SCHEDULED MAINTENANCE
Assessing the limitations of transparent conducting oxides as thermoelectrics†
Abstract
Thermoelectrics are a promising technology for converting heat into renewable electricity. Currently, however, most of the best thermoelectrics are based on toxic and/or rare materials such as PbTe and Bi2Te3, limiting their practical applications. Transparent conducting oxides (TCOs) are well understood and widely used commercially, so if they could be made into thermoelectrics, they could be rapidly and prolifically deployed. TCOs have been tested for their thermoelectric capabilities, however their performance is far below that needed for industrial deployment. Here we use hybrid density functional theory to screen four TCOs: BaSnO3, CdO, SnO2 and ZnO for thermoelectric efficiency and analyse the limitations of TCOs as thermoelectrics. We demonstrate that the dominant factor limiting these materials is the lattice thermal conductivity, and more specifically very long phonon mean free paths up to the order 10 μm, making them strong candidates for nanostructuring to increase performance. Based on these insights we critically discuss materials design principles for increasing the ZT of the conducting oxides.
- This article is part of the themed collection: Journal of Materials Chemistry A HOT Papers
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