Google Scholar 

  9. S.I. Najafi, Introduction to Glass Integrated Optics (Artech House, USA, 1992)

    Google Scholar 

  10. U. Kriebig, M. Vollmer, Optical Properties of Metal Clusters (Springer-Verlag, Berlin, Heidelberg, New York, 1995)

    Book  Google Scholar 

  11. P.L. Inácio, B.J. Barreto, F. Horowitz, R.R.B. Correia, M.B. Pereira, Silver migration at the surface of ion-exchange waveguides: a plasmonic template. Opt. Mater. Express 3, 390 (2013)

    Article  Google Scholar 

  12. A. Nahal, A. Jalehdoost, Kh Hassani, A. Farokhniaee, Variation of index of refraction in the ion-exchanged glasses with the evolution of ionic and neutral silver nano-clusters“. Eur. Phys. J. Appl. Phys. 53, 10701 (2011)

    Article  Google Scholar 

  13. A. Nahal, H.R.M. Khalesifard, Beam power-dependent laser-induced fluorescence radiation quenching of silver-ion-exchanged glasses. Opt. Mater. 29, 987–994 (2007)

    Article  CAS  Google Scholar 

  14. A. Nahal, F. Moslehirad, Laser-induced anisotropy in Ag+-doped glasses. J. Mater. Sci. 42(12), 9075–9082 (2007)

    Article  CAS  Google Scholar 

  15. A. Nahal, K. Shapoori, Linear dichroism, produced by thermo-electric alignment of silver nanoparticles on the surface of ion-exchanged glass. Appl. Surf. Sci. 255, 7946–7950 (2009)

    Article  CAS  Google Scholar 

  16. A. Nahal, R. Talebi, M.F. Miri, Thermo-electric-induced dichroism in ion-exchanged glasses: a candidate mechanism for the alignment of silver nanoparticles. Appl. Phys. A 106, 941–947 (2012)

    Article  CAS  Google Scholar 

  17. A. Sharma, S. Aggarwal, Optical investigation of soda lime glass with buried silver nanoparticles synthesized by ion implantation. J. Non-Cryst. Solids 485, 57–65 (2018)

    Article  Google Scholar 

  18. an EXAFS study, G. Battaglin, E. Cattaruzza, F. Gonella, R. Polloni, F. D_Acapito, S. Colonna, G. Mattei, C. Maurizio, P. Mazzoldi, S. Padovani, C. Sada, A. Quaranta, A. Longo. Silver nanocluster formation in ion-xchanged glasses by annealing, ion beam and laser beam irradiation. Nucl. Instrum. Methods Phys. Res. B 200, 185–190 (2003)

    Article  Google Scholar 

  19. JPh Blondeau, O. Veron, F. Catan, O. Kaitasov, N. Sbai, C. Andreazza-Vignolle, Clustering of silver nanoclusters embedded in soda lime glasses using ionic exchange and helium ion bombardment. Plasmonics 4, 245–252 (2009)

    Article  CAS  Google Scholar 

  20. J.C. Pivin, G. Roger, M.A. Garcia, F. Singh, D.K. Avasthi, Nucleation and growth of Ag clusters in silicate glasses under ion irradiation. Nucl. Instrum. Methods Phys. Res. B 215, 373–384 (2004)

    Article  CAS  Google Scholar 

  21. F. Singh, S. Mohapatra, J.P. Stoquert, D.K. Avasthi, J.C. Pivin, Shape deformation of embedded metal nanoparticles by swift heavy ion irradiation. Nucl. Instr. Meth. Phys. Res. B 267, 936–940 (2009)

    Article  CAS  Google Scholar 

  22. D. Manikandana, S. Mohanc, K.G.M. Nairb, Absorption and luminescence of silver nanocomposite soda-lime glass formed by Agþ-Naþ ion-exchange. Mater. Res. Bull. 38, 1545–1550 (2003)

    Article  Google Scholar 

  23. A. Nahal, G. Ghodsi, Investigation of refractive index specifying parameters for planar waveguides produced by ion-exchange method, by means of Brewster's angle measurement. Proc. of 13th Ann. Iranian Conf. on Optics and Photonics, 747–750, Feb. 2007, Tehran, Iran (In Persian)

  24. M. Mahjour-Shafiei, H. Noori, A.H. Ranjbar, Influence of magnetic field on the electric breakdown in penning ion source. Rev. Sci. Instrum. 82, 113502 (2011)

    Article  CAS  Google Scholar 

  25. D.P. Peters, C. Strohhofer, M.L. Brongersma, J. van der Elsken, A. Polman, Formation mechanism of silver nanocrystals made by ion irradiation of Na+ ↔ Ag+ ion-exchanged soda lime silicate glass. Nucl. Instrum. Methods Phys. Res. B 168, 237–244 (2000)

    Article  CAS  Google Scholar 

  26. T. Isaji, T. Wakasugi, K. Fukumi, K. Kadono, Reversible redox and clusterization of silver in glasses by X-ray irradiation and heat treatment: mechanism of photochromic behavior of halogen-free silver-doped glass. Chem. Phys. Lett. 522, 72–78 (2012)

    Article  CAS  Google Scholar 

  27. V.V. Kresin, Collective resonances in silver clusters: role of d electrons and the polarization-free surface layer. Phys. Rev. B 51, 1844 (1995)

    Article  CAS  Google Scholar 

  28. https://prism.mit.edu/xray

Download references

Acknowledgements

A. Nahal would like appreciate Dr. MirFaez Miri from Department of Physics of University of Tehran for his valuable discussions.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Arashmid Nahal.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Nahal, A., Mahjour-Shafiei, M. & Hosseini, S.R. Index of refraction variation and photoluminescence quenching in silver-ion-exchanged glasses, due to interaction with low-energy He+ beam. J Mater Sci: Mater Electron 31, 5499–5510 (2020). https://doi.org/10.1007/s10854-020-03115-1

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10854-020-03115-1

Navigation