Skip to main content
Log in

Field emission performance of vertically aligned carbon nanotubes and their improved enhancement factors by the simple solution treatment

  • Published:
Journal of Materials Science: Materials in Electronics Aims and scope Submit manuscript

Abstract

In this study, the vertically aligned carbon nanotubes (VACNTs) are fabricated on substrate via a simply spraying chemical vapor deposition method. The relationship between the field emission performance and the aspect ratio of the VACNTs is systematically studied. The optimal growth conditions of the VACNTs with outstanding field emission performance are obtained. Meanwhile, the field emission properties of the VACNTs are further improved via a simple acetone-densification treatment. After the densification, the turn-on electric field and threshold electric field could decrease to 0.83 V/μm and 2.45 V/μm, respectively, and the field enhancement factor will increase to 26,588. In addition, the field emission current stability of the VACNTs is also strengthened. The improvement of field emission performance could be resulted from the reduction of field shielding effect after tip densification. The high current density and good stability demonstrate that the densified VACNTs are the promising and highly efficient field electron emitters.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8

Similar content being viewed by others

References

  1. Y. Liu, S. Kumar, Recent progress in fabrication, structure, and properties of carbon fibers. Polym. Rev. 52(3), 234–258 (2012)

    Article  CAS  Google Scholar 

  2. H. Dai, Carbon nanotubes: synthesis, integration, and properties. Acc. Chem. Res. 35(12), 1035–1044 (2003)

    Article  Google Scholar 

  3. W.A. de Heer, A. Châtelain, D. Ugarte, A carbon nanotube field-emission electron source. Science 270(5239), 1179–1180 (1995)

    Article  Google Scholar 

  4. J.I. Sohn, S. Lee, Y.H. Song, S.Y. Choi, K.I. Cho, K.S. Nam, Large field emission current density from well-aligned carbon nanotube field emitter arrays. Curr. Appl. Phys. 1(1), 61–65 (2001)

    Article  Google Scholar 

  5. Z. Chen, Q. Zhang, P. Lan, B. Zhu, T. Yu, G. Cao, D.D. Engelsen, Ultrahigh-current field emission from sandwich-grown well-aligned uniform multi-walled carbon nanotube arrays with high adherence strength. Nanotechnology. 18(26), 265702 (2007)

    Article  Google Scholar 

  6. J.H. Han, T.Y. Lee, D. Kim, J.W. Yoo, C.Y. Park, J. Choi, T. Jung, I. Han, J.M. Kim, Field emission properties of carbon nanotubes grown on Co/TiN coated Ta substrate for cathode in microwave power amplifier. Diam. Relat. Mater. 13, 987–993 (2004)

    Article  CAS  Google Scholar 

  7. S.H. Heo, H.J. Kim, J.M. Ha, S.O. Cho, A vacuum-sealed miniature X-ray tube based on carbon nanotube field emitters. Nanoscale Res. Lett. 7(1), 258 (2012)

    Article  Google Scholar 

  8. W.B. Choi, D.S. Chung, J.H. Kang, H.Y. Kim, Y.W. Jin, I.T. Han, Y.H. Lee, J.E. Jung, N.S. Lee, G.S. Park, J.M. Kim, Fully sealed, high-brightness carbon-nanotube field-emission display. Appl. Phys. Lett. 75(20), 3129–3131 (1999)

    Article  CAS  Google Scholar 

  9. Y. Nakanishi, A. Miyake, H. Kominami, T. Aoki, Y. Hatanaka, G. Shimaoka, Preparation of ZnO thin films for high-resolution field emission display by electron beam evaporation. Appl. Surf. Sci. 142, 233–236 (1999)

    Article  CAS  Google Scholar 

  10. C. Chen, R. Pakter, Mechanisms and control of beam halo formation in intense microwave sources and accelerators. Phys. Plasmas. 7(5), 2203–2214 (2000)

    Article  CAS  Google Scholar 

  11. Y.C. Choi, Y.M. Shin, D.J. Bae, L.S. Cim, Y.H. Lee, B.S. Lee, Patterned growth and field emission properties of vertically aligned carbon nanotubes. Diam. Relat. Mater. 10(8), 1457–1464 (2001)

    Article  CAS  Google Scholar 

  12. J.I. Sohn, S. Lee, Y.H. Song, S.Y. Choi, K.I. Cho, K.S. Nam, Patterned selective growth of carbon nanotubes and large field emission from vertically well-aligned carbon nanotube field emitter arrays. Appl. Phys. Lett. 78(7), 901–903 (2001)

    Article  CAS  Google Scholar 

  13. E. Fedorovskaya, L. Bulusheva, A.G. Kurenya, I. Asanov, N.A. Rudina, K. Funtov, I. Lyubutin, A. Okotrub, Supercapacitor performance of vertically aligned multiwall carbon nanotubes produced by aerosol-assisted CCVD method. Electrochim. Acta. 139, 165–172 (2014)

    Article  CAS  Google Scholar 

  14. S. Neupane, M. Lastres, M. Chiarella, W. Li, Q. Su, G. Du, Synthesis and field emission properties of vertically aligned carbon nanotube arrays on copper. Carbon 50(7), 2641–2650 (2012)

    Article  CAS  Google Scholar 

  15. Y. Yang, S. Huang, H. He, A.W.H. Mau, L. Dai, Patterned growth of well-aligned carbon nanotubes: a photolithographic approach. J. Am. Chem. Soc. 121(46), 10832–10833 (1999)

    Article  CAS  Google Scholar 

  16. P.B. Amama, C.L. Pint, S.M. Kim, L. McJilton, K.G. Eyink, E.A. Stach, R.H. Hauge, B. Maruyama, Influence of alumina type on the evolution and activity of alumina-supported Fe catalysts in single-walled carbon nanotube carpet growth. ACS Nano 4(2), 895–904 (2010)

    Article  CAS  Google Scholar 

  17. L. Zhu, J. Xu, Y. Xiu, Y. Sun, D. Hess, C.P. Wong, Growth and electrical characterization of high-aspect-ratio carbon nanotube arrays. Carbon 44(2), 253–258 (2006)

    Article  CAS  Google Scholar 

  18. A. Mathur, S. Roy, K. Hazra, D. Misra, J. McLaughlin, Growth of carbon nanotube arrays using nanosphere lithography and their application in field emission devices. Diam. Relat. Mater. 19, 914–917 (2010)

    Article  CAS  Google Scholar 

  19. Y. Wang, B. Li, P.S. Ho, Z. Yao, L. Shi, Effect of supporting layer on growth of carbon nanotubes by thermal chemical vapor deposition. Appl. Phys. Lett. 89(18), 183113 (2006)

    Article  Google Scholar 

  20. S. Esconjauregui, R. Xie, M. Fouquet, R. Cartwright, D. Hardeman, J. Yang, J. Robertson, Measurement of area density of vertically aligned carbon nanotube forests by the weight-gain method. J. Appl. Phys. 113(14), 144309 (2013)

    Article  Google Scholar 

  21. J. Yun, R. Wang, W.K. Choi, J. Thong, C.V. Thompson, M. Zhu, Y.L. Foo, M.H. Hong, Field emission from a large area of vertically-aligned carbon nanofibers with nanoscale tips and controlled spatial geometry. Carbon 48(5), 1362–1368 (2010)

    Article  CAS  Google Scholar 

  22. L. Nilsson, O. Gröning, C. Emmenegger, O. Kuttel, E. Schaller, L. Schlapbach, H. Kind, J.M. Bonard, K. Kern, Scanning field emission from patterned carbon nanotube films. Appl. Phys. Lett. 76(15), 2071–2073 (2000)

    Article  CAS  Google Scholar 

  23. S.H. Jo, Y. Tu, Z.P. Huang, D. Carnahan, D. Wang, Z.F. Ren, Effect of length and spacing of vertically aligned carbon nanotubes on field emission properties. Appl. Phys. Lett. 82(20), 3520–3522 (2003)

    Article  CAS  Google Scholar 

  24. M. Chhowalla, C. Ducati, N. Rupesinghe, K.B.K. Teo, G. Amaratunga, Field emission from short and stubby vertically aligned carbon nanotubes. Appl. Phys. Lett. 79(13), 2079–2081 (2001)

    Article  CAS  Google Scholar 

  25. D.H. Kim, H.S. Jang, C.D. Kim, D.S. Cho, H.D. Kang, H.R. Lee, Enhancement of the field emission of carbon nanotubes straightened by application of argon ion irradiation. Chem. Phys. Lett. 378, 232–237 (2003)

    Article  CAS  Google Scholar 

  26. L.A. Gautier, V. Le Borgne, M.A.E. Khakani, Field emission properties of graphenated multi-wall carbon nanotubes grown by plasma enhanced chemical vapour deposition. Carbon 98, 259–266 (2015)

    Article  Google Scholar 

  27. X. Yang, G. Fang, N. Liu, C. Wang, Q. Zheng, H. Zhou, D. Zhao, H. Long, Y. Liu, X. Zhao, Synthesis and field emission properties of carbon nanotubes grown in ethanol flame based on a photoresist-assisted catalyst annealing process. Appl. Surf. Sci. 255(18), 7905–7911 (2009)

    Article  CAS  Google Scholar 

  28. X. Wang, M. Wang, P.M. He, Y.B. Xu, Z.H. Li, Model calculation for the field enhancement factor of carbon nanotube. J. Appl. Phys. 96(11), 6752–6755 (2004)

    Article  CAS  Google Scholar 

  29. S. Dumpala, J. Jasinski, G. Sumanasekera, M. Sunkara, Large area synthesis of conical carbon nanotube arrays on graphite and tungsten foil substrates. Carbon 49(8), 2725–2734 (2011)

    Article  CAS  Google Scholar 

  30. Z. Li, X. Yang, F. He, B. Bai, H. Zhou, C. Li, Q. Dai, High current field emission from individual non-linear resistor ballasted carbon nanotube cluster array. Carbon 89, 1–7 (2015)

    Article  CAS  Google Scholar 

  31. M. Meyyappan, L. Delzeit, A. Cassell, B. Hash, Carbon nanotube growth by PECVD: a review. Plasma Sources Sci. Technol. 12(2), 205–216 (2003)

    Article  CAS  Google Scholar 

  32. S. Park, A.P. Gupta, S.J. Yeo, J. Jung, S. Paik, M. Mativenga, S. Kim, J. Shin, J. Ahn, J. Ryu, Carbon nanotube field emitters synthesized on metal alloy substrate by PECVD for customized compact field emission devices to be used in X-ray source applications. Nanomaterials. 8(6), 378 (2018)

    Article  Google Scholar 

  33. M. Sreekanth, S. Ghosh, P. Srivastava, Tuning vertical alignment and field emission properties of multi-walled carbon nanotube bundles. Appl. Phys. A 124(1), 52 (2018)

    Article  Google Scholar 

  34. D. Varshney, A. Sumant, B. Weiner, G. Morell, Growth of carbon nanotubes on spontaneously detached free standing diamond films and their field emission properties. Diam. Relat. Mater. 30, 42–47 (2012)

    Article  CAS  Google Scholar 

  35. R. Rakhi, K. Sethupathi, R. Sundara, Field emission from carbon nanotubes on a graphitized carbon fabric. Carbon 46(13), 1656–1663 (2008)

    Article  CAS  Google Scholar 

Download references

Acknowledgements

The work is financially supported by the National Natural Science Foundation of China (Grant No. 51572218), the Key Project of Research and Development of Shaanxi Province (China) (No. 2018ZDCXL-GY-08-05), and the Key Science and Technology Innovation Team Project of Natural Science Foundation of Shaanxi Province (China) (2017KCT-01).

Author information

Authors and Affiliations

Authors

Corresponding authors

Correspondence to Weilong Li or Zhaoyu Ren.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Wei, D., Li, W., Liu, Y. et al. Field emission performance of vertically aligned carbon nanotubes and their improved enhancement factors by the simple solution treatment. J Mater Sci: Mater Electron 31, 5274–5283 (2020). https://doi.org/10.1007/s10854-020-03087-2

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10854-020-03087-2

Navigation